The DOI matches its Crossref record.
Cu2+-Adsorption Characteristics of Aluminum Hydroxide and Oxyhydroxides
Abstract
The nature of Cu 2+ adsorption by boehmite, gibbsite, and noncrystalline alumina was studied over a range of equilibrium pH (4.5–7.5) and Cu 2+ concentration (10−3–10−8 M) by electron spin resonance (ESR). Available chemisorption sites at pH 4.5 were the most numerous for noncrystalline alumina (~1 mmole/100 g), less for boehmite, and least for gibbsite as indicated by the relative strength of the rigid-limit ESR signal attributed to Cu 2+ adsorbed at discrete sites. The chemisorption process involved immobilization of Cu 2+ by displacement of one or more H 2 O ligands by hydroxyl or surface oxygen ions, with the formation of at least one Cu-O-Al bond. As the pH was raised from 4.5 to 6.0, essentially all of the solution Cu 2+ appeared to be adsorbed by the solids. However, the noncrystalline alumina and boehmite chemisorbed much of the total adsorbed Cu 2+ (10 mmole/100 g), whereas precipitation or nucleation of Cu(OH)2 in the gibbsite system was indicated. Precipitated Cu 2+ was more readily redissolved by exposure to NH 3 vapor than chemisorbed Cu 2+.
Overview
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
Claims other papers make about this one
Each is checked against this paper’s own text: does it say what the citing paper says it does?
In the citing paper
“Experiments with various synthetic Fe, Al and Mn oxides showed that the affinity of trace elements for Mn oxide was usually much greater than that for Fe or Al oxides.”
From MOBILITY AND BIOAVAILABILITY OF HEAVY METALS AND METALLOIDS IN SOIL ENVIRONMENTS (2010) · cites this paper as McBride, 1982
Citations
Cites
No references could be resolved yet.
Research works printed but not linked: 17
- 10.1021/j100502a021 · DOI
- Baes, 1976, The Hydrolysis of Cations
- 10.1021/j100621a010 · DOI
- 10.2136/sssaj1978.03615995004200010007x · DOI
- 10.1111/j.1365-2389.1977.tb02294.x · DOI
- 10.1111/j.1365-2389.1976.tb01986.x · DOI
- 10.1021/ba-1968-0073.ch021 · DOI
- 10.1097/00010694-197901000-00002 · DOI
- Nalovic, 1975, Proc. Int. Clay Conf., Mexico City, 1975, 601
- 10.1063/1.1727057 · DOI
- 10.1021/j100589a018 · DOI
- 10.1063/1.1695780 · DOI
- 10.1346/CCMN.1977.0250102 · DOI
- 10.1021/j100455a020 · DOI
- 10.1063/1.1731880 · DOI
- Parfitt, 1978, Anion adsorption by soils and soil materials, Adv. Agron., 30, 1
- 10.2136/sssaj1976.03615995004000050047x · DOI · Paper page
Cited by
Sorted by citations
MOBILITY AND BIOAVAILABILITY OF HEAVY METALS AND METALLOIDS IN SOIL ENVIRONMENTS
Violante, A., Cozzolino, V, Perelomov, L., Caporale, A. G., & Pigna, M. (2010) · Journal of Soil Science and Plant Nutrition · doi:10.4067/s0718-95162010000100005 · Cited by 957
“…size of the crystals, surface charge of metal oxides and mixed metal oxides (e.g., FeAl oxides) also play an important role in the sorption selectivity of trace elements in cationic form (Kinniburg and Jackson, 1976; McBride, 1982; Violante et al., 2003; Sparks, 2003; Violante et al., 2008).”
BackgroundThe Environmental Chemistry of Aluminum
Sposito, G. (1995) · Choice Reviews Online · doi:10.5860/choice.33-5716 · Cited by 710
Reactions Controlling Heavy Metal Solubility in Soils
McBride, M. B. (1989) · Advances in soil science · doi:10.1007/978-1-4613-8847-0_1 · Cited by 692
Self-citationRole of Metal-Organic complexation in metal sorption by Soils
Harter, R. D., & Naidu, R. (1995) · Advances in agronomy · doi:10.1016/s0065-2113(08)60541-6 · Cited by 281
Brown, G. E., & Parks, G. A. (2001) · International Geology Review · doi:10.1080/00206810109465060 · Cited by 257
Aluminum Hydroxides and Oxyhydroxides
Hsu, P. H. (1989) · SSSA Book Series · doi:10.2136/sssabookser1.2ed.c7 · Cited by 231
Chlorites and Hydroxy‐Interlayered Vermiculite and Smectite
Barnhisel, R. I., & Bertsch, P. M. (1989) · Soil Science Society of America book series · doi:10.2136/sssabookser1.2ed.c15 · Cited by 431
“significantly greater than the amount of Cu adsorbed to noncrystalline alumina and microcrystalline gibbsite (McBride, 1982; McBride et aI., 1984) and led to the speculation that AUOHW~Y interlayer components had a greater specific surface than discrete All0HW~Y phases, perhaps resulting from the "atoll" -like distrib…”
BackgroundMeima, J. A., van der Weijden, R. D., Eighmy, T. T., & Comans, R. N. J. (2002) · Applied Geochemistry · doi:10.1016/s0883-2927(02)00015-x · Cited by 207
Kim, T., Kim, T.-K., & Zoh, K. (2019) · Journal of Water Process Engineering · doi:10.1016/j.jwpe.2019.101109 · Cited by 208
Lee, S.-M., Laldawngliana, C., & Tiwari, D. (2012) · Chemical Engineering Journal · doi:10.1016/j.cej.2012.04.075 · Cited by 179
An assemblage model for cation binding by natural particulate matter
Lofts, S., & Tipping, E. (1998) · Geochimica et Cosmochimica Acta · doi:10.1016/s0016-7037(98)00183-5 · Cited by 162
A CRITICAL ASSESSMENT OF SORPTION-DESORPTION MECHANISMS AT THE SOIL MINERAL/WATER INTERFACE
Scheidegger, A., & Sparks, D. (1996) · Soil Science · doi:10.1097/00010694-199612000-00002 · Cited by 160
Thompson, H. A., Parks, G. A., & Brown, G. E. (1999) · Geochimica et Cosmochimica Acta · doi:10.1016/s0016-7037(99)00125-8 · Cited by 125
Yan, Z., Yang, H.-M., Ouyang, J., et al. (2017) · doi:10.1016/j.cej.2017.02.043 · Cited by 118
Spectroscopic investigation of Pb(II) complexes at the γ-Al2O3/water interface
Chisholm-Brause, C. J., Hayes, K. F., Roe, A. L., Brown, G. E., Parks, G. A., & Leckie, J. O. (1990) · Geochimica et Cosmochimica Acta · doi:10.1016/0016-7037(90)90260-r · Cited by 114
Application of Electron Spin Resonance (ESR) Spectroscopy in Soil Chemistry
Senesi, N. (1990) · Advances in soil science · doi:10.1007/978-1-4612-3356-5_3 · Cited by 113
EDTA modified LDHs as Cu2+ scavengers: removal kinetics and sorbent stability.
Rojas, R., Perez, M. R., Erro, E. M., et al. (2009) · Journal of Colloid and Interface Science · doi:10.1016/j.jcis.2008.11.045 · Cited by 98
Copper Sorption Mechanisms on Smectites
Strawn, D. G., Palmer, N. E., Furnare, L. J., Goodell, C., Amonette, J. E., & Kukkadapu, R. (2004) · Clays and Clay Minerals · doi:10.1346/ccmn.2004.0520307 · Cited by 88
Cheah, S., Brown, G. E., & Parks, G. A. (1998) · Journal of Colloid and Interface Science · doi:10.1006/jcis.1998.5678 · Cited by 87
Kulik, D. (2002) · American Journal of Science · doi:10.2475/ajs.302.3.227 · Cited by 82
“Similar phenomena are known also for Cr III sorption on MnOx ,C r III on FeOOH, and Cu sorption on Al oxides ( McBride, 1982; Karthikeyan and others, 1997).”
BackgroundThe Surface Chemistry of Aluminum Oxides and Hydroxides
Goldberg, S., Davis, J. A., & Hem, J. D. (2020) · CRC Press eBooks · doi:10.1201/9780138736781-7 · Cited by 57
Chemisorption of Cu(II) and Co(II) on Allophane and Imogolite
Clark, C. J., & McBride, M. B. (1984) · doi:10.1346/ccmn.1984.0320408 · Cited by 66
“Exposure of moist samples to ammonia vapor following Cu 2§ adsorption permitted the "availability" of adsorbed Cu for ligand exchange to be assessed ( McBride, 1982 ), because the coordination of NH3 to Cu 2§ greatly shifts the ESR parameters.”
BackgroundMethodInfluentialSelf-citationŠljivić-Ivanović, M. Z., Smičiklas, I. D., Plećaš, I. B., & Mitrić, M. N. (2008) · Chemical Engineering Journal · doi:10.1016/j.cej.2008.08.003 · Cited by 64
Cu2+ Interaction with Microcrystalline Gibbsite. Evidence for Oriented Chemisorbed Copper Ions
McBride, M. B., Fraser, A. R., & McHardy, W. J. (1984) · Clays and Clay Minerals · doi:10.1346/ccmn.1984.0320102 · Cited by 70
“Recent electron spin resonance (ESR) studies ofCu 2+alumina systems have revealed that noncrystalline AI(OH)3 and microcrystalline A1OOH chemisorb Cu 2+ at isolated bonding sites, probably by the formation of one or two direct bonds between surface A1-O groups and Cu 2+ ( McBride, 1982a ).”
BackgroundInfluentialSelf-citationCheah, S.-F., Brown, G. E., & Parks, G. A. (2000) · American Mineralogist · doi:10.2138/am-2000-0113 · Cited by 63
“Several studies used EPR, XAFS, and magnetic susceptibility measurements to investigate Cu2+ sorption on different oxides and mica (McBride 1982; Motschi 1984; Farquhar et al. 1996; Xia et al. 1997, 1998).”
MethodAging of coprecipitated Cu in alumina: changes in structural location, chemical form, and solubility
Martínez, C., & McBride, M. (2000) · doi:10.1016/s0016-7037(00)00344-6 · Cited by 54
Self-citationSurface Complexation Modeling of Copper Sorption by Hydrous Oxides of Iron and Aluminum.
Karthikeyan, K., & Elliott, H. (1999) · Journal of Colloid and Interface Science · doi:10.1006/jcis.1999.6507 · Cited by 52
The chemistry of adsorbed Cu(II) and Mn(II) in aqueous titanium dioxide suspensions
Bleam, W. F., & McBride, M. B. (1986) · Journal of Colloid and Interface Science · doi:10.1016/0021-9797(86)90388-7 · Cited by 62
Self-citationComplexation of copper with polymeric silica in aqueous solution
Yates, D., Joyce, K. J., & Heaney, P. (1998) · doi:10.1016/s0883-2927(97)00062-0 · Cited by 44
Mondillo, N., Balassone, G., Boni, M., et al. (2019) · Minerals · doi:10.3390/min9090504 · Cited by 42
Sorption of Metal Ions on Alumina
Baumgarten, E., & Kirchhausen-Düsing, U. (1997) · Journal of Colloid and Interface Science · doi:10.1006/jcis.1997.5085 · Cited by 43
Effect of accelerated carbonation and zero valent iron on metal leaching from bottom ash
Nilsson, M., Andreas, L., & Lagerkvist, A. (2016) · Waste Management · doi:10.1016/j.wasman.2015.12.028 · Cited by 43
Surface complexation modeling of cadmium adsorption on gibbsite
Weerasooriya, R., Wijesekara, H., & Bandara, A. (2002) · doi:10.1016/s0927-7757(02)00004-3 · Cited by 39
Olguín, M., Solache-Ríos, M., Acosta, D., et al. (1997) · Journal of Radioanalytical and Nuclear Chemistry · doi:10.1007/bf02033975 · Cited by 38
Effect of low concentration hydroxides on Al hydrolysis for hydrogen production
Gai, W.-Z., Wang, L.-Y., Lu, M., et al. (2023) · Energy · doi:10.1016/j.energy.2023.126731 · Cited by 37
Adsorption of Heavy Metals by Clay-Aluminum Hydroxide Complexes
Keizer, P., & Bruggenwert, M. G. M. (1991) · Springer eBooks · doi:10.1007/978-94-017-1909-4_6 · Cited by 39
Influence of Glycine on Cu2+ Adsorption by Microcrystalline Gibbsite and Boehmite
McBride, M. B. (1985) · Clays and Clay Minerals · doi:10.1346/ccmn.1985.0330504 · Cited by 35
“face-A1OOH groups per unit of surface area ( McBride, 1982 ).”
BackgroundSelf-citationWeesner, F., & Bleam, W. (1997) · Journal of Colloid and Interface Science · doi:10.1006/jcis.1997.5190 · Cited by 33
A study of the factors controlling the adsorption of Cr(III) on modified montmorillonites
Bakhti, A., Derriche, Z., Iddou, A., et al. (2001) · doi:10.1046/j.1365-2389.2001.00413.x · Cited by 30
Retention of copper by desert sands coated with ferric hydroxides
Al-Sewailem, M., Khaled, E. M., & Mashhady, A. S. (1999) · doi:10.1016/s0016-7061(98)00082-2 · Cited by 30
Zinc(II) adsorption on aluminium hydroxide
Micera, G., Gessa, C., Melis, P., et al. (1986) · doi:10.1016/0166-6622(86)80261-x · Cited by 30
Modeling Adsorption of Metals and Metalloids by Soil Components
Goldberg, S., & Criscenti, L. (2007) · Wiley eBooks · doi:10.1002/9780470175484.ch6 · Cited by 26
Anion-induced metal binding in amorphous aluminium hydroxide
Gessa, C., Cherchi, M. L. D., Melis, P., et al. (1984) · doi:10.1016/0166-6622(84)80239-5 · Cited by 25
Du, H., Huang, Q., Zhou, M., Tie, B., Lei, M., Wei, X., Liu, X., & Yang, Y. (2018) · Chemical Geology · doi:10.1016/j.chemgeo.2018.09.026 · Cited by 29
NMR relaxometry for adsorption studies: Proof of concept with copper adsorption on activated alumina
Gossuin, Y., & Vuong, Q. (2018) · Separation and Purification Technology · doi:10.1016/j.seppur.2018.03.051 · Cited by 23
Martin, R. (1990) · doi:10.1007/978-94-009-1868-9_2 · Cited by 23
Abeysinghe, S., Corum, K. W., Neff, D., et al. (2013) · Langmuir · doi:10.1021/la402736t · Cited by 22
Organic Anion Adsorption on Aluminum Hydroxides: Spin Probe Studies
McBride, M. B. (1982) · doi:10.1346/ccmn.1982.0300606 · Cited by 22
Self-citationGuilherme, L. R. G., & Anderson, S. (1998) · doi:10.1016/b978-012384245-9/50010-4 · Cited by 22
Ternary [Al(2)O(3)-electrolyte-Cu(2+)] species: EPR spectroscopy and surface complexation modeling.
Papadas, I., Kosma, C., & Deligiannakis, Y. (2009) · Journal of Colloid and Interface Science · doi:10.1016/j.jcis.2009.07.008 · Cited by 19
Ikoma, S., Kawakita, K., & Yokoi, H. (1990) · doi:10.1016/0022-3093(90)91064-x · Cited by 19
Xia, K., Taylor, R., Bleam, W., et al. (1998) · doi:10.1006/jcis.1997.5351 · Cited by 17
X-Ray Absorption Fine Structure Spectroscopy
Fendorf, S., & Sparks, D. (1996) · SSSA Book Series · doi:10.2136/sssabookser5.3.c13 · Cited by 17
Chemisorption of Copper on Hydroxy-Aluminum-Hectorite: An Electron Spin Resonance Study
Harsh, J., Doner, H., & McBride, M. B. (1984) · doi:10.1346/ccmn.1984.0320509 · Cited by 15
Self-citationCOK‐16: A Cation‐Exchanging Metal–Organic Framework Hybrid
Bajpe, S., Breynaert, E., Martín-Calvo, A., et al. (2013) · doi:10.1002/cplu.201300080 · Cited by 14
Trace elements adsorption by natural and chemically modified humic acids
Perelomov, L., Sarkar, B., Pinsky, D., et al. (2020) · Environmental Geochemistry and Health · doi:10.1007/s10653-020-00686-0 · Cited by 13
“Similarly, McBride (1982) investigating the interaction of Cu2? with HA by the same EPR method indicated that Cu2? formed a complex with oxygen ligands, and the –”
BackgroundEstablishing trends in ion adsorption on the aqueous aluminium hydroxide nanoparticle Al30
Corum, K. W., & Mason, S. (2015) · doi:10.1080/08927022.2014.895001 · Cited by 11
“[25] Some studies have found thatwhenbound to alumina,Cu2þ loses twoof its water ligands and forms a square planar coordination only, [24] so the existence of water ligands in the axial positions is up for debate.”
BackgroundFundamental Aspects and Applications of X-Ray Absorption Spectroscopy in Clay and Soil Sciences
Fendorf, S. E. (1999) · Clay Minerals Society eBooks · doi:10.1346/cms-wls-9.2 · Cited by 13
Chatterjee, M., Iwasaki, T., Onodera, Y., et al. (2004) · doi:10.1016/j.clay.2003.11.003 · Cited by 10
Baumer, T., & Hixon, A. (2018) · Journal of Environmental Radioactivity · doi:10.1016/j.jenvrad.2018.09.004 · Cited by 9
Sorption of microamounts of Ce3+, Pm3+, Eu3+, Gd3+ and Yb3+ on aluminium hydroxide
Musić, S. (1986) · doi:10.1007/bf02060836 · Cited by 9
Surface Chemistry of Soil Minerals
McBride, M. B. (2018) · doi:10.2136/sssabookser1.2ed.c2 · Cited by 6
Self-citationAn EPR study of Cu adsorption by clinoptilolite from Cl−, NO3− and SO42− solutions
Doula, M., & Dimirkou, A. (2008) · doi:10.1007/s10934-007-9102-x · Cited by 5
Terzano, R., Cuccovillo, G., Pascazio, S., et al. (2016) · Biology and Fertility of Soils · doi:10.1007/s00374-016-1164-y · Cited by 5
“Concurrently to the Al-(hydr)oxides formation, Cu ions can be also removed from solution, being trapped in the Al-(hydr)oxide precipitates through a process named coprecipitation (McBride 1982; Martinez and McBride 2000).”
BackgroundPampinella, D., Laudicina, V. A., Saiano, F., et al. (2024) · Water · doi:10.3390/w16081112 · Cited by 4
Baumer, T. M., & Hixon, A. E. (2019) · Journal of Environmental Radioactivity · doi:10.1016/j.jenvrad.2019.05.006 · Cited by 4
Rida, K., Goutas, W., & Medjetena, I. (2012) · doi:10.1002/cjce.20566 · Cited by 4
Tazaki, K., Lindenmayer, Z., & Fyfe, W. (1988) · doi:10.1016/0009-2541(88)90134-9 · Cited by 4
(2012) · doi:10.1007/978-94-007-4177-5_7 · Cited by 3
Ronzhin, N., Posokhina, E., Mikhlina, E., et al. (2022) · Journal of Physics and Chemistry of Solids · doi:10.1016/j.jpcs.2022.110785 · Cited by 2
Lavrent’eva, G., Kruglov, S., & Anisimov, V. (2008) · doi:10.1134/s106422930809007x · Cited by 2
“The adsorption of HM cations by the solid phase also results in the release of protons [6, 25 , 28], although other mechanisms (including, e.g., the hydrolysis of metals [10]) are also proposed to explain the decrease in the pH of the equilibrium solutions.”
BackgroundTortella, G., Rubilar, O., Cea, M., et al. (2019) · Journal of soil science and plant nutrition · doi:10.1007/s42729-019-00037-8 · Cited by 1
Electron Spin (or Paramagnetic) Resonance Spectroscopy
Senesi, N. (2018) · SSSA Book Series · doi:10.2136/sssabookser5.3.c11 · Cited by 1
Application of Spectroscopic Methods to Sorption Model Parameter Estimation
Katz, L. E., & Boyle-Wight, E. J. (2001) · SSSA special publication series · doi:10.2136/sssaspecpub56.c7 · Cited by 5
Harsh, J., & Doner, H. (1985) · doi:10.1346/ccmn.1985.0330515 · Cited by 1
ESR and ESEM Study of Spin Probe Aqueous Solutions Adsorbed on Silica Gel
Romanelli, N., Martini, G., & Kevan, L. (1986) · doi:10.1007/978-1-4615-8521-3_31
Metadata
- Authors
- McBride, M. B.
- Affiliations
- Cornell University (US)
- Corresponding author
- McBride, M. B.
- ORCID
- McBride, M. B.
- Venue
- Clays and Clay Minerals
- Publisher
- Cambridge University Press (CUP)
- Published
- 1982-02
- Volume
- 30
- Issue
- 1
- Pages
- 21-28
- ISSN
- 0009-8604 (ISSN-L)
- 1552-8367
- OpenAlex
- W2095926172
- Semantic Scholar
- 20b9c54b6a95b93073b40e5f17bc92c787d01e2b
- Cited by
- 86
- References
- 0
- Citations by year
- 2026: 2 · 2024: 1 · 2023: 2 · 2022: 2 · 2020: 1 · 2019: 4 · 2018: 3 · 2017: 2 · 2016: 2 · 2014: 2 · 2013: 2 · 2012: 2
- FWCI
- 9.01
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Clays and Clay Minerals (publishedVersion)
- Topics
- Physical Sciences › Environmental Science › Water Science and Technology › Adsorption and biosorption for pollutant removal
- Physical Sciences › Environmental Science › Water Science and Technology › Coagulation and Flocculation Studies
- Physical Sciences › Environmental Science › Water Science and Technology › Environmental and Analytical Chemistry Studies
- Keywords
- copper adsorption, boehmite, gibbsite, aluminum oxyhydroxide, surface hydroxyl groups, pH dependence, copper hydroxide precipitation
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
