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Numerical Simulations of Subsurface Probing in Diffusely Scattering Media Using Spatially Offset Raman Spectroscopy
Open accessAbstract
We present the first elementary model predicting how Raman intensities vary for a range of experimental variables for spatially offset Raman spectroscopy (SORS), a recently proposed technique for the effective retrieval of Raman spectra of subsurface layers in diffusely scattering media. The model was able to reproduce the key observations made from the first SORS experiments, namely the dependence of Raman signal intensities on the spatial offset between the illumination and collection points and the relative contributions to the overall spectrum from the top layer and sub-layer. The application of the SORS concept to a three-layer system is also discussed. The model also clearly indicates that an annular geometry, rather than a point-collection geometry, which was used in the earlier experiments, would yield much improved data.
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Citations
Cited by
Analytical applications of Raman spectroscopy
Kudelski, A. (2008) · Talanta · doi:10.1016/j.talanta.2008.02.042 · Cited by 455
Raman spectroscopy: techniques and applications in the life sciences
Shipp, D. W., Sinjab, F., & Notingher, I. (2017) · Advances in Optics and Photonics · doi:10.1364/aop.9.000315 · Cited by 396
Forensic and homeland security applications of modern portable Raman spectroscopy
Izake, E. L. (2010) · Forensic Science International · doi:10.1016/j.forsciint.2010.03.020 · Cited by 263
Surface enhanced spatially offset Raman spectroscopic (SESORS) imaging – the next dimension
Stone, N., Kerssens, M., Lloyd, G. R., Faulds, K., Graham, D., & Matousek, P. (2011) · Chemical Science · doi:10.1039/c0sc00570c · Cited by 183
Self-citationSurface enhanced deep Raman detection of cancer tumour through 71 mm of heterogeneous tissue
Dey, P., Vaideanu, A., Mosca, S., Salimi, M., Gardner, B., Palombo, F., Uchegbu, I., Baumberg, J., Schatzlein, A., Matousek, P., et al. (2022) · Nanotheranostics · doi:10.7150/ntno.71510 · Cited by 34
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Metadata
- Authors
- Matousek, P., Morris, M. D., Everall, N., Clark, I. P., Towrie, M., Draper, E., Goodship, A., & Parker, A. W.
- Venue
- Applied Spectroscopy
- Publisher
- SAGE Publications
- Published
- 2005-12
- Volume
- 59
- Issue
- 12
- Pages
- 1485-1492
- ISSN
- 0003-7028 (ISSN-L)
- 1943-3530
- OpenAlex
- W1972383782
- Cited by
- 209
- References
- 0
- FWCI
- 4.69
- Type
- journal article
- Language
- en
- Open access
- green
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- The paper
- Matousek, P., Morris, M. D., Everall, N., Clark, I. P., Towrie, M., Draper, E., Goodship, A., & Parker, A. W. (2005). Numerical Simulations of Subsurface Probing in Diffusely Scattering Media Using Spatially Offset Raman Spectroscopy. Applied Spectroscopy. https://doi.org/10.1366/000370205775142548
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