Cited by 70Chemical Thermodynamics and Molecular StructureCalcium Carbonate Crystallization and InhibitionThermal and Kinetic Analysis

Thermodynamics of Carbonates

Radha, A. V., Navrotsky, A.·2013·Reviews in Mineralogy and Geochemistry

Abstract

Research Article| January 01, 2013 Thermodynamics of Carbonates A.V. Radha; A.V. Radha Peter A. Rock Thermochemistry Laboratory and NEAT ORU (Nanomaterials in the Environment, Agriculture, and Technology Organized Research Unit), University of California Davis, Davis, California 95616, U.S.A., ravenkat@ucdavis.edu Search for other works by this author on: GSW Google Scholar A. Navrotsky A. Navrotsky * Peter A. Rock Thermochemistry Laboratory and NEAT ORU (Nanomaterials in the Environment, Agriculture, and Technology Organized Research Unit), University of California Davis, Davis, California 95616, U.S.A., ravenkat@ucdavis.edu *corresponding author: anavrotsky@ucdavis.edu Search for other works by this author on: GSW Google Scholar Author and Article Information A.V. Radha Peter A. Rock Thermochemistry Laboratory and NEAT ORU (Nanomaterials in the Environment, Agriculture, and Technology Organized Research Unit), University of California Davis, Davis, California 95616, U.S.A., ravenkat@ucdavis.edu A. Navrotsky * Peter A. Rock Thermochemistry Laboratory and NEAT ORU (Nanomaterials in the Environment, Agriculture, and Technology Organized Research Unit), University of California Davis, Davis, California 95616, U.S.A., ravenkat@ucdavis.edu *corresponding author: anavrotsky@ucdavis.edu Publisher: Mineralogical Society of America First Online: 09 Mar 2017 © 2013 Mineralogical Society of America Reviews in Mineralogy and Geochemistry (2013) 77 (1): 73–121. https://doi.org/10.2138/rmg.2013.77.3 Article history First Online: 09 Mar 2017 Cite View This Citation Add to Citation Manager Share Icon Share Facebook Twitter LinkedIn Email Permissions Search Site Citation A.V. Radha, A. Navrotsky; Thermodynamics of Carbonates. Reviews in Mineralogy and Geochemistry 2013;; 77 (1): 73–121. doi: https://doi.org/10.2138/rmg.2013.77.3 Download citation file: Ris (Zotero) Refmanager EasyBib Bookends Mendeley Papers EndNote RefWorks BibTex toolbar search Search Dropdown Menu toolbar search search input Search input auto suggest filter your search All ContentBy SocietyReviews in Mineralogy and Geochemistry Search Advanced Search The goal of geologic CO2 sequestration is not just to pump large volumes of supercritical carbon dioxide into underground repositories but to keep it there for hundreds to thousands of years, preferably in chemically bound form. The permanence of CO2 storage in geological repositories is important since large leakage rates would diminish the CO2 abatement achieved with carbon capture and sequestration (CCS). Effective permanent geologic CO2 storage depends ultimately on the interactions of the supercritical CO2 with the minerals and fluids present in the host underground repositories and their caprock sealing (Xu et al.... You do not have access to this content, please speak to your institutional administrator if you feel you should have access.

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Crossref · 10.2138/rmg.2013.77.3

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  • The interfacial free energy of the mineral with respect to its solution is a key parameter that determines its nucleation rate.

    “The interfacial free energy of the mineral with respect to its solution is a key parameter that determines its nucleation rate.”
  • A variety of precursor phases exist in the early stages of carbonate crystallization, including prenucleation clusters, metastable liquid-like precursors, mesocrystals and amorphous and nanophase precursors.

    “Recent studies have shown that a variety of precursor phases exist in the early stages of carbonate crystallization, including prenucleation clusters, metastable liquid-like precursors, mesocrystals and amorphous and nanophase precursors [114-123].”
  • Crystal nucleation and growth are free-energy-driven phenomena and reflect solution supersaturation.

    “Crystal nucleation and growth are free-energy-driven phenomena and reflect solution supersaturation [121].”

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Authors
Radha, A. V., & Navrotsky, A.
Affiliations
University of California, Davis (US)
Corresponding author
Navrotsky, A.
Venue
Reviews in Mineralogy and Geochemistry
Published
2013-01-01
Volume
77
Issue
1
Pages
73-121
ISSN
1529-6466 (ISSN-L)
OpenAlex
W2113679425
Cited by
70
References
9
Citations by year
2026: 6 · 2025: 3 · 2024: 4 · 2023: 8 · 2022: 9 · 2021: 2 · 2020: 3 · 2019: 4 · 2018: 3 · 2017: 7 · 2016: 6 · 2015: 7 · 2014: 5 · 2013: 2 · 2012: 1
FWCI
3.04
Type
journal article
Language
en
Open access
closed
Locations
Reviews in Mineralogy and Geochemistry (publishedVersion)
Topics
  • Physical Sciences › Chemistry › Organic Chemistry › Chemical Thermodynamics and Molecular Structure
  • Physical Sciences › Materials Science › Biomaterials › Calcium Carbonate Crystallization and Inhibition
  • Physical Sciences › Materials Science › Materials Chemistry › Thermal and Kinetic Analysis
Keywords
carbonate minerals, Gibbs energy of formation, enthalpy of formation, entropy, enthalpy of solution, hydration enthalpy

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