The DOI matches its Crossref record; 7 of the 7 references it cites were found in a registry or an index.
“Stretching” the energy landscape of oxides—Effects on electrocatalysis and diffusion
Open accessAbstract
Elastic strain engineering offers a new route to enable high-performance catalysts, electrochemical energy conversion devices, separation membranes and memristors. By applying mechanical stress, the inherent energy landscape of reactions involved in the material can be altered. This is the so-called mechano-chemical coupling. Here we discuss how elastic strain activates reactions on metals and oxides. We also present analogies to strained polymer reactions. A rich set of investigations have been performed on strained metal surfaces over the last 15 years, and the mechanistic reasons behind strain-induced reactivity are explained by an electronic structure model. On the other hand, the potential of strain engineering of oxides for catalytic and energy applications has been largely underexplored. In oxides, mechanical stress couples to reaction and diffusion kinetics by altering the oxygen defect formation enthalpy, migration energy barrier, adsorption energy, dissociation barrier, and charge transfer barrier. A generalization of the principles for stress activated reactions from polymers to metals to oxides is offered, and the prospect of using elastic strain to tune reaction and diffusion kinetics in functional oxides is discussed.
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Cites
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Diebold, U. (2003) · Surface Science Reports · doi:10.1016/s0167-5729(02)00100-0 · Cited by 7,944
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Waser, R., Dittmann, R., Staikov, G., & Szot, K. (2009) · Advanced Materials · doi:10.1002/adma.200900375 · Cited by 5,080
Nanoionics-based resistive switching memories
Waser, R., & Aono, M. (2007) · Nature Materials · doi:10.1038/nmat2023 · Cited by 4,923
Improved Oxygen Reduction Activity on Pt 3 Ni(111) via Increased Surface Site Availability
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Adsorption and Dissociation of O 2 on Pt−Co and Pt−Fe Alloys
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Cited by
Bachman, J. C., Muy, S., Grimaud, A., Chang, H.-H., Pour, N., Lux, S. F., Paschos, O., Maglia, F., Lupart, S., Lamp, P., et al. (2016) · Chemical Reviews · doi:10.1021/acs.chemrev.5b00563 · Cited by 2,537
Li, H., Tsai, C., Koh, A. L., Cai, L., Contryman, A. W., Fragapane, A. H., Zhao, J., Han, H. S., Manoharan, H. C., Abild-Pedersen, F., et al. (2016) · Nature Materials · doi:10.1038/nmat4465 · Cited by 2,529
Enhancing Electrocatalytic Water Splitting by Strain Engineering
You, B., Tang, M. T., Tsai, C., Abild‐Pedersen, F., Zheng, X., & Li, H. (2019) · Advanced Materials · doi:10.1002/adma.201807001 · Cited by 793
Enhanced Bifunctional Oxygen Catalysis in Strained LaNiO3 Perovskites
Petrie, J. R., Cooper, V. R., Freeland, J. W., Meyer, T. L., Zhang, Z., Lutterman, D. A., & Lee, H. N. (2016) · Journal of the American Chemical Society · doi:10.1021/jacs.5b11713 · Cited by 396
Gür, T. M. (2016) · Progress in Energy and Combustion Science · doi:10.1016/j.pecs.2015.10.004 · Cited by 340
Metadata
- Authors
- Yildiz, B.
- Venue
- MRS Bulletin
- Published
- 2014-02
- Volume
- 39
- Issue
- 2
- Pages
- 147-156
- ISSN
- 0883-7694 (ISSN-L)
- 1938-1425
- OpenAlex
- W1594857923
- Cited by
- 224
- References
- 7
- FWCI
- 9.61
- Type
- journal article
- Language
- en
- Open access
- green
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Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
