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Electrolyte Additive in Support of 5 V Li Ion Chemistry
Open accessAbstract
An electrolyte additive based on highly fluorinated phosphate ester structure was identified as being able to stabilize carbonate-based electrolytes on class cathode surfaces. The synthesis and structural analysis of the additive are described, and preliminary yet encouraging results from electrochemical characterization showed that this additive participates in forming a protective interphasial chemistry not only on transition metal oxide cathode at high voltage ( vs Li) but also on graphitic graphite at low voltage ( vs Li), making it possible to formulate an electrolyte supporting reversible -intercalation chemistry in the coveted region.
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Citations
Cited by
Electrolytes and Interphases in Li-Ion Batteries and Beyond
Xu, K. (2014) · Chemical Reviews · doi:10.1021/cr500003w · Cited by 5,566
Self-citationChen, S., Wen, K., Fan, J., Bando, Y., & Golberg, D. (2018) · Journal of Materials Chemistry A · doi:10.1039/c8ta03358g · Cited by 367
Borodin, O., Behl, W., & Jow, T. R. (2013) · The Journal of Physical Chemistry C · doi:10.1021/jp400527c · Cited by 365
Perspective—Fluorinating Interphases
Wang, C., Meng, Y. S., & Xu, K. (2019) · Journal of The Electrochemical Society · doi:10.1149/2.0281903jes · Cited by 173
Self-citationLi + Solvation and Ionic Transport in Lithium Solvate Ionic Liquids Diluted by Molecular Solvents
Ueno, K., Murai, J., Ikeda, K., Tsuzuki, S., Tsuchiya, M., Tatara, R., Mandai, T., Umebayashi, Y., Dokko, K., & Watanabe, M. (2016) · The Journal of Physical Chemistry C · doi:10.1021/acs.jpcc.5b11642 · Cited by 149
Metadata
- Authors
- von Cresce, A., & Xu, K.
- Venue
- Journal of The Electrochemical Society
- Publisher
- The Electrochemical Society
- Published
- 2011
- Volume
- 158
- Issue
- 3
- Pages
- A337
- ISSN
- 0013-4651 (ISSN-L)
- OpenAlex
- W2061325091
- Cited by
- 227
- References
- 0
- FWCI
- 15.82
- Type
- journal article
- Language
- en
- Open access
- bronze
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