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The crystal structure of the 11Å natural tobermorite Ca2.25[Si3O7.5(OH)1.5] · 1H2O
Abstract
The crystal structure of a natural tobermorite from Zeilberg, Maroldsweisach, Germany (average formula Ca 2.2 5[Si 3 O 7.5 s(OH)1.5].-1H 2 O), is solved using the data obtained from an automatic diffractometer. For the structure determination only the sharp main reflexions are considered. The crystal data of the chosen subcell are: a′ = 5.586(4)Å, b′ = 3.696(2)Å, c = 22.779(7)Å, S.G Imm 2, V = 470.25Å 3, Dx = 2.39 g/cm 3, Dcxp = 2.43 g/cm 3, and Z = 2. The disordered superposed structure is refined to a weighted R-value of 0.085. From the average structure the superposed chains are resolved and the tobermorite structure is then developed. One of the possible ordered tobermorite structures is monoclinic, space group P2l, with the unit cell dimensions: a m = 6.69 Å, b m = 7.39 Å, c m = 22.779Å, and y = 123.49°. The tobermorite has infinite Si 3(O/OH)9 chains running parallel b. The calcium atoms are coordinated by seven oxygen atoms.
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Cited by
Structure of Calcium Silicate Hydrate (C‐S‐H): Near‐, Mid‐, and Far‐Infrared Spectroscopy
Yu, P., Kirkpatrick, R. J., Poe, B., McMillan, P. F., & Cong, X. (1999) · Journal of the American Ceramic Society · doi:10.1111/j.1151-2916.1999.tb01826.x · Cited by 1,640
Richardson, I. G. (2004) · Cement and Concrete Research · doi:10.1016/j.cemconres.2004.05.034 · Cited by 1,082
29Si MAS NMR study of the structure of calcium silicate hydrate
Cong, X., & Kirkpatrick, R. J. (1996) · Advanced Cement Based Materials · doi:10.1016/s1065-7355(96)90046-2 · Cited by 678
Andersen, M. D., Jakobsen, H. J., & Skibsted, J. (2003) · Inorganic Chemistry · doi:10.1021/ic020607b · Cited by 434
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Metadata
- Venue
- Zeitschrift für Kristallographie - Crystalline Materials
- Publisher
- Walter de Gruyter GmbH
- Published
- 1981-02-01
- Volume
- 154
- Issue
- 3-4
- Pages
- 189-198
- ISSN
- 2194-4946 (ISSN-L)
- 2196-7105
- OpenAlex
- W2322107805
- Cited by
- 329
- References
- 0
- FWCI
- 0.45
- Type
- journal article
- Language
- en
- Open access
- closed
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- The crystal structure of the 11Å natural tobermorite Ca2.25[Si3O7.5(OH)1.5] · 1H2O. (1981). Zeitschrift für Kristallographie - Crystalline Materials. https://doi.org/10.1524/zkri.1981.154.3-4.189
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