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Infrared Intensities of Liquids I: Determination of Infrared Optical and Dielectric Constants by FT-IR Using the CIRCLE ATR Cell
Abstract
The CIRCLE ATR accessory has been used to measure the optical and dielectric constants of organic liquids and water. The method, based on Fresnel's equations, is described in detail, and the agreement between the results obtained and literature values is shown to be adequate for chemical use. The utility of optical and dielectric constants for the calculation of traditional infrared intensities in liquids and of dipole moment derivatives is outlined.
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Cited by
Ab initio molecular dynamics: Concepts, recent developments, and future trends
Iftimie, R., Minary, P., & Tuckerman, M. E. (2005) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.0500193102 · Cited by 472
Temperature dependence of the optical constants for liquid H2O and D2O in the far IR region
Zelsmann, H. R. (1995) · Journal of Molecular Structure · doi:10.1016/0022-2860(94)08471-s · Cited by 364
Structures of Ionic Liquids with Different Anions Studied by Infrared Vibration Spectroscopy
Jeon, Y., Sung, J., Seo, C., Lim, H., Cheong, H., Kang, M., Moon, B., Ouchi, Y., & Kim, D. (2008) · The Journal of Physical Chemistry B · doi:10.1021/jp7120752 · Cited by 277
Bertie, J. E., & Lan, Z. (1996) · The Journal of Chemical Physics · doi:10.1063/1.472635 · Cited by 74
Self-citationSurface-Catalyzed Oxygen Exchange during Mineral Carbonation in Nanoscale Water Films
Miller, Q. R. S., Dixon, D. A., Burton, S. D., Walter, E. D., Hoyt, D. W., McNeill, A. S., Moon, J. D., Thanthiriwatte, K. S., Ilton, E. S., Qafoku, O., et al. (2019) · The Journal of Physical Chemistry C · doi:10.1021/acs.jpcc.9b02215 · Cited by 42
Metadata
- Authors
- Bertie, J. E., & Eysel, H. H.
- Venue
- Applied Spectroscopy
- Publisher
- SAGE Publications
- Published
- 1985-05
- Volume
- 39
- Issue
- 3
- Pages
- 392-401
- ISSN
- 0003-7028 (ISSN-L)
- 1943-3530
- OpenAlex
- W2139012575
- Cited by
- 159
- References
- 0
- FWCI
- 4.50
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: Infrared Intensities of Liquids I: Determination of Infrared Optical and Dielectric Constants by FT-IR Using the CIRCLE ATR Cell. https://app.cochat.ai/papers/10.1366/0003702854248575
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- Bertie, J. E., & Eysel, H. H. (1985). Infrared Intensities of Liquids I: Determination of Infrared Optical and Dielectric Constants by FT-IR Using the CIRCLE ATR Cell. Applied Spectroscopy. https://doi.org/10.1366/0003702854248575
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