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TiO2-graphene oxide nanocomposite as advanced photocatalytic materials
Open accessAbstract
BACKGROUND: Graphene oxide composites with photocatalysts may exhibit better properties than pure photocatalysts via improvement of their textural and electronic properties. RESULTS: TiO2-Graphene Oxide (TiO2 - GO) nanocomposite was prepared by thermal hydrolysis of suspension with graphene oxide (GO) nanosheets and titania peroxo-complex. The characterization of graphene oxide nanosheets was provided by using an atomic force microscope and Raman spectroscopy. The prepared nanocomposites samples were characterized by Brunauer-Emmett-Teller surface area and Barrett-Joiner-Halenda porosity, X-ray Diffraction, Infrared Spectroscopy, Raman Spectroscopy and Transmission Electron Microscopy. UV/VIS diffuse reflectance spectroscopy was employed to estimate band-gap energies. From the TiO2 - GO samples, a 300 μm thin layer on a piece of glass 10×15 cm was created. The photocatalytic activity of the prepared layers was assessed from the kinetics of the photocatalytic degradation of butane in the gas phase. CONCLUSIONS: The best photocatalytic activity under UV was observed for sample denoted TiGO_100 (k = 0.03012 h-1), while sample labeled TiGO_075 (k = 0.00774 h-1) demonstrated the best activity under visible light.
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Cites
Adsorption of Gases in Multimolecular Layers
Brunauer, S., Emmett, P. H., & Teller, E. (1938) · Journal of the American Chemical Society · doi:10.1021/ja01269a023 · Cited by 28,156
Cited by
Hybrid nanostructures based on titanium dioxide for enhanced photocatalysis
Reddy, K. R., Hassan, M., & Gomes, V. G. (2015) · Applied Catalysis A: General · doi:10.1016/j.apcata.2014.10.001 · Cited by 696
Graphene and Graphene Oxide-Based Composites for Removal of Organic Pollutants: A Review
Thakur, K., & Kandasubramanian, B. (2019) · Journal of Chemical & Engineering Data · doi:10.1021/acs.jced.8b01057 · Cited by 469
Ederer, J., Janoš, P., Ecorchard, P., Tolasz, J., Štengl, V., Beneš, H., Perchacz, M., & Pop-Georgievski, O. (2017) · RSC Advances · doi:10.1039/c6ra28745j · Cited by 406
Self-citationDevelopment of novel SiO2–GO nanohybrid/polysulfone membrane with enhanced performance
Wu, H., Tang, B., & Wu, P. (2014) · Journal of Membrane Science · doi:10.1016/j.memsci.2013.09.018 · Cited by 305
Metadata
- Authors
- Štengl, V., Bakardjieva, S., Grygar, T. M., Bludská, J., & Kormunda, M.
- Venue
- Chemistry Central Journal
- Published
- 2013-02-27
- Volume
- 7
- Issue
- 1
- Pages
- 41-41
- ISSN
- 1752-153X (ISSN-L)
- OpenAlex
- W2154674654
- Cited by
- 276
- References
- 1
- FWCI
- 7.93
- Type
- journal article
- Language
- en
- Open access
- gold
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- Štengl, V., Bakardjieva, S., Grygar, T. M., Bludská, J., & Kormunda, M. (2013). TiO2-graphene oxide nanocomposite as advanced photocatalytic materials. Chemistry Central Journal. https://doi.org/10.1186/1752-153x-7-41
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