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The Influence of Aluminum on Iron Oxides. VIII. Unit-Cell Dimensions of Al-Substituted Goethites and Estimation of Al from them
Abstract
The unit-cell dimensions of synthetic, Al-substituted goethites showed that the c dimension is a linear function of Al substitution in the range 0–33 mole % Al, but that the a dimension is variable over this same range. The b dimension is also linearly related to Al substitution but is slightly more variable than the c dimension for Al substitutions of 20–33 mole %. The variability of the a dimension is postulated to be the result of structural defects. An improved procedure for estimating Al substitution from x-ray powder diffraction positions requires (1) calculation of the c dimension from the positions of the 110 and 111 diffraction lines using the formula: c = (1/d(111)2 − 1/d(110)2)−1/2, and (2) estimation of Al substitution from the relationship: mole % Al = 1730 − 572.0 c. The 95% confidence interval of the estimate is ±2.6 mole % Al when using this procedure, in contrast to ±4.0 mole % Al when the position of the 111 reflection alone is used.
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Cited by
Regolith geology of the Yilgarn Craton, Western Australia: Implications for exploration
Anand, R. R., & Paine, M. (2002) · Australian Journal of Earth Sciences · doi:10.1046/j.1440-0952.2002.00912.x · Cited by 458
Crystal chemistry of trace elements in natural and synthetic goethite
Manceau, A., Schlegel, M. L., Musso, M., Sole, V. A., Gauthier, C., Petit, P. E., & Trolard, F. (2000) · Geochimica et Cosmochimica Acta · doi:10.1016/s0016-7037(00)00427-0 · Cited by 282
The geologic history of seawater oxygen isotopes from marine iron oxides
Galili, N., Shemesh, A., Yam, R., Brailovsky, I., Sela-Adler, M., Schuster, E. M., Collom, C., Bekker, A., Planavsky, N., Macdonald, F. A., et al. (2019) · Science · doi:10.1126/science.aaw9247 · Cited by 128
Metadata
- Authors
- Schulze, D. G.
- Venue
- Clays and Clay Minerals
- Publisher
- Cambridge University Press (CUP)
- Published
- 1984-02
- Volume
- 32
- Issue
- 1
- Pages
- 36-44
- ISSN
- 0009-8604 (ISSN-L)
- 1552-8367
- OpenAlex
- W2116634224
- Cited by
- 389
- References
- 0
- FWCI
- 11.73
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: The Influence of Aluminum on Iron Oxides. VIII. Unit-Cell Dimensions of Al-Substituted Goethites and Estimation of Al from them. https://app.cochat.ai/papers/10.1346/ccmn.1984.0320105
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- Schulze, D. G. (1984). The Influence of Aluminum on Iron Oxides. VIII. Unit-Cell Dimensions of Al-Substituted Goethites and Estimation of Al from them. Clays and Clay Minerals. https://doi.org/10.1346/ccmn.1984.0320105
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