The DOI matches its Crossref record; 3 of the 3 references it cites were found in a registry or an index.
Enhanced reverse saturable absorption and optical limiting in heavy-atom-substituted phthalocyanines
Abstract
The reverse saturable absorption and the optical-limiting response of metal phthalocyanines can be enhanced by use of the heavy-atom effect. Phthalocyanines containing heavy-metal atoms, such as In, Sn, and Pb, show a nearly factor-of-2 enhancement in the ratio of effective excited-state to ground-state absorption cross sections compared with those containing lighter atoms, such as Al and Si. In an f/8 optical geometry, homogeneous solutions of heavy-metal phthalocyanines, at 30% linear transmission, limit 8-ns 532-nm laser pulses to </=3 microJ (the energy for 50% probability of eye damage) for incident energies as high as 800 microJ.
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Citations
Cites
Photophysical properties of sixty atom carbon molecule (C60)
Arbogast, J. W., Darmanyan, A. P., Foote, C. S., Diederich, F. N., Whetten, R. L., Rubin, Y., Alvarez, M. M., & Anz, S. J. (1991) · The Journal of Physical Chemistry · doi:10.1021/j100154a006 · Cited by 1,214
Optical limiting performance of C60 and C70 solutions
Tutt, L. W., & Kost, A. (1992) · Nature · doi:10.1038/356225a0 · Cited by 845
Silicon naphthalocyanine triplet state and oxygen. A reversible energy-transfer reaction
Firey, P. A., Ford, W. E., Sounik, J. R., Kenney, M. E., & Rodgers, M. A. J. (1988) · Journal of the American Chemical Society · doi:10.1021/ja00231a007 · Cited by 166
Cited by
Hirata, S., Totani, K., Zhang, J., Yamashita, T., Kaji, H., Marder, S. R., Watanabe, T., & Adachi, C. (2013) · Advanced Functional Materials · doi:10.1002/adfm.201203706 · Cited by 851
Self-citationHirata, S. (2017) · Advanced Optical Materials · doi:10.1002/adom.201700116 · Cited by 785
Recent development in the design of organic materials for optical power limiting
Spangler, C. W. (1999) · Journal of Materials Chemistry · doi:10.1039/a902802a · Cited by 516
Li, J., Jiang, Y., Cheng, J., Zhang, Y., Su, H., Lam, J. W. Y., Sung, H. H. Y., Wong, K. S., Kwok, H. S., & Tang, B. Z. (2015) · Physical Chemistry Chemical Physics · doi:10.1039/c4cp04052j · Cited by 80
Metadata
- Authors
- Perry, J. W., Alvarez, D., Choong, I., Mansour, K., Marder, S. R., & Perry, K. J.
- Venue
- Optics Letters
- Publisher
- Optica Publishing Group
- Published
- 1994-05-01
- Volume
- 19
- Issue
- 9
- Pages
- 625
- ISSN
- 0146-9592 (ISSN-L)
- 1539-4794
- OpenAlex
- W2074455832
- Cited by
- 388
- References
- 3
- FWCI
- 11.42
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: Enhanced reverse saturable absorption and optical limiting in heavy-atom-substituted phthalocyanines. https://app.cochat.ai/papers/10.1364/ol.19.000625
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- Perry, J. W., Alvarez, D., Choong, I., Mansour, K., Marder, S. R., & Perry, K. J. (1994). Enhanced reverse saturable absorption and optical limiting in heavy-atom-substituted phthalocyanines. Optics Letters. https://doi.org/10.1364/ol.19.000625
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