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Perspective—Fluorinating Interphases
Open accessAbstract
Electrode/electrolyte interphase in Li-ion batteries is a critical component that ensures reversible cell reactions far from thermodynamic equilibria. The desired chemical composition and morphology for such interphase, however, remain controversial. Recent advances in battery chemistries and their electrolytes demonstrated that the presence of fluorine in the interphase, either in the form of simple inorganic fluorides (LiF) or organofluoro-moieties, brought positive impacts on the electrochemical performances. Beside the identification of chemical composition, understanding how these fluorinated species exists and distribute in the interphase might constitute the key know-how for the next generation battery chemistries. This is a topic that the battery research community should focus their attention on.
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“Strangely, the signature of Li fluoride (LiF) lattice was not detected, even though LiF is considered to be a primary reason for performance enhancement [162].”
From Review on Low-Temperature Electrolytes for Lithium-Ion and Lithium Metal Batteries (2023) · cites this paper as [162]
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Metadata
- Authors
- Wang, C., Meng, Y. S., & Xu, K.
- Affiliations
- University of Maryland, College Park (US)
- University of California San Diego (US)
- DEVCOM Army Research Laboratory (US)
- Venue
- Journal of The Electrochemical Society
- Publisher
- The Electrochemical Society
- Published
- 2018-12-18
- Volume
- 166
- Issue
- 3
- Pages
- A5184-A5186
- ISSN
- 0013-4651 (ISSN-L)
- 1945-7111
- OpenAlex
- W2905440981
- Cited by
- 173
- References
- 35
- Citations by year
- 2026: 8 · 2025: 22 · 2024: 21 · 2023: 26 · 2022: 25 · 2021: 21 · 2020: 33 · 2019: 17
- FWCI
- 6.79
- Type
- journal article
- Language
- en
- Open access
- hybrid
- doi.org
- Locations
- Journal of The Electrochemical Society (publishedVersion, cc-by)
- OSTI OAI (U.S. Department of Energy Office of Scientific and Technical Information) (submittedVersion)
- Funders
- US DOE
- Topics
- Physical Sciences › Engineering › Electrical and Electronic Engineering › Advancements in Battery Materials
- Physical Sciences › Engineering › Electrical and Electronic Engineering › Advanced Battery Materials and Technologies
- Physical Sciences › Engineering › Automotive Engineering › Battery Modeling and Management
- Keywords
- electrode-electrolyte interphase, lithium-ion batteries, fluorination, lithium fluoride, organofluorine compounds
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