Thermodynamics of Carbonates
Abstract
Research Article| January 01, 2013 Thermodynamics of Carbonates A.V. Radha; A.V. Radha Peter A. Rock Thermochemistry Laboratory and NEAT ORU (Nanomaterials in the Environment, Agriculture, and Technology Organized Research Unit), University of California Davis, Davis, California 95616, U.S.A., ravenkat@ucdavis.edu Search for other works by this author on: GSW Google Scholar A. Navrotsky A. Navrotsky * Peter A. Rock Thermochemistry Laboratory and NEAT ORU (Nanomaterials in the Environment, Agriculture, and Technology Organized Research Unit), University of California Davis, Davis, California 95616, U.S.A., ravenkat@ucdavis.edu *corresponding author: anavrotsky@ucdavis.edu Search for other works by this author on: GSW Google Scholar Author and Article Information A.V. Radha Peter A. Rock Thermochemistry Laboratory and NEAT ORU (Nanomaterials in the Environment, Agriculture, and Technology Organized Research Unit), University of California Davis, Davis, California 95616, U.S.A., ravenkat@ucdavis.edu A. Navrotsky * Peter A. Rock Thermochemistry Laboratory and NEAT ORU (Nanomaterials in the Environment, Agriculture, and Technology Organized Research Unit), University of California Davis, Davis, California 95616, U.S.A., ravenkat@ucdavis.edu *corresponding author: anavrotsky@ucdavis.edu Publisher: Mineralogical Society of America First Online: 09 Mar 2017 © 2013 Mineralogical Society of America Reviews in Mineralogy and Geochemistry (2013) 77 (1): 73–121. https://doi.org/10.2138/rmg.2013.77.3 Article history First Online: 09 Mar 2017 Cite View This Citation Add to Citation Manager Share Icon Share Facebook Twitter LinkedIn Email Permissions Search Site Citation A.V. Radha, A. Navrotsky; Thermodynamics of Carbonates. Reviews in Mineralogy and Geochemistry 2013;; 77 (1): 73–121. doi: https://doi.org/10.2138/rmg.2013.77.3 Download citation file: Ris (Zotero) Refmanager EasyBib Bookends Mendeley Papers EndNote RefWorks BibTex toolbar search Search Dropdown Menu toolbar search search input Search input auto suggest filter your search All ContentBy SocietyReviews in Mineralogy and Geochemistry Search Advanced Search The goal of geologic CO2 sequestration is not just to pump large volumes of supercritical carbon dioxide into underground repositories but to keep it there for hundreds to thousands of years, preferably in chemically bound form. The permanence of CO2 storage in geological repositories is important since large leakage rates would diminish the CO2 abatement achieved with carbon capture and sequestration (CCS). Effective permanent geologic CO2 storage depends ultimately on the interactions of the supercritical CO2 with the minerals and fluids present in the host underground repositories and their caprock sealing (Xu et al.... You do not have access to this content, please speak to your institutional administrator if you feel you should have access.
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The interfacial free energy of the mineral with respect to its solution is a key parameter that determines its nucleation rate.
“The interfacial free energy of the mineral with respect to its solution is a key parameter that determines its nucleation rate.”
From Thermodynamic and Kinetic Studies of Dolomite Formation: A Review (2023) · cites this paper as [121]
A variety of precursor phases exist in the early stages of carbonate crystallization, including prenucleation clusters, metastable liquid-like precursors, mesocrystals and amorphous and nanophase precursors.
“Recent studies have shown that a variety of precursor phases exist in the early stages of carbonate crystallization, including prenucleation clusters, metastable liquid-like precursors, mesocrystals and amorphous and nanophase precursors [114-123].”
From Thermodynamic and Kinetic Studies of Dolomite Formation: A Review (2023) · cites this paper as [121]
Crystal nucleation and growth are free-energy-driven phenomena and reflect solution supersaturation.
“Crystal nucleation and growth are free-energy-driven phenomena and reflect solution supersaturation [121].”
From Thermodynamic and Kinetic Studies of Dolomite Formation: A Review (2023) · cites this paper as [121]
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Stability of some carbonates at 25 degrees C and one atmosphere total pressure
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Tosca, N. J., Guggenheim, S., & Pufahl, P. K. (2016) · Geological Society of America Bulletin · doi:10.1130/b31339.1 · Cited by 241 · see citing works
Dissolution enables dolomite crystal growth near ambient conditions
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Thermodynamic and Kinetic Studies of Dolomite Formation: A Review
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Raudsepp, M. J., Wilson, S., Morgan, B., Patel, A., Johnston, S. G., Gagen, E. J., & Fallon, S. J. (2022) · Sedimentology · doi:10.1111/sed.12991 · Cited by 29 · see citing works
- Authors
- Radha, A. V., & Navrotsky, A.
- Affiliations
- University of California, Davis (US)
- Corresponding author
- Navrotsky, A.
- ORCID
- Navrotsky, A.
- Venue
- Reviews in Mineralogy and Geochemistry
- Publisher
- Mineralogical Society of America
- Published
- 2013-01-01
- Volume
- 77
- Issue
- 1
- Pages
- 73-121
- ISSN
- 1529-6466 (ISSN-L)
- OpenAlex
- W2113679425
- Cited by
- 70
- References
- 9
- Citations by year
- 2026: 6 · 2025: 3 · 2024: 4 · 2023: 8 · 2022: 9 · 2021: 2 · 2020: 3 · 2019: 4 · 2018: 3 · 2017: 7 · 2016: 6 · 2015: 7 · 2014: 5 · 2013: 2 · 2012: 1
- FWCI
- 3.04
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Reviews in Mineralogy and Geochemistry (publishedVersion)
- Topics
- Physical Sciences › Chemistry › Organic Chemistry › Chemical Thermodynamics and Molecular Structure
- Physical Sciences › Materials Science › Biomaterials › Calcium Carbonate Crystallization and Inhibition
- Physical Sciences › Materials Science › Materials Chemistry › Thermal and Kinetic Analysis
- Keywords
- carbonate minerals, Gibbs energy of formation, enthalpy of formation, entropy, enthalpy of solution, hydration enthalpy
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