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Designs of Functional π-Electron Materials based on the Characteristic Features of Boron

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Wakamiya, Atsushi, Yamaguchi, Shigehiro·2015·Bulletin of the Chemical Society of Japan

Abstract

Boron, a group 13 element, has several characteristic structural and electronic features: 1) trivalent boron compounds usually adopt a trigonal planar geometry; 2) due to the presence of a vacant p-orbital, effective orbital interaction with π-conjugated compounds is possible; 3) the presence of a vacant p-orbital is furthermore responsible for high Lewis acidity; 4) the boryl group acts as a π-electron-accepting group particularly in the excited state. The consequent exploitation of these characteristic features of boron in the molecular design enables us to produce sophisticated π-functional materials with attractive photophysical and electronic properties. This account article illustrates our systematic studies on the molecular design and the development of functional π-electron materials using boron as a key element.

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Metadata

Authors
Wakamiya, A., & Yamaguchi, S.
Venue
Bulletin of the Chemical Society of Japan
Published
2015-05-27
Volume
88
Issue
10
Pages
1357-1377
ISSN
  • 0009-2673 (ISSN-L)
  • 1348-0634
OpenAlex
W1909050858
Cited by
257
References
3
FWCI
11.99
Type
journal article
Language
en
Open access
bronze

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CoChat. (2026). Citation check: Designs of Functional π-Electron Materials based on the Characteristic Features of Boron. https://app.cochat.ai/papers/10.1246/bcsj.20150151
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Wakamiya, A., & Yamaguchi, S. (2015). Designs of Functional π-Electron Materials based on the Characteristic Features of Boron. Bulletin of the Chemical Society of Japan. https://doi.org/10.1246/bcsj.20150151

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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

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