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Molecular shape selective catalysis
Open accessAbstract
Mstract -Molecular shape selective catalysis in intracrys- talline space of siliceous zeolites has opened up a spectrum of new opportunities in catalytic science and in industry.The mechanisms involved include: (a) selective, diffusional mass transport dynamics, and (b) steric modification of the intrinsic reaction rates. THE CHALLENGEAlmost any thermodynamically possible chemical reactions may occur to some extent at a sufficiently high temperature.It follows that the most unique role and purpose of a catalyst is to provide selectivity to direct the transformation along a very specific, desired path.
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Citations
Cited by
Small-Pore Zeolites: Synthesis and Catalysis
Dusselier, M., & Davis, M. E. (2018) · Chemical Reviews · doi:10.1021/acs.chemrev.7b00738 · Cited by 831
Molecular Simulations of Zeolites: Adsorption, Diffusion, and Shape Selectivity
Smit, B., & Maesen, T. L. M. (2008) · Chemical Reviews · doi:10.1021/cr8002642 · Cited by 829
Martínez, C., & Corma, A. (2011) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2011.03.014 · Cited by 723
Organic catalysis over zeolites: A perspective on reaction paths within micropores
Venuto, P. B. (1994) · Microporous Materials · doi:10.1016/0927-6513(94)00002-6 · Cited by 658
YOUNG, L. (1982) · Journal of Catalysis · doi:10.1016/0021-9517(82)90271-8 · Cited by 428
Metadata
- Authors
- Weisz, P. B.
- Venue
- Pure and Applied Chemistry
- Publisher
- Walter de Gruyter GmbH
- Published
- 1980-01-01
- Volume
- 52
- Issue
- 9
- Pages
- 2091-2103
- ISSN
- 0033-4545 (ISSN-L)
- 1365-3075
- OpenAlex
- W2022619038
- Cited by
- 315
- References
- 0
- FWCI
- 4.50
- Type
- journal article
- Language
- en
- Open access
- bronze
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- Weisz, P. B. (1980). Molecular shape selective catalysis. Pure and Applied Chemistry. https://doi.org/10.1351/pac198052092091
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