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Designs of Functional π-Electron Materials based on the Characteristic Features of Boron
Open accessAbstract
Boron, a group 13 element, has several characteristic structural and electronic features: 1) trivalent boron compounds usually adopt a trigonal planar geometry; 2) due to the presence of a vacant p-orbital, effective orbital interaction with π-conjugated compounds is possible; 3) the presence of a vacant p-orbital is furthermore responsible for high Lewis acidity; 4) the boryl group acts as a π-electron-accepting group particularly in the excited state. The consequent exploitation of these characteristic features of boron in the molecular design enables us to produce sophisticated π-functional materials with attractive photophysical and electronic properties. This account article illustrates our systematic studies on the molecular design and the development of functional π-electron materials using boron as a key element.
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Cites
BODIPY Dyes and Their Derivatives: Syntheses and Spectroscopic Properties
Loudet, A., & Burgess, K. (2007) · Chemical Reviews · doi:10.1021/cr078381n · Cited by 5,238
Electron Transport Materials for Organic Light-Emitting Diodes
Kulkarni, A. P., Tonzola, C. J., Babel, A., & Jenekhe, S. A. (2004) · Chemistry of Materials · doi:10.1021/cm049473l · Cited by 1,624
Band Gap Control in Conjugated Oligomers via Lewis Acids
Welch, G. C., Coffin, R., Peet, J., & Bazan, G. C. (2009) · Journal of the American Chemical Society · doi:10.1021/ja902789w · Cited by 159
Cited by
Recent developments in and perspectives on three-coordinate boron materials: a bright future
Ji, L., Griesbeck, S., & Marder, T. B. (2017) · Chemical Science · doi:10.1039/c6sc04245g · Cited by 733
Mamada, M., Hayakawa, M., Ochi, J., & Hatakeyama, T. (2024) · Chemical Society Reviews · doi:10.1039/d3cs00837a · Cited by 482
Khan, A. H., Ghosh, S., Pradhan, B., Dalui, A., Shrestha, L. K., Acharya, S., & Ariga, K. (2017) · Bulletin of the Chemical Society of Japan · doi:10.1246/bcsj.20170043 · Cited by 432
Metadata
- Authors
- Wakamiya, A., & Yamaguchi, S.
- Venue
- Bulletin of the Chemical Society of Japan
- Publisher
- Oxford University Press (OUP)
- Published
- 2015-05-27
- Volume
- 88
- Issue
- 10
- Pages
- 1357-1377
- ISSN
- 0009-2673 (ISSN-L)
- 1348-0634
- OpenAlex
- W1909050858
- Cited by
- 257
- References
- 3
- FWCI
- 11.99
- Type
- journal article
- Language
- en
- Open access
- bronze
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- Wakamiya, A., & Yamaguchi, S. (2015). Designs of Functional π-Electron Materials based on the Characteristic Features of Boron. Bulletin of the Chemical Society of Japan. https://doi.org/10.1246/bcsj.20150151
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