Cited by 4,253Spectroscopy and Quantum Chemical StudiesPhotochemistry and Electron Transfer StudiesMolecular Spectroscopy and Structure

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The exciton model in molecular spectroscopy

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Kasha, M., Rawls, H. R., Ashraf El-Bayoumi, M.·1965·Pure and Applied Chemistry

DOI 10.1351/pac196511030371

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Abstract

The molecular exciton model has received its most extensive development and application in the field of molecular crystals1'2. More recently, numerous applications to non-crystalline molecular composite systems have been made, including van der Waals and hydrogen-bonded dimers, trimers, and

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Kitamura, C., Abe, Y., Ohara, T., Yoneda, A., Kawase, T., Kobayashi, T., Naito, H., & Komatsu, T. (2009) · Chemistry - A European Journal · doi:10.1002/chem.200901668 · Cited by 72
Rate expressions for excitation transfer I. Radiationless transition theory perspective
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Formation of Highly Luminescent Supramolecular Architectures Possessing Columnar Order from Octupolar Oxadiazole Derivatives: Hierarchical Self‐Assembly from Nanospheres to Fibrous Gels
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Single Molecule Photobleaching Probes the Exciton Wave Function in a Multichromophoric System
Hernando, J. C., Hoogenboom, J. P., van Dijk, E. M. H. P., García-López, J. J., Crego‐Calama, M., Reinhoudt, D. N., van Hulst, N. F., & Parajo, M. F. G. (2004) · Physical Review Letters · doi:10.1103/physrevlett.93.236404 · Cited by 72
Chiroptical Inversion in Helical Si–Si Bond Polymer Aggregates
Suzuki, N., Fujiki, M., Kimpinde-Kalunga, R., & Koe, J. R. (2013) · Journal of the American Chemical Society · doi:10.1021/ja405570q · Cited by 72
Photoinduced charge separation in self-assembled cofacial pentamers of zinc-5,10,15,20-tetrakis(perylenediimide)porphyrin
Ahrens, M. J., Kelley, R. F., Dance, Z. E. X., & Wasielewski, M. R. (2007) · Physical Chemistry Chemical Physics · doi:10.1039/b617876f · Cited by 71
Singlet oxygen formation in monomeric and aggregated porphyrin c
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Dimers of polyene antibiotic amphotericin B detected by means of fluorescence spectroscopy: molecular organization in solution and in lipid membranes
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Design, Synthesis, Structure, and Spectroscopic and Electrochemical Properties of Phthalocyanines
Kobayashi, N. (2002) · Bulletin of the Chemical Society of Japan · doi:10.1246/bcsj.75.1 · Cited by 70
Synthesis, Structures, and Properties of meso‐Phosphorylporphyrins: Self‐Organization through P–Oxo–Zinc Coordination
Matano, Y., Matsumoto, K., Terasaka, Y., Hotta, H., Araki, Y., Ito, O., Shiro, M., Sasamori, T., Tokitoh, N., & Imahori, H. (2006) · Chemistry - A European Journal · doi:10.1002/chem.200600835 · Cited by 70
Aligned Thin Films of Discotic Hexabenzocoronenes: Anisotropy in the Optical and Charge Transport Properties
Piris, J., Debije, M. G., Stingelin, N., Laursen, B. W., Pisula, W., Watson, M. D., Bjørnholm, T., Müllen, K., & Warman, J. M. (2004) · Advanced Functional Materials · doi:10.1002/adfm.200400182 · Cited by 70
Nonperipherally Octa(butyloxy)‐Substituted Phthalocyanine Derivatives with Good Crystallinity: Effects of Metal–Ligand Coordination on the Molecular Structure, Internal Structure, and Dimensions of Self‐Assembled Nanostructures
Gao, Y., Chen, Y., Li, R., Bian, Y., Li, X., & Jiang, J. (2009) · Chemistry - A European Journal · doi:10.1002/chem.200901722 · Cited by 70
Localization/Delocalization of Charges in Bay‐Linked Perylene Bisimides
Jiang, W., Xiao, C., Hao, L., Wang, Z., Ceymann, H., Lambert, C., Motta, S. D., & Negri, F. (2012) · Chemistry - A European Journal · doi:10.1002/chem.201103954 · Cited by 69
Aromatic interaction vs.hydrogen bonding in self-assembly at the liquid–solid interface
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Porphyrin Dimers Linked by Conjugated Butadiyne Bridges: Preparations, Spectra, Voltammetry and Reductive Spectroelectrochemistry of {[ M ( OEP )](μ- C 4)[ M ( OEP )]}( M 2≡ H 4, Co 2, Ni 2, Cu 2, Zn 2, Pd 2, Pt 2, Co / Ni , Ni / Cu , Ni / Zn )
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The architecture of invertebrate carotenoproteins
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Research works printed but not linked: 26

2006, Meso?meso linked core modified 22? smaragdyrins with unusual absorption properties, Chemical Communications, 4584
2013, Corannulene-Fused Anion-Responsive π-Conjugated Molecules that Form Self-Assemblies with Unique Electronic Properties, Chemistry - An Asian Journal
2009, Selective glucose recognition by boronic acid azoprobe/γ-cyclodextrin complexes in water, Chemical Communications, 1709
1993, Spectroscopy and Electrochemistry of a Monomer and Sandwich Dimer of Lutetium Tetra-tert-Butylpyrazinoporphyrazine., Chemistry Letters, 185
2013, Linear conjuncted porphyrin trimer synthesis via "click" reaction, Journal of Porphyrins and Phthalocyanines, 1
2012, Controlling J-aggregate formation for increased short-circuit current and power conversion efficiency with a squaraine donor, Progress in Photovoltaics: Research and Applications
2013, Sulfur-Bridged BODIPY DYEmers, Chemistry - A European Journal
2002, Self-association of Disulfonated Deuteroporphyrin and its Esters in Aqueous Solution and Photosensitized Production of Singlet Oxygen by the Dimers¶, Photochemistry and Photobiology, 75, 229, 10.1562/0031-8655(2002)075<0229:SAODDA>2.0.CO;2 · DOI
1999, Synthesis, Optical Properties, Structures and Molecular Orbital Calculations of Subazaporphyrins, Subphthalocyanines, Subnaphthalocyanines and Related Compounds, Journal of Porphyrins and Phthalocyanines (JPP), 03, 453, 10.1002/(SICI)1099-1409(199908/10)3:6/7<453::AID-JPP157>3.0.CO;2-2 · DOI
2013, Unusual Stepwise Protonation and J-Aggregation of meso-Tetrakis(N-methylpyridinium-4-yl)porphine on Binding Poly(sodium vinylsulfonate), Chemistry - A European Journal
2013, Discotic liquid crystals of transition metal complexes 48: Synthesis of novel phthalocyanine-fullerene dyads and effect of a methoxy group on their clearing points, Journal of Porphyrins and Phthalocyanines, 1
1999, Synthesis, optical properties, structures and molecular orbital calculations of subazaporphyrins, subphthalocyanines, subnaphthalocyanines and related compounds, Journal of Porphyrins and Phthalocyanines, 3, 453, 10.1002/(SICI)1099-1409(199908/10)3:6/7<453::AID-JPP157>3.0.CO;2-2 · DOI
2000, The Effect of pH on the Photophysics and Photochemistry of Di-sulphonated Aluminum Phthalocyanine, Photochemistry and Photobiology, 71, 397, 10.1562/0031-8655(2000)071<0397:TEOPOT>2.0.CO;2 · DOI
2012, Growth mode and self-organization of LuPc_{2} on Si(001)-2×1 vicinal surfaces: An optical investigation, Physical Review B, 86
1999, Porphyrin Dimers Linked by Conjugated Butadiyne Bridges: Preparations, Spectra, Voltammetry and Reductive Spectroelectrochemistry of {[M(OEP)](μ-C4)[M(OEP)]}(M2≡H4, Co2, Ni2, Cu2, Zn2, Pd2, Pt2, Co/Ni, Ni/Cu, Ni/Zn), Journal of Porphyrins and Phthalocyanines (JPP), 03, 5, 10.1002/(SICI)1099-1409(199901)3:1<5::AID-JPP98>3.0.CO;2-N · DOI
1999, Further Studies on the Oxidation State of Iron in μ-Oxo Dimeric Phthalocyanine Complexes, Journal of Porphyrins and Phthalocyanines (JPP), 03, 87, 10.1002/(SICI)1099-1409(199902)3:2<87::AID-JPP108>3.0.CO;2-G · DOI
2012, Highly Fluorescent Slipped-Cofacial Phthalocyanine Dimer as a Shallow Inclusion Complex with α-Cyclodextrin, The Journal of Physical Chemistry A, 120518112558002
1999, Steamrollers, Sports Cars and Security: Phthalocyanine Progress Through the Ages, Journal of Porphyrins and Phthalocyanines (JPP), 03, 468, 10.1002/(SICI)1099-1409(199908/10)3:6/7<468::AID-JPP158>3.0.CO;2-K · DOI
1999, Porphyrin dimers linked by conjugated butadiyne bridges: preparations, spectra, voltammetry and reductive spectroelectrochemistry of {[M(OEP)](µ-C4)[M(OEP)]} (M2≡H4, Co2, Ni2, Cu2, Zn2, Pd2, Pt2, Co/Ni, Ni/Cu, Ni/Zn), Journal of Porphyrins and Phthalocyanines, 3, 5, 10.1002/(SICI)1099-1409(199901)3:1<5::AID-JPP98>3.0.CO;2-N · DOI
2000, Theoretical interpretation of spectroscopic data, Journal of Porphyrins and Phthalocyanines (JPP), 04, 377, 10.1002/(SICI)1099-1409(200006/07)4:4<377::AID-JPP236>3.0.CO;2-3 · DOI
1999, A one-pot, one-step, high-yield reaction leading to metal-metal dimacrocycles: the phthalocyanine dimer with a direct Si–Si linkage, Journal of Porphyrins and Phthalocyanines, 3, 433, 10.1002/(SICI)1099-1409(199908/10)3:6/7<433::AID-JPP152>3.0.CO;2-J · DOI
1999, Excited state dynamics of novel diporphyrins with dissimilar cores, Journal of Porphyrins and Phthalocyanines, 3, 70, 10.1002/(SICI)1099-1409(199901)3:1<70::AID-JPP106>3.0.CO;2-9 · DOI
2001, Protonation of Tetrasulfonated Zinc Phthalocyanine in Aqueous Acetonitrile Solution¶, Photochemistry and Photobiology, 74, 566, 10.1562/0031-8655(2001)074<0566:POTZPI>2.0.CO;2 · DOI
1999, Excitonic Interactions in Covalently Linked Porphyrin Dimers with Rotational Freedom, Journal of Porphyrins and Phthalocyanines (JPP), 03, 346, 10.1002/(SICI)1099-1409(199906)3:5<346::AID-JPP139>3.0.CO;2-E · DOI
2011, Metal-Mediated Synthesis of Antiaromatic Porphyrinoids from a BODIPY Precursor, Angewandte Chemie
1993, None, Journal of Physics D Applied Physics, 26, 198

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Authors: Kasha, M., Rawls, H. R., & Ashraf El-Bayoumi, M.
Affiliations: Florida State University (US)
Venue: Pure and Applied Chemistry
Publisher: Walter de Gruyter GmbH
Published: 1965-01-01
Volume: 11
Issue: 3-4
Pages: 371-392
ISSN: 0033-4545 (ISSN-L)
1365-3075
DOI: 10.1351/pac196511030371
OpenAlex: W2034078366
Cited by: 4,253
References: 1,079
Citations by year: 2026: 128 · 2025: 167 · 2024: 166 · 2023: 161 · 2022: 192 · 2021: 177 · 2020: 191 · 2019: 170 · 2018: 182 · 2017: 197 · 2016: 180 · 2015: 187 · 2014: 183 · 2013: 163 · 2012: 163
FWCI: 1.32
Type: journal article
Language: en
Open access: bronze
doi.org
Locations: Pure and Applied Chemistry (publishedVersion)
Topics: Physical Sciences › Physics and Astronomy › Atomic and Molecular Physics, and Optics › Spectroscopy and Quantum Chemical Studies
Physical Sciences › Chemistry › Physical and Theoretical Chemistry › Photochemistry and Electron Transfer Studies
Physical Sciences › Chemistry › Spectroscopy › Molecular Spectroscopy and Structure
Keywords: exciton model, molecular crystals, van der Waals dimers, hydrogen-bonded dimers, molecular trimers, molecular composites, electronic excitation, molecular spectroscopy

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The exciton model in molecular spectroscopy

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