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Enhancement on Cycle Performance of Zn Anodes by Activated Carbon Modification for Neutral Rechargeable Zinc Ion Batteries

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Li, Hongfei, Xu, Chengjun, Han, Cuiping, Chen, Yanyi, Wei, Chunguang, Li, Baohua, Kang, Feiyu·2015·Journal of The Electrochemical Society

Abstract

A novel composite anode is prepared by mixing zinc particles with activated carbon (AC) to improve the cycle performance of the neutral rechargeable zinc ion batteries. Galvanostatic charge/discharge cycling tests indicate that the capacity retention of the cell with adding 12 wt% activated carbon in Zn anode is 85.6% after 80 cycles, which is much higher than that of 56.7% for the cell using unmodified Zn anode. X-ray diffraction analysis indicates that the addition of activated carbon can suppress the formation of inactive basic zinc sulfates (Zn 4 SO 4 (OH) 6 · n H 2 0). Morphology, elemental mapping and N 2 adsorption and desorption measurements indicate that the pores of activated carbon can accommodate the deposition of Zn dendrites and insoluble anodic products. As a result, the cycle stability of the Zn anode has been greatly enhanced by activated carbon modification.

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Metadata

Authors
Li, H., Xu, C., Han, C., Chen, Y., Wei, C., Li, B., & Kang, F.
Venue
Journal of The Electrochemical Society
Published
2015
Volume
162
Issue
8
Pages
A1439-A1444
ISSN
  • 0013-4651 (ISSN-L)
  • 1945-7111
OpenAlex
W1542273847
Cited by
212
References
0
FWCI
4.65
Type
journal article
Language
en
Open access
hybrid

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Li, H., Xu, C., Han, C., Chen, Y., Wei, C., Li, B., & Kang, F. (2015). Enhancement on Cycle Performance of Zn Anodes by Activated Carbon Modification for Neutral Rechargeable Zinc Ion Batteries. Journal of The Electrochemical Society. https://doi.org/10.1149/2.0141508jes

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