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Electrocatalysis of the HER in acid and alkaline media

Open access
Danilovic, Nemanja, Subbaraman, Ram, Strmcnik, Dusan, Stamenkovic, Vojislav, Markovic, Nenad·2013·Journal of the Serbian Chemical Society

Abstract

Trends in the HER are studied on selected metals (M= Cu, Ag, Au, Pt, Ru, Ir, Ti) in acid and alkaline environments. We found that with the exception of Pt, Ir and Au, due to high coverage by spectator species on non-noble metal catalysts, experimentally established positions of Cu , Ag, Ru and Ti in the observed volcano relations are still uncertain. We also found that while in acidic solutions the M-Hupd binding energy most likely is controlling the activity trends, the trends in activity in alkaline solutions are controlled by a delicate balance between two descriptors: the M-Had interaction as well as the energetics required to dissociate water molecules. The importance of the second descriptor is confirmed by introducing bifunctional catalysts such as M modified by Ni(OH); e.g. while the latter serves to enhance catalytic decomposition of water, the metal sites are required for collecting and recombining the produced hydrogen intermediates.

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Metadata

Authors
Danilovic, N., Subbaraman, R., Strmcnik, D., Stamenkovic, V., & Markovic, N.
Venue
Journal of the Serbian Chemical Society
Published
2013
Volume
78
Issue
12
Pages
2007-2015
ISSN
  • 0352-5139 (ISSN-L)
  • 1820-7421
OpenAlex
W2059605953
Cited by
190
References
0
FWCI
1.92
Type
journal article
Language
en
Open access
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CoChat. (2026). Citation check: Electrocatalysis of the HER in acid and alkaline media. https://app.cochat.ai/papers/10.2298/jsc131118136d
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Danilovic, N., Subbaraman, R., Strmcnik, D., Stamenkovic, V., & Markovic, N. (2013). Electrocatalysis of the HER in acid and alkaline media. Journal of the Serbian Chemical Society. https://doi.org/10.2298/jsc131118136d

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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

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