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Graphene Nanosheets and Graphite Oxide as Promising Adsorbents for Removal of Organic Contaminants from Aqueous Solution

Ji, Liangliang, Chen, Wei, Xu, Zhaoyi, Zheng, Shourong, Zhu, Dongqiang·2013·Journal of Environmental Quality

Abstract

Graphenes are an emerging class of carbon nanomaterials whose adsorption properties toward organic compounds have not been well understood. In the present study, graphene nanosheets were prepared by reoxidation and abrupt heating of graphite oxide, which was prepared by sequential chemical oxidation of commercial nonporous graphite powder. Adsorption properties of three aromatic compounds (naphthalene, 2-naphthol, and 1-naphthylamine) and one pharmaceutical compound (tylosin) on graphene nanosheets and graphite oxide were examined to explore the potential of these two adsorbents for the removal of organic contaminants from aqueous solutions. Compared with the literature data of adsorption on carbon nanotubes, adsorption of bulky, flexible tylosin on graphene nanosheets exhibited markedly faster adsorption kinetics, which can be attributed to their opened-up layer structure. Graphene nanosheets and graphite oxide showed similar sequences of adsorption affinity: 1-naphthylamine > 2-naphthol > tylosin > naphthalene (with much larger differences observed on graphite oxide). It was proposed that the strong adsorption of the three aromatic compounds was mainly due to π-π electron donor-acceptor interactions with the graphitic surfaces of adsorbents. Additionally, Lewis acid-base interaction was likely an important factor contributing to the strong adsorption of 1-naphthylamine and tylosin, especially for the O-functionality-abundant graphite oxide. After being normalized on the basis of adsorbent surface area, adsorption affinities of all four tested adsorbates on graphene nanosheets were very close to those on nonporous graphite powder, reflecting complete accessibility of the adsorbent surface area in adsorption.

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Metadata

Authors
Ji, L., Chen, W., Xu, Z., Zheng, S., & Zhu, D.
Venue
Journal of Environmental Quality
Publisher
Wiley
Published
2013-01
Volume
42
Issue
1
Pages
191-198
ISSN
0047-2425 (ISSN-L)
OpenAlex
W1998327237
Cited by
165
References
0
FWCI
10.96
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Graphene Nanosheets and Graphite Oxide as Promising Adsorbents for Removal of Organic Contaminants from Aqueous Solution. https://app.cochat.ai/papers/10.2134/jeq2012.0172
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Ji, L., Chen, W., Xu, Z., Zheng, S., & Zhu, D. (2013). Graphene Nanosheets and Graphite Oxide as Promising Adsorbents for Removal of Organic Contaminants from Aqueous Solution. Journal of Environmental Quality. https://doi.org/10.2134/jeq2012.0172

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