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Electrochemical Properties of Monoclinic NaNiO2
Open accessAbstract
Monoclinic NaNiO 2 is re-investigated as a positive electrode material for sodium ion batteries. We observe reversible Na extraction and insertion of about 120 mAh/g when NaNiO 2 is cycled between 1.25 V and 3.75 V, though discharge only proceeds to Na 0.91 NiO 2 . The voltage profile shows large and pronounced steps, which are fully reversible. Charging to 4.5 V leads to higher charge and discharge capacity, though with poor coulombic efficiency and rapid capacity fade. X-ray diffraction of charged samples indicates that high voltage charging leads to the formation of an inactive phase.
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Cited by
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Han, M. H., Gonzalo, E., Singh, G., & Rojo, T. (2015) · Energy & Environmental Science · doi:10.1039/c4ee03192j · Cited by 1,380
Update on Na-based battery materials. A growing research path
Palomares, V., Casas-Cabanas, M., Castillo-Martínez, E., Han, M. H., & Rojo, T. (2013) · Energy & Environmental Science · doi:10.1039/c3ee41031e · Cited by 992
Compatibility issues between electrodes and electrolytes in solid-state batteries
Tian, Y., Shi, T., Richards, W. D., Li, J., Kim, J. C., Bo, S.-H., & Ceder, G. (2017) · Energy & Environmental Science · doi:10.1039/c7ee00534b · Cited by 396
Self-citationPark, Y., Seo, D., Kim, H., Kim, J., Lee, S., Kim, B., & Kang, K. (2014) · Advanced Functional Materials · doi:10.1002/adfm.201400561 · Cited by 351
Wang, T., Su, D., Shanmukaraj, D., Rojo, T., Armand, M., & Wang, G. (2018) · Electrochemical Energy Reviews · doi:10.1007/s41918-018-0009-9 · Cited by 328
Metadata
- Authors
- Vassilaras, P., Ma, X., Li, X., & Ceder, G.
- Venue
- Journal of The Electrochemical Society
- Publisher
- The Electrochemical Society
- Published
- 2012-11-29
- Volume
- 160
- Issue
- 2
- Pages
- A207-A211
- ISSN
- 0013-4651 (ISSN-L)
- 1945-7111
- OpenAlex
- W4241222571
- Cited by
- 316
- References
- 0
- FWCI
- 11.60
- Type
- journal article
- Language
- en
- Open access
- bronze
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