The DOI matches its Crossref record.
Electrode Kinetics of Oxygen Evolution and Dissolution on Rh, Ir, and Pt-Rh Alloy Electrodes
Open accessAbstract
Cathodic and anodic Tafel parameters, stoichiometric numbers, and decay kinetics have been determined on rhodium, iridium, and platinum‐rhodium alloy electrodes. Two regions of constant for a given substrate were observed. The catalytic activity of the substrates in acid solution above about 1.4v ( vs. N.H.E.) was On the anodic side, the alloy substrate tends to behave as Rh, on the cathodic side as Pt. Time decay behavior was conventional except for the alloy surface, where the decay from the anodic side behavior resembled that on Pt. The stoichiometric number on Rh, Ir, and Pt‐Rh was about 2. Rate‐determining steps have been determined unambiguously by the criteria mentioned because of the existence and helpful diagnostic nature of two distinct values for on the anodic side, and because of the availability of stoichiometric numbers. After anodic polarization, Pt‐Rh electrodes behave as if the substrate were an individual area of Pt and Rh oxides. A model which rationalizes this deduction is suggested.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cited by
Design of electrocatalysts for oxygen- and hydrogen-involving energy conversion reactions
Jiao, Y., Zheng, Y., Jaroniec, M., & Qiao, S. Z. (2015) · Chemical Society Reviews · doi:10.1039/c4cs00470a · Cited by 5,388
Recent progress in alkaline water electrolysis for hydrogen production and applications
Zeng, K., & Zhang, D. (2010) · Progress in Energy and Combustion Science · doi:10.1016/j.pecs.2009.11.002 · Cited by 3,611
Toward the rational design of non-precious transition metal oxides for oxygen electrocatalysis
Hong, W. T., Risch, M., Stoerzinger, K. A., Grimaud, A., Suntivich, J., & Shao-Horn, Y. (2015) · Energy & Environmental Science · doi:10.1039/c4ee03869j · Cited by 2,089
Developments and perspectives of oxide-based catalysts for the oxygen evolution reaction
Fabbri, E., Habereder, A., Waltar, K., Kötz, R., & Schmidt, T. J. (2014) · Catal. Sci. Technol. · doi:10.1039/c4cy00669k · Cited by 1,303
Oxygen electrocatalysts for water electrolyzers and reversible fuel cells: status and perspective
Park, S., Shao, Y., Liu, J., & Wang, Y. (2012) · Energy & Environmental Science · doi:10.1039/c2ee22554a · Cited by 578
Metadata
- Authors
- Damjanovic, A., Dey, A., & Bockris, J. O.
- Venue
- Journal of The Electrochemical Society
- Publisher
- The Electrochemical Society
- Published
- 1966
- Volume
- 113
- Issue
- 7
- Pages
- 739
- ISSN
- 0013-4651 (ISSN-L)
- OpenAlex
- W2088192590
- Cited by
- 184
- References
- 0
- FWCI
- 5.07
- Type
- journal article
- Language
- en
- Open access
- bronze
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
How to cite
Cite CoChat for the checks on this page, and the paper for its own findings.
- This page
- CoChat. (2026). Citation check: Electrode Kinetics of Oxygen Evolution and Dissolution on Rh, Ir, and Pt-Rh Alloy Electrodes. https://app.cochat.ai/papers/10.1149/1.2424104
- The paper
- Damjanovic, A., Dey, A., & Bockris, J. O. (1966). Electrode Kinetics of Oxygen Evolution and Dissolution on Rh, Ir, and Pt-Rh Alloy Electrodes. Journal of The Electrochemical Society. https://doi.org/10.1149/1.2424104
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
