The DOI matches its Crossref record.
A New Hypothesis Regarding the Surface Acidity of Binary Metal Oxides
Abstract
We have proposed a new hypothesis that the acid sites on binary metal oxides are formed by an excess of a negative or positive charge in the mixed oxides and that whether the charge is excess or not, and whether it is positive or negative, are determined by the coordination numbers and valences of the positive and negative elements in the model structures pictured according to two postulates. The validity of the hypothesis is, in fact, 90% for the 31 kinds of binary oxides tested, much higher than the validity (48%) of Thomas’ hypothesis. The hypothesis explains well the mechanism of the acidity generation of binary oxides and predicts whether the acid sites will be of the Brönsted or the Lewis type.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cited by
Specific Poisoning and Characterization of Catalytically Active Oxide Surfaces
Knöuzinger, H. (1976) · Advances in Catalysis · doi:10.1016/s0360-0564(08)60315-6 · Cited by 426
Activation of Carbonyl-Containing Molecules with Solid Lewis Acids in Aqueous Media
Román-Leshkov, Y., & Davis, M. E. (2011) · ACS Catalysis · doi:10.1021/cs200411d · Cited by 401
Zhao, D., Chen, C., Wang, Y., Ma, W., Zhao, J., Rajh, T., & Zang, L. (2008) · Environmental Science & Technology · doi:10.1021/es071770e · Cited by 194
Metadata
- Authors
- Tanabe, K., Sumiyoshi, T., Shibata, K., Kiyoura, T., & Kitagawa, J.
- Venue
- Bulletin of the Chemical Society of Japan
- Publisher
- Oxford University Press (OUP)
- Published
- 1974-05-01
- Volume
- 47
- Issue
- 5
- Pages
- 1064-1066
- ISSN
- 0009-2673 (ISSN-L)
- 1348-0634
- OpenAlex
- W2084554577
- Cited by
- 464
- References
- 0
- FWCI
- 2.65
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
How to cite
Cite CoChat for the checks on this page, and the paper for its own findings.
- This page
- CoChat. (2026). Citation check: A New Hypothesis Regarding the Surface Acidity of Binary Metal Oxides. https://app.cochat.ai/papers/10.1246/bcsj.47.1064
- The paper
- Tanabe, K., Sumiyoshi, T., Shibata, K., Kiyoura, T., & Kitagawa, J. (1974). A New Hypothesis Regarding the Surface Acidity of Binary Metal Oxides. Bulletin of the Chemical Society of Japan. https://doi.org/10.1246/bcsj.47.1064
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
