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Cited by 204

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An overview and historical look back at the solvent extraction using nitrogen donor ligands to extract and separate An(III) from Ln(III)

Ekberg, Christian, Fermvik, Anna, Retegan, Teodora, Skarnemark, Gunnar, Foreman, M. R. S., Hudson, M. J., Englund, Sofie, Nilsson, Mikael·2008·Radiochimica Acta

Abstract

The partitioning of minor trivalent actinides (An) from lanthanides (Ln) is one of the challenges in the chemical treatment of nuclear waste. The optimal ligand to carry out the separation of An(III) and Ln(III) using solvent extraction has to meet several important criteria: high selectivity towards the solute, chemical and radiolytic stability, stripping possibilities and recycling of the organic phase, high separation factors and good distribution ratio, to name just a few of them. A chronological line can be drawn along the development of each extraction ligand family and some milestones are emphasized in this overview. Further developments in organic synthesis of extracting ligands are expected.

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Metadata

Authors
Ekberg, C., Fermvik, A., Retegan, T., Skarnemark, G., Foreman, M. R. S., Hudson, M. J., Englund, S., & Nilsson, M.
Venue
Radiochimica Acta
Published
2008-05-01
Volume
96
Issue
4-5
Pages
225-233
ISSN
  • 0033-8230 (ISSN-L)
  • 2193-3405
OpenAlex
W1968568860
Cited by
204
References
1
FWCI
7.61
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: An overview and historical look back at the solvent extraction using nitrogen donor ligands to extract and separate An(III) from Ln(III). https://app.cochat.ai/papers/10.1524/ract.2008.1483
The paper
Ekberg, C., Fermvik, A., Retegan, T., Skarnemark, G., Foreman, M. R. S., Hudson, M. J., Englund, S., & Nilsson, M. (2008). An overview and historical look back at the solvent extraction using nitrogen donor ligands to extract and separate An(III) from Ln(III). Radiochimica Acta. https://doi.org/10.1524/ract.2008.1483

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