The DOI matches its Crossref record.
1. Rate Laws of Chemical Reactions
Abstract
In addressing geochemical phenomena from the kinetic point of view, a deeper understanding is obtained of the mechanisms and molecular pathways by which the reactions are carried out. The element distribution in the earth is the result of a series of such transformations, which involve sedimentary metamorphic, and igneous processes that lead to the concept of geochemical cycles. As a particular mineral assemblage undergoes changes in pressure and/or temperature, disequilibrium will drive certain chemical reactions. Changes in the fluid content of the system will also drive other reactions. In this Chapter, the rate of change of the concentration of species participating in chemical reactions is related to the state of the system (i.e., the pressure, the temperature, and the bulk composition). The concepts include: steady state; overall reactions; reactive intermediates; activation energies; adsorption; detailed balancing; and mass transfer. The major conclusion made in the chapter is that many natural systems are not in equilibrium. (JMT)
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cited by
Quantifying the degradation of organic matter in marine sediments: A review and synthesis
Arndt, S., Jørgensen, B. B., LaRowe, D. E., Middelburg, J. J., Pancost, R. D., & Regnier, P. (2013) · Earth-Science Reviews · doi:10.1016/j.earscirev.2013.02.008 · Cited by 1,040
Stumm, W., & Sulzberger, B. (1992) · Geochimica et Cosmochimica Acta · doi:10.1016/0016-7037(92)90301-x · Cited by 608
Correlating quartz dissolution kinetics in pure water from 25 to 625°C
Tester, J. W., Worley, W. G., Robinson, B. A., Grigsby, C. O., & Feerer, J. L. (1994) · Geochimica et Cosmochimica Acta · doi:10.1016/0016-7037(94)90020-5 · Cited by 287
Inskeep, W. P., & Bloom, P. R. (1985) · Geochimica et Cosmochimica Acta · doi:10.1016/0016-7037(85)90074-2 · Cited by 172
On the temperature dependence of mineral dissolution rates
Casey, W. H., & Sposito, G. (1992) · Geochimica et Cosmochimica Acta · doi:10.1016/0016-7037(92)90173-g · Cited by 161
Metadata
- Venue
- Kinetic Theory in the Earth Sciences
- Publisher
- Princeton University Press
- Published
- 1998-12-31
- Pages
- 1-151
- OpenAlex
- W1975491457
- Cited by
- 329
- References
- 0
- FWCI
- 15.84
- Type
- book chapter
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
How to cite
Cite CoChat for the checks on this page, and the paper for its own findings.
- This page
- CoChat. (2026). Citation check: 1. Rate Laws of Chemical Reactions. https://app.cochat.ai/papers/10.1515/9781400864874.1
- The paper
- 1. Rate Laws of Chemical Reactions. (1998). Kinetic Theory in the Earth Sciences. https://doi.org/10.1515/9781400864874.1
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
