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Cited by 901Advanced Cellulose Research StudiesNatural Fiber Reinforced CompositesNanocomposite Films for Food Packaging

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Cellulosic nanocomposites: a review

Open access
Martin Allen Hubbe, Orlando José Rojas, Lucian A. Lucia, Mohini M. Sain·2008·BioResources
DOI 10.15376/biores.3.3.929-980
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Abstract

Because of their wide abundance, their renewable and environmentally benign nature, and their outstanding mechanical properties, a great deal of attention has been paid recently to cellulosic nanofibrillar structures as components in nanocomposites. A first major challenge has been to find efficient ways to liberate cellulosic fibrils from different source materials, including wood, agricultural residues, or bacterial cellulose. A second major challenge has involved the lack of compatibility of cellulosic surfaces with a variety of plastic materials. The water-swellable nature of cellulose, especially in its non-crystalline regions, also can be a concern in various composite materials. This review of recent work shows that considerable progress has been achieved in addressing these issues and that there is potential to use cellulosic nano-components in a wide range of high-tech applications.

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Research works printed but not linked: 50

  1. Adams, D. O. (1980). 'Core stock paper,' TAPPI Plastic Laminates Seminar Notes , TAPPI Press, Atlanta, 7-16.
  2. Alén, R. (2000). 'Structure and chemical composition of wood,' in Forest Products Chemistry , Stenius, P. (ed.), Fapet Oy, Helsinki, Ch. 1, 12-57.
  3. Alince, B., and van de Ven, T. G. M. (1997). 'Porosity of swollen pulp fibers evaluated by polymer adsorption,' in Baker, C. F. (ed.), The Fundamentals of Papermaking Materials , Trans. 11 th Fundamental Res. Symp., Cambridge, Vol. 2, 771-788.
  4. Angellier, H., Molina-Boisseau, S., Lebrun, L., and Dufresne, A. (2005). 'Processing and structural properties of waxy maize starch nanocrystals reinforced natural rubber,' Macromol. 38(9), 3783-3792.
  5. Azizi Samir, M. A. S., Alloin, F., Sanchez, J. Y., and Dufresne, A. (2004c). 'Crosslinked nanocomposite polymer electrolytes reinforced with cellulose whiskers,' Macromol. 37(13), 4839-4844.
  6. Berthold, J., and Salmén, L. (1997). 'Effects of mechanical and chemical treatments on the pore-size distribution in wood pulps examined by inverse size-exclusion chromatography,' J. Pulp Paper Sci. 23(6), J245-J253.
  7. Bochek, A. M., Ten'kovtsev, A. V., Dudkina, M. M., et al. (2004). 'Nonlinear optically active nanocomposites based on cellulose,' Polymer Sci. Ser. B 46(3-4), 109-112.
  8. Bodin, A., Backdahl, H., Risberg, B., and Gatenholm, P. (2007). 'Nano cellulose as a scaffold for tissue engineered blood vessels,' Tissue Eng. 13(4), 885-885.
  9. Caulfield, D. F., Koutsky, J. A., and Quillen, D. T. (1993). 'Cellulose/polypropylene composites: The use of AKD and ASA sizing as compatibilizers,' in Wood Fiber / Polymer Composites , Wolcott, M. P. (ed.), Forest Prod. Soc., 128-134.
  10. Chazeau, L., Cavaille, J. Y., and Perez, J. (2000). 'Plasticized PVC reinforced with cellulose whiskers. II. Plastic behavior,' J. Polymer Sci. B - Polymer Phys. 38(3), 383-392.
  11. Chazeau, L., Paillet, M., and Cavaille, J. Y. (1999c). 'Plasticized PVC reinforced with cellulose whiskers. I. Linear viscoelastic behavior analyzed through the quasi-point defect theory,' J. Polymer Sci. B - Polymer Phys. 37(16), 2151-2164.
  12. Chowdhury, M. J. A., and Wolcott, M. P. (2007). 'Compatibilizer selection to improve mechanical and moisture properties of extruded wood-HDPE composites,' Forest Prod. J. 57(9), 46-53.
  13. Correa, C. A., Razzino, C. A., and Hage, E. (2007). 'Role of maleated coupling agents on the interface adhesion of polypropylene-wood composites,' J. Thermoplastic Composite Mater. 20(3), 323-339.
  14. Dufresne, A. (2003). 'Interfacial phenomena in nanocomposites based on polysaccharide nanocrystals,' Composite Interfaces 10(4-5), 369-387.
  15. Dufresne, A., Kellerhals, M. B., and Witholt, B. (1999). 'Transcrystallization in MclPHAs/cellulose whiskers composites,' Macromol. 32(22), 7396-7401.
  16. Gea, S., Torres, F. G., Troncoso, O. P., Reynolds, C. T., Vilasecca, F., Iguchi, M., and Peijs, T. (2007). 'Biocomposites based on bacterial cellulose and apple and radish pulp,' Intl. Polymer Proc. 22(5), 497-501.
  17. Heng, J. Y. Y., Pearse, D. F., Thielmann, F., Lampke, T., and Bismarck, A. (2007). 'Methods to determine surface energies of natural fibres: A review,' Composite Interf. 14(7-9), 581-604.
  18. Hubbe, M. A. (2006b). 'Does production of the world's highest-tonnage manufactured item often involve nanotechnology?' Nanotech. Perceptions 2(3), 263-266.
  19. Ioelovich, M., and Leykin, A. (2006). 'Microcrystalline cellulose: Nano-structure formation,' Cellulose Chem. Technol. 40(5), 313-317.
  20. Ivanov, C., Popa, M., Ivanov, M., and Popa, A. A. (2007). 'Synthesis of poly(vinyl alcohol) - methyl cellulose hydrogel as possible scaffolds in tissue engineering,' J. Optoelectronics and Advanced Materials 9(11), 3440-3444.
  21. Jacob, M., Joseph, S., Pothan, L. A., and Thomas, S. (2005). 'A study of advances in characterization of interfaces and fiber surfaces in lignocellulosic fiber-reinforced composites,' Composite Interfaces 12(1-2), 95-124.
  22. Kroonbatenburg, L. M. J., Kroon, J., and Northolt, M. G. (1986). 'Chain modulus and intermolecular hydrogen bonding in native and regenerated cellulose fibers,' Polymer Communications 27(10), 290-292.
  23. Kulpinski, P. (2005). 'Cellulose nanofibers prepared by the N-methylmorpholine-Noxide method,' J. Appl. Polymer Sci. 98(4), 1855-1859.
  24. Laka, M., Chernyavskaya, S., Treimanis, A., and Faitelson, L. (2000). 'Preparation and properties of microcrystalline cellulose gels,' Cellulose Chem. Technol. 34(3-4), 217227.
  25. Li, T.-Q., Heriksson, U., and Ödberg, L. (1993). 'Determination of pore sizes in wood cellulose fibers by 2 H and 1 H NMR,' Nordic Pulp Paper Res. J. 8(3), 326-330.
  26. Li, Q. X., and Matuana, L. M. (2003). 'Surface of cellulosic materials modified with functionalized polyethylene coupling agents,' J. Appl. Polymer Sci. 88(2), 278-286.
  27. Lindström, T., and Wågberg, L. (2002). 'An overview of some possibilities to modify fiber surfaces for tailoring composite interfaces,' Proc. 23 rd Risø Intl. Symp. Materials Sci. - Sustainable Natural and Polymeric Composites - Sci. and Technol. , Lilholt, H. et al. (eds.), Risø Natl. Lab., Roskilde, Denmark, 35-59.
  28. Michailova, V., Titeva, S., and Kotsilkova, R. (2005). 'Rheological characteristics and diffusion processes in mixed cellulose hydrogen matrices,' J. Drug Delivery Science and Technology 15(6), 443-449.
  29. Matsumura, H., and Glasser, W. G. (2000). 'Cellulosic nanocomposites. II. Studies by atomic force microscopy,' J. Appl. Polymer Sci. 78(13), 2254-2261.
  30. Miller, B., Penn, L. S., and Hedvat, S. (1983). 'Wetting forces measurements on single fibers,' Colloids Surf. 6(1), 49-61.
  31. Neuman, R. D. (1993b). 'Surface force measurement in paper making systems,' in Products of Papermaking. Transactions of the Tenth Fundamental Research Symposium , Oxford, Sept. 1993, Vol. 2, Pira International, Leatherhead, UK, 969.
  32. Notingher, P. V., Panaitescu, D., Vuluga, Z., Iorga, M., Paven, H., and Florea, D. (2006). 'The effect of water on electrical properties of polymer composites with cellulose fibers,' J. Optoelectronics Adv. Mater. 8(2), 687-689.
  33. Okubo, K., Fujii, T., and Yamashita, N. (2005). 'Improvement of interfacial adhesion in bamboo polymer composite enhanced with micro-fibrillated cellulose,' JSME Intl. J. A - Solid Mechanics Mater. Eng. 48(4), 199-204.
  34. Panaitescu, D. M., Matasaru, I., Iovu, H., Ghiurea, M., Iorga, M. D., and Stanescu, P. (2007a). 'Thermoplastic composites with cellulose microfibrils obtained through mechanical treatment,' Materiale Plastice 44(2), 144-147.
  35. Piejs, T. (2002). 'Novel concepts for obtaining sustainable composites based on synthetic polymers,' Proc. 23 rd Risø Intl. Symp. Materials Sci. - Sustainable Natural and Polymeric Composites - Sci. and Technol. , Lilholt, H. et al. (eds.), Risø Natl. Lab., Roskilde, Denmark, 61-75.
  36. Podsiadlo, P., Sui, L., Elkasabi, Y., Burgardt, P., Lee, J., Miryala, A., Kusumaatmaja, W., Carman, M. R., Shtein, M., Kieffer, J., Lahann, J., and Kotov, N. A. (2007). 'Layerby-layer assembled films of cellulose nanowires with antireflective properties,' Langmuir 23(15), 7901-7906.
  37. Roberts, J. C., and Tatham, J. (1992). 'Succinylation of pulps,' in The Chemistry of Papermaking , Conference Preprints, Pira, Leatherhead, UK, Paper 08.
  38. Roman, M., and Winter, W. T. (2004). 'Effect of sulphate groups from sulphuric acid hydrolysis on the thermal degradation behavior of bacterial cellulose,' Biomacromol. 5(5), 1671-1677.
  39. Singh, B., Gupta, M., Verma, A., and Tyagi, O. S. (2000). 'FT-IR microscopic studies on coupling agents: Treated natural fibres,' Polymer Intl. 49(11), 1444-1451.
  40. Stenstad, P., Andresen, M., Tanem, B. S., Tanem, B. S., and Stenius, P. (2008). 'Chemical surface modification of microfibrillated cellulose,' Cellulose 15(1), 35-45.
  41. Stone, J. E., and Scallan, A. M. (1966). 'Influence of drying on the pore structures of the cell wall,' in Consolidation of the Paper Web , Trans. Symp. Cambridge, Sept. 1965, Bolam, F. (ed.), Tech. Sec. British Paper & Board Makers' Assoc., London, Vol. 1, 145-174.
  42. Stone, J. E., and Scallan, A. M. (1968b). 'A structural model for the cell wall of waterswollen wood pulp fibers based on their accessibility to macromolecules,' Cellulose Chem. Technol. 2(3), 343-358.
  43. Sui, X., Yuan, U., Yuan, W., and Zhou, M. (2008). 'Preparation of cellulose nanofibers/ nanopoarticles via electrospray,' Chemistry Letters 37(1), 114.
  44. TAPPI (1997). 'Freeness of pulp (Canadian standard method),' in TAPPI Test Methods , TAPPI Press, Atlanta, T227 om-94.
  45. Trejo-O'Reilly, J. A., Cavaille, J. Y., Belgacem, N. M., and Gandini, A. (1998). 'Surface energy and wettability of modified cellulosic fibres for use in composite materials,' J. Adhes. 67(1-4), 359-374.
  46. Vallejos, M. E., Girones, J., Vilaseca, F., Mendez, J. A., Lopez, A., and Mutje, P. (2006). 'Polypropylene reinforced with hemp strands: Study of the influence of propylene modified with maleic anhydride as coupling agent,' AFINIDAD 63(522), 94-105.
  47. Wågberg, L., Forsberg, S., Johansson, A., and Juntti, P. (2002). 'Engineering of fiber surface properties by application of polyelectrolyte multilayer concept. Part 1: Modification of paper strength,' J. Pulp Paper Sci. 28(7), 222-228.
  48. Wang, B., Panigrahi, S., Tabil, L., and Crerar, W. (2007b). 'Pre-treatment of flax fibers for use in rotationally molded biocomposites,' J. Reinforced Plastics Composites 26(5), 447-463.
  49. Ye, D. (2007). 'Preparation of nanocellulose,' Prog. Chem. 19(10), 1568-1575.
  50. Yu, L., Dean, K., and Li, L. (2006). 'Polymer blends and composites from renewable resources,' Prog. Polymer Sci. 31(6), 576-602.

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Metadata

Authors
Hubbe, M. A., Rojas, O. J., Lucia, L. A., & Sain, M. M.
Affiliations
North Carolina State University (US)
ORCID
Venue
BioResources
Publisher
BioResources
Published
2008-08
Volume
3
Issue
3
Pages
929-980
ISSN
1930-2126 (ISSN-L)
DOI
10.15376/biores.3.3.929-980
OpenAlex
W3189617131
Cited by
901
References
284
Citations by year
2026: 19 · 2025: 29 · 2024: 35 · 2023: 43 · 2022: 42 · 2021: 51 · 2020: 52 · 2019: 74 · 2018: 59 · 2017: 92 · 2016: 70 · 2015: 57 · 2014: 67 · 2013: 53 · 2012: 49
FWCI
15.44
Type
journal article
Language
en
Open access
Locations
  • BioResources (publishedVersion)
  • NCSU Libraries Repository (North Carolina State University Libraries) (submittedVersion)
  • DOAJ (DOAJ: Directory of Open Access Journals) (submittedVersion, cc-by-sa)
  • BioResources
Topics
  • Physical Sciences › Materials Science › Biomaterials › Advanced Cellulose Research Studies
  • Physical Sciences › Materials Science › Polymers and Plastics › Natural Fiber Reinforced Composites
  • Physical Sciences › Materials Science › Biomaterials › Nanocomposite Films for Food Packaging
Keywords
cellulose nanofibers, bacterial cellulose, wood, agricultural residues, interfacial compatibility, water swelling, mechanical properties, renewable materials

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