The DOI matches its Crossref record; 108 of the 108 references it cites were found in a registry or an index.
Implications of apparent pseudo-second-order adsorption kinetics onto cellulosic materials: A review
Open accessAbstract
The pseudo-second-order (PSO) kinetic model has become among the most popular ways to fit rate data for adsorption of metal ions, dyes, and other compounds from aqueous solution onto cellulose-based materials.This review first considers published evidence regarding the validity of the mechanistic assumptions underlying application of the PSO model to adsorption kinetics.A literal interpretation of the model requires an assumption that different adsorption sites on a solid substrate randomly collide with each other during a rate-limiting mechanistic step.Because of problems revealed by the literature regarding the usual assumptions associated with the PSO model, this review also considers how else to account for good fits of adsorption data to the PSO model.Studies have shown that adsorption behavior that fits the PSO model well often can be explained by diffusion-based mechanisms.Hypothetical data generated using the assumption of pseudo-first-order rate behavior has been shown to fit the PSO model very well.In light of published evidence, adsorption kinetics of cellulosic materials is expected to mainly depend on diffusionlimited processes, as affected by heterogeneous distributions of pore sizes and continual partitioning of solute species between a dissolved state and a fixed state of adsorption.
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Cites
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Cited by
Raji, Z., Karim, A., Karam, A., & Khalloufi, S. (2023) · Waste · doi:10.3390/waste1030046 · Cited by 517
Fixed bed adsorption as affected by thermodynamics and kinetics: yellow tuff for CO2 capture
Ammendola, P., Raganati, F., Chirone, R., & Miccio, F. (2020) · Powder Technology · doi:10.1016/j.powtec.2020.06.075 · Cited by 88
Metadata
- Authors
- Hubbe, M., Azizian, S., & Douven, S.
- Venue
- BioResources
- Publisher
- BioResources
- Published
- 2019-08
- Volume
- 14
- Issue
- 3
- Pages
- 7582-7626
- ISSN
- 1930-2126 (ISSN-L)
- OpenAlex
- W4245250076
- Cited by
- 599
- References
- 108
- FWCI
- 21.48
- Type
- journal article
- Language
- en
- Open access
- gold
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- Hubbe, M., Azizian, S., & Douven, S. (2019). Implications of apparent pseudo-second-order adsorption kinetics onto cellulosic materials: A review. BioResources. https://doi.org/10.15376/biores.14.3.7582-7626
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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