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Size-Dependent Lithium Miscibility Gap in Nanoscale Li[sub 1−x]FePO[sub 4]
Open accessAbstract
Olivine compounds have emerged as important and enabling positive electrode materials for high-power, safe, long-life lithium rechargeable batteries. In this work, the miscibility gap in undoped is shown to contract systematically with decreasing particle size in the nanoscale regime and with increasing temperature at a constant particle size. These effects suggest that the miscibility gap completely disappears below a critical size. In the size-dependent regime, the kinetic response of nanoscale olivines should deviate from the simple size-scaling implicit in Fickian diffusion.
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Cited by
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Ellis, B. L., Makahnouk, W. R. M., Makimura, Y., Toghill, K., & Nazar, L. F. (2007) · Nature Materials · doi:10.1038/nmat2007 · Cited by 964
Identify capacity fading mechanism in a commercial LiFePO4 cell
Dubarry, M., & Liaw, B. Y. (2009) · Journal of Power Sources · doi:10.1016/j.jpowsour.2009.05.036 · Cited by 675
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Calculations of Li-Ion Diffusion in Olivine Phosphates
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Metadata
- Authors
- Meethong, N., Huang, H.-Y. S., Carter, W. C., & Chiang, Y.-M.
- Venue
- Electrochemical and Solid-State Letters
- Publisher
- The Electrochemical Society
- Published
- 2007
- Volume
- 10
- Issue
- 5
- Pages
- A134
- ISSN
- 1099-0062 (ISSN-L)
- OpenAlex
- W2414043227
- Cited by
- 443
- References
- 0
- FWCI
- 29.30
- Type
- journal article
- Language
- en
- Open access
- bronze
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- Meethong, N., Huang, H.-Y. S., Carter, W. C., & Chiang, Y.-M. (2007). Size-Dependent Lithium Miscibility Gap in Nanoscale Li[sub 1−x]FePO[sub 4]. Electrochemical and Solid-State Letters. https://doi.org/10.1149/1.2710960
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