The DOI matches its Crossref record; 9 of the 9 references it cites were found in a registry or an index.
Clay-Organic Complexes as Adsorbents for Phenol and Chlorophenols
Abstract
Several clay-organic complexes were synthesized by placing quaternary ammonium cations on smectite by cation exchange. They were then examined for their ability to adsorb phenol and several of its chlorinated congeners. The organic cations used were: hexadecylpyridinium (HDPY+), hexadecyltri-methyl ammonium (HDTMA+), trimethylphenyl ammonium (TMPA), and tetramethylammonium (TMA+). The complexes containing long-chain alkyl (hexadecyl) groups were the most hydrophobic and adsorbed the phenols from water in proportion to their hydrophobicities, which increase with chlorine addition (phenol < chlorophenol < dichloropohenol < trichlorophenol). With n-hexane as the solvent, different adsorption was found which depended on the type and degree of solvent interactions with the compound and the clay-organic complex. Thus, the amount of adsorption of these phenols on clay-organic complexes was dependent on the relative energies of adsorbent-adsorbate and adsorbate-solvent interactions.
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Citations
Cites
Adsorption Surface Area and Porosity
Gregg, S. J., Sing, K. S. W., & Salzberg, H. W. (1967) · Journal of The Electrochemical Society · doi:10.1149/1.2426447 · Cited by 9,507
Adsorption surface area and porosity
Steele, W. A. (1983) · Journal of Colloid and Interface Science · doi:10.1016/0021-9797(83)90305-3 · Cited by 7,928
Mortland, M. M. (1975) · Soil Science Society of America Journal · doi:10.2136/sssaj1975.03615995003900020002x · Cited by 1,154
Self-citationThe Chemistry of Clay-Organic Reactions
Theng, B. K. G. (2024) · CRC Press eBooks · doi:10.1201/9781003080244 · Cited by 1,091
Clay-Organic Complexes and Interactions
Mortland, M. M. (1970) · Advances in Agronomy · doi:10.1016/s0065-2113(08)60266-7 · Cited by 559
Self-citationChemistry of Pigments and Fillers
Solomon, D. H., & Hawthorne, D. G. (1983) · Cited by 242
Mechanisms of Adsorption of Nonhumic Organic Species by Clays
MORTLAND, M. M. (1986) · SSSA special publication series · doi:10.2136/sssaspecpub17.c3 · Cited by 51
Self-citationSelective effects of smectite-organic complexes on the activities of immobilized enzymes
Boyd, S. A., & MORTLAND, M. M. (1986) · Journal of Molecular Catalysis · doi:10.1016/0304-5102(86)87032-8 · Cited by 30
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Hybrid materials based on clays for environmental and biomedical applications
Ruiz-Hitzky, E., Aranda, P., Darder, M., & Rytwo, G. (2010) · Journal of Materials Chemistry · doi:10.1039/c0jm00432d · Cited by 325
Adsorptive removal of chlorophenols from water by bituminous shale
Tütem, E., Apak, R., & Ünal, Ç. F. (1998) · Water Research · doi:10.1016/s0043-1354(97)00476-4 · Cited by 317
Metadata
- Authors
- Mortland, M. M., Shaobai, S., & Boyd, S. A.
- Venue
- Clays and Clay Minerals
- Publisher
- Cambridge University Press (CUP)
- Published
- 1986-10
- Volume
- 34
- Issue
- 5
- Pages
- 581-585
- ISSN
- 0009-8604 (ISSN-L)
- 1552-8367
- OpenAlex
- W2097585914
- Cited by
- 448
- References
- 9
- FWCI
- 9.83
- Type
- journal article
- Language
- en
- Open access
- closed
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