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Binding Forces Contributing to the Association of Cyclodextrin with Alcohol in an Aqueous Solution
Abstract
The association constants and thermodynamic parameters were determined for complexes of α- and β-cyclodextrins (CD) with a variety of alcohols (ROH) by the spectrophotometric examination of the inhibitory effect of ROH on the association of CD with azo dyes, and they were analyzed in connection with the partition coefficients of ROH in a diethyl ether–water solvent system in order to elucidate the binding forces contributing to the association of CD with an organic substrate. Hydrophobic and van der Waals interactions were of primary importance in the complexation. Among them, the latter was preferential in α-CD–1-alkanol adducts, while the former, in β-CD–1-alkanol adducts. As the bulkiness of ROH increased, the stability of the α-CD adduct was lowered owing to van der Waals repulsion between ROH and the relatively small α-CD cavity, whereas that of the β-CD adduct was enhanced by the attainment of the close van der Waals contact of ROH with the relatively large β-CD cavity.
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Citations
Cited by
Complexation Thermodynamics of Cyclodextrins
Rekharsky, M. V., & Inoue, Y. (1998) · Chemical Reviews · doi:10.1021/cr970015o · Cited by 3,199
Goubet, I., Le Quere, J.-L., & Voilley, A. J. (1998) · Journal of Agricultural and Food Chemistry · doi:10.1021/jf970709y · Cited by 273
High‐Performance Electrocatalysis on Palladium Aerogels
Liu, W., Herrmann, A., Geiger, D., Borchardt, L., Simon, F., Kaskel, S., Gaponik, N., & Eychmüller, A. (2012) · Angewandte Chemie International Edition · doi:10.1002/anie.201108575 · Cited by 217
Inclusion complexes of carotenoids with cyclodextrins: 1HNMR, EPR, and optical studies
Polyakov, N. E., Leshina, T. V., Konovalova, T. A., Hand, E. O., & Kispert, L. D. (2004) · Free Radical Biology and Medicine · doi:10.1016/j.freeradbiomed.2003.12.009 · Cited by 111
Metadata
- Authors
- Matsui, Y., & Mochida, K.
- Venue
- Bulletin of the Chemical Society of Japan
- Publisher
- Oxford University Press (OUP)
- Published
- 1979-10-01
- Volume
- 52
- Issue
- 10
- Pages
- 2808-2814
- ISSN
- 0009-2673 (ISSN-L)
- 1348-0634
- OpenAlex
- W1996070717
- Cited by
- 380
- References
- 0
- FWCI
- 2.83
- Type
- journal article
- Language
- en
- Open access
- closed
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- Matsui, Y., & Mochida, K. (1979). Binding Forces Contributing to the Association of Cyclodextrin with Alcohol in an Aqueous Solution. Bulletin of the Chemical Society of Japan. https://doi.org/10.1246/bcsj.52.2808
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