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Electrocatalysis of the HER in acid and alkaline media
Open accessAbstract
Trends in the HER are studied on selected metals (M= Cu, Ag, Au, Pt, Ru, Ir, Ti) in acid and alkaline environments. We found that with the exception of Pt, Ir and Au, due to high coverage by spectator species on non-noble metal catalysts, experimentally established positions of Cu , Ag, Ru and Ti in the observed volcano relations are still uncertain. We also found that while in acidic solutions the M-Hupd binding energy most likely is controlling the activity trends, the trends in activity in alkaline solutions are controlled by a delicate balance between two descriptors: the M-Had interaction as well as the energetics required to dissociate water molecules. The importance of the second descriptor is confirmed by introducing bifunctional catalysts such as M modified by Ni(OH); e.g. while the latter serves to enhance catalytic decomposition of water, the metal sites are required for collecting and recombining the produced hydrogen intermediates.
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Cited by
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McCrory, C. C. L., Jung, S., Ferrer, I. M., Chatman, S. M., Peters, J. C., & Jaramillo, T. F. (2015) · Journal of the American Chemical Society · doi:10.1021/ja510442p · Cited by 4,145
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Metadata
- Authors
- Danilovic, N., Subbaraman, R., Strmcnik, D., Stamenkovic, V., & Markovic, N.
- Venue
- Journal of the Serbian Chemical Society
- Publisher
- National Library of Serbia
- Published
- 2013
- Volume
- 78
- Issue
- 12
- Pages
- 2007-2015
- ISSN
- 0352-5139 (ISSN-L)
- 1820-7421
- OpenAlex
- W2059605953
- Cited by
- 190
- References
- 0
- FWCI
- 1.92
- Type
- journal article
- Language
- en
- Open access
- diamond
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- Danilovic, N., Subbaraman, R., Strmcnik, D., Stamenkovic, V., & Markovic, N. (2013). Electrocatalysis of the HER in acid and alkaline media. Journal of the Serbian Chemical Society. https://doi.org/10.2298/jsc131118136d
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