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Nonlinear response function for time-domain and frequency-domain four-wave mixing

Mukamel, Shaul, Loring, Roger F.·1986·Journal of the Optical Society of America B

Abstract

A unified theory of time-domain and frequency-domain four-wave mixing processes, which is based on the nonlinear response function R(t3, t2, t1), is developed. The response function is expressed in terms of the four-point correlation function of the dipole operator F(τ1, τ2, τ3, τ4) and is evaluated explicitly for a stochastic model of line broadening that holds for any correlation time of the bath. Our results interpolate between the fast-modulation limit, in which the optical Bloch equations are valid, and the static limit of inhomogeneous line broadening. As an example of the relationship between time-domain and frequency-domain four-wave mixing, we compare the capabilities of steady-state and transient coherent anti-Stokes Raman spectroscopy experiments to probe the vibrational dynamics in ground and excited electronic states.

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Metadata

Authors
Mukamel, S., & Loring, R. F.
Venue
Journal of the Optical Society of America B
Published
1986-04-01
Volume
3
Issue
4
Pages
595
ISSN
  • 0740-3224 (ISSN-L)
  • 1520-8540
OpenAlex
W2155597348
Cited by
207
References
1
FWCI
9.61
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Nonlinear response function for time-domain and frequency-domain four-wave mixing. https://app.cochat.ai/papers/10.1364/josab.3.000595
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Mukamel, S., & Loring, R. F. (1986). Nonlinear response function for time-domain and frequency-domain four-wave mixing. Journal of the Optical Society of America B. https://doi.org/10.1364/josab.3.000595

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