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Mixed magnesium-aluminiun hydroxides. I. Preparation and characterization of compounds formed in dialysed systems
Open accessAbstract
The materials formed by dialysis of the precipitates formed by the reaction of NaOH with mixed Mg-Al solutions are described. In addition to aluminium and magnesium hydroxides, two hydrocarbonates having Mg/Al ratios of about 5 : 1 and 2 : 1 are formed, essentially pure, from solutions with Mg/Mg + Al molar ratios of 0.8 and 0.7, respectively. X-ray powder data shows that they have partially ordered hexagonal layer structures with unit layer dimensions a = 3.048 Å, layer thickness 7.60 Å for the Al-rich compound and a = 3.072 Å, layer thickness 7.92 Å for the Al-poor compound. X-ray and chemical data show that the new compounds resemble the minerals hydrotalcite and manasseite and also the compounds described as Mg-Al hydroxides by Feitknecht.
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Citations
Cited by
Hydration products of alkali activated slag cement
Wang, S.-D., & Scrivener, K. L. (1995) · Cement and Concrete Research · doi:10.1016/0008-8846(95)00045-e · Cited by 997
Physico-Chemical Properties of Synthetic Hydrotalcites in Relation to Composition
Miyata, S. (1980) · Clays and Clay Minerals · doi:10.1346/ccmn.1980.0280107 · Cited by 834
Ke, X., Bernal, S. A., & Provis, J. L. (2017) · Cement and Concrete Research · doi:10.1016/j.cemconres.2017.05.015 · Cited by 375
Ke, X., Bernal, S. A., & Provis, J. L. (2016) · Cement and Concrete Research · doi:10.1016/j.cemconres.2015.11.012 · Cited by 328
Miyata, S., & Okada, A. (1977) · Clays and Clay Minerals · doi:10.1346/ccmn.1977.0250103 · Cited by 316
Metadata
- Authors
- Gastuche, M. C., Brown, G., & Mortland, M. M.
- Venue
- Clay Minerals
- Publisher
- Mineralogical Society
- Published
- 1967-12
- Volume
- 7
- Issue
- 2
- Pages
- 177-192
- ISSN
- 0009-8558 (ISSN-L)
- 1471-8030
- OpenAlex
- W2002291704
- Cited by
- 189
- References
- 0
- FWCI
- 2.11
- Type
- journal article
- Language
- en
- Open access
- green
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- Gastuche, M. C., Brown, G., & Mortland, M. M. (1967). Mixed magnesium-aluminiun hydroxides. I. Preparation and characterization of compounds formed in dialysed systems. Clay Minerals. https://doi.org/10.1180/claymin.1967.007.2.05
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