A LiMn2O4-Polypyrrole System for the Extraction of LiCl from Natural Brine
Open accessAbstract
A highly selective LiMn 2 O 4 -Polypyrrole electrochemical cell for the extraction of LiCl from natural brine is described. Reproducible intercalation of Li + in Li x Mn 2 O 4 (0 ≤ x ≤ 1) and Cl − in oxidized polypyrrole (PPy + ) is achieved with an overall cell voltage of less 1 V over more than 200 cycles with 50% charge efficiency and 5–10 Wh.mol −1 energy consumption. No insertion of Na + has been observed.
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Calvo et al. demonstrated excellent cycling ability of electrochemical systems for lithium recovery, with stability of the electrodes and the lithium capturing ability maintained for over 200 cycles.
“Calvo et al. were the only ones to demonstrate the excellent cycling ability of electrochemical systems for lithium recovery, with stability of the electrodes and the lithium capturing ability maintained for over 200 cycles.”
From Lithium recovery from brines: A vital raw material for green energies with a potential environmental impact in its mining and processing (2018) · cites this paper as Missoni et al., 2016
Experiments performed on real brine samples yield much more light on the potential real applications of any new recovery technology.
“Therefore, experiments performed on real brine samples (Chitrakar et al., 2012; Chitrakar et al., 2014; Marchini et al., 2016; Missoni et al., 2016) yield much more light on the potential real applications of any new recovery technology.”
From Lithium recovery from brines: A vital raw material for green energies with a potential environmental impact in its mining and processing (2018) · cites this paper as Missoni et al., 2016
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References 29 · Cited by 103
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- H. Kanoh, K. Ooi, Y. Miyai, and S. Katoh, Langmuir, 7, 1841 (1991). · DOI
- H. Kanoh, K. Ooi, Y. Miyai, and S. Katoh, Separation Science and Technology, 28, 643 (1993). · DOI
- H. Kanoh, Q. Feng, T. Hirotsu, and K. Ooi, Journal of the Electrochemical Society, 143, 2610 (1996). · DOI
- H. Kanoh, Q. Feng, Y. Miyai, and K. Ooi, Journal of the Electrochemical Society, 142, 702 (1995). · DOI
- R. Trocoli, A. Battistel, and F. La Mantia, Chemistry-a European Journal, 20, 9888 (2014). · DOI · Paper page
- J. Lee, S. Kim, C. Kim, and J. Yoon, Energy & Environmental Science, 7, 3683 (2014). · DOI
- S. Kim, J. Lee, J. S. Kang, K. Jo, S. Kim, Y.-E. Sung, and J. Yoon, Chemosphere, 125, 50 (2015). · DOI · Paper page
- J. S. Kim, Y. H. Lee, S. Choi, J. Shin, H. C. Dinh, and J. W. Choi, Environmental Science and Technology, 49, 9415 (2015). · DOI
- T. Hoshino, Fusion Engineering and Design, 88, 2956 (2013). · DOI
- T. Hoshino, in ECS Transactions, p. 173 (2013).
- N. Intaranont, N. Garcia-Araez, A. L. Hector, J. A. Milton, and J. R. Owen, Journal of Materials Chemistry A, 2, 6374 (2014). · DOI
- X. Liu, X. Chen, Z. Zhao, and X. Liang, Hydrometallurgy, 146, 24 (2014). · DOI
- D. Guyomard and J. M. Tarascon, Journal of the Electrochemical Society, 140, 3071 (1993). · DOI
- J. M. Tarascon and D. Guyomard, Journal of the Electrochemical Society, 138, 2864 (1991). · DOI
- M. Rossouw, A. de Kock, L. de Picciotto, M. Thackeray, W. David, and R. Ibberson, Materials Research Bulletin, 25, 173 (1990). · DOI
- K. Ooi, Y. Miyai, S. Katoh, H. Maeda, and M. Abe, Langmuir, 5, 150 (1989). · DOI
- S. W. Feldberg, Journal of the American Chemical Society, 106, 4671 (1984). · DOI
- A. Rougier, K. A. Striebel, S. J. Wen, and E. J. Cairns, Journal of the Electrochemical Society, 145, 2975 (1998). · DOI
- F. K. Shokoohi, J. M. Tarascon, B. J. Wilkens, D. Guyomard, and C. C. Chang, Journal of the Electrochemical Society, 139, 1845 (1992). · DOI
- F. Marchini, S. Herrera, W. Torres, A. Y. Tesio, F. J. Williams, and E. J. Calvo, Langmuir, 31, 9236 (2015). · DOI
- D. Guyomard and J. M. Tarascon, Advanced Materials, 6, 408 (1994). · DOI
- C. Weidlich, K. M. Mangold, and K. Jüttner, Electrochimica Acta, 50, 1547 (2005). · DOI
- S. Bruckenstein, J. Chen, I. Jureviciute, and A. R. Hillman, Electrochimica Acta, 54, 3516 (2009). · DOI
- L. Yang, J. T. Frith, N. Garcia-Araez, and J. R. Owen, Chemical Communications, 51, 1705 (2015). · DOI
- X. Q. Yang, X. Sun, S. J. Lee, J. McBreen, S. Mukerjee, M. L. Daroux, and X. K. Xing, Electrochemical and Solid State Letters, 2, 157 (1999). · DOI
- Authors
- Missoni, L. L., Marchini, F., del Pozo, M., & Calvo, E. J.
- Affiliations
- Universidad de Buenos Aires (AR)
- Venue
- Journal of The Electrochemical Society
- Publisher
- The Electrochemical Society
- Published
- 2016
- Volume
- 163
- Issue
- 9
- Pages
- A1898-A1902
- ISSN
- 0013-4651 (ISSN-L)
- 1945-7111
- OpenAlex
- W2474068305
- Cited by
- 103
- References
- 29
- Citations by year
- 2026: 6 · 2025: 11 · 2024: 8 · 2023: 10 · 2022: 13 · 2021: 14 · 2020: 19 · 2019: 9 · 2018: 8 · 2017: 4 · 2016: 1
- FWCI
- 3.38
- Type
- journal article
- Language
- en
- Open access
- bronze
- doi.org
- Locations
- Journal of The Electrochemical Society (publishedVersion)
- Conicet (submittedVersion, cc-by-nc-sa)
- Funders
- Consejo Nacional de Investigaciones Científicas y Técnicas
- Agencia Nacional de Promoción Científica y Tecnológica (PICT-2012, CONICET)
- Topics
- Physical Sciences › Engineering › Electrical and Electronic Engineering › Advancements in Battery Materials
- Physical Sciences › Engineering › Mechanical Engineering › Extraction and Separation Processes
- Physical Sciences › Chemical Engineering › Fluid Flow and Transfer Processes › Molten salt chemistry and electrochemical processes
- Keywords
- LiMn2O4, polypyrrole, natural brines, lithium recovery, electrochemical intercalation, lithium intercalation, lithium-ion battery cathodes, selective ion extraction, energy consumption
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