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Towards An Understanding of the Mechanism of Electron-Capture Dissociation: A Historical Perspective and Modern Ideas
Abstract
Electron-capture dissociation (ECD) is a new fragmentation technique that utilizes ion–electron recombination reactions. The latter have parallels in other research fields; revealing these parallels helps to understand the ECD mechanism. An overview is given of ECD-related phenomena and of the history of ECD discovery and development. Current views on the ECD mechanism are discussed using both published and new examples.
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Cited by
Peptide and protein sequence analysis by electron transfer dissociation mass spectrometry
Syka, J. E. P., Coon, J. J., Schroeder, M. J., Shabanowitz, J., & Hunt, D. F. (2004) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.0402700101 · Cited by 2,370
Top Down proteomics: Facts and perspectives
Catherman, A. D., Skinner, O. S., & Kelleher, N. L. (2014) · Biochemical and Biophysical Research Communications · doi:10.1016/j.bbrc.2014.02.041 · Cited by 507
“CID and other collisional methods are based upon vibrational excitation, where vibrational energy can be distributed throughout the molecule, often causing the fragmentation of the weakest bonds [86].”
BackgroundSimons, J. (2008) · The Journal of Physical Chemistry A · doi:10.1021/jp711490b · Cited by 417
Fragmentation of Integral Membrane Proteins in the Gas Phase
Skinner, O. S., Catherman, A. D., Early, B. P., Thomas, P. M., Compton, P. D., & Kelleher, N. L. (2014) · Analytical Chemistry · doi:10.1021/ac500864w · Cited by 29
Metadata
- Authors
- Zubarev, R. A., Haselmann, K. F., Budnik, B., Kjeldsen, F., & Jensen, F.
- Venue
- European Journal of Mass Spectrometry
- Publisher
- SAGE Publications
- Published
- 2002-10
- Volume
- 8
- Issue
- 5
- Pages
- 337-349
- ISSN
- 1356-1049 (ISSN-L)
- 1469-0667
- 1751-6838
- OpenAlex
- W2081620687
- Cited by
- 248
- References
- 0
- FWCI
- 7.10
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: Towards An Understanding of the Mechanism of Electron-Capture Dissociation: A Historical Perspective and Modern Ideas. https://app.cochat.ai/papers/10.1255/ejms.517
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- Zubarev, R. A., Haselmann, K. F., Budnik, B., Kjeldsen, F., & Jensen, F. (2002). Towards An Understanding of the Mechanism of Electron-Capture Dissociation: A Historical Perspective and Modern Ideas. European Journal of Mass Spectrometry. https://doi.org/10.1255/ejms.517
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