Synthesis of protodolomite from aqueous solution at normal temperature and pressure.
Open accessAbstract
To estimate the conditions of the protodolomite formation, laboratory syntheses from simple aqueous solutions have been carried out under normal temperature and pressure conditions. Protodolomites have been synthesized from CaCl2 + MgCl2 + (NaCl) + NaHCO3 solutions. This paper shows the concentrations of calcium and magnesium ions in the parent solution, which are required for the protodolomite formation. The synthesis experiment indicates that concentrated seawater is favorable to the protodolomite formation. That is, the high value of [Mg2+] / [Ca2+], and the high concentrations of sodium and chlorine ions in a parent solution are favorable to the protodolomite formation.
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Only a few experimental studies have attempted to quantify the fundamental reactions controlling the formation of inorganic dolomite directly from solution.
“Only a few experimental studies have attempted to quantify the fundamental reactions controlling the formation of inorganic dolomite 'directly' from solution (Ohde and Kitano 1978; Kelleher and Redfern 2002; Schmidt et al. 2005).”
From A route for the direct crystallization of dolomite (2015) · cites this paper as Ohde and Kitano 1978
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- Authors
- Ohde, S., & Kitano, Y.
- Affiliations
- Nagoya University (JP)
- Venue
- GEOCHEMICAL JOURNAL
- Publisher
- Geochemical Society of Japan
- Published
- 1978
- Volume
- 12
- Issue
- 2
- Pages
- 115-119
- ISSN
- 0016-7002 (ISSN-L)
- OpenAlex
- W2031682844
- Cited by
- 28
- References
- 39
- Citations by year
- 2024: 1 · 2022: 1 · 2020: 2 · 2019: 1 · 2018: 1 · 2015: 1 · 2014: 2 · 2012: 1
- FWCI
- 2.59
- Type
- journal article
- Language
- en
- Open access
- diamond
- doi.org
- Locations
- GEOCHEMICAL JOURNAL (publishedVersion)
- Topics
- Physical Sciences › Earth and Planetary Sciences › Geochemistry and Petrology › Geochemistry and Elemental Analysis
- Physical Sciences › Materials Science › Biomaterials › Calcium Carbonate Crystallization and Inhibition
- Physical Sciences › Earth and Planetary Sciences › Paleontology › Paleontology and Stratigraphy of Fossils
- Keywords
- protodolomite, dolomite formation, dolomitization, aqueous synthesis, seawater, sodium and chloride ions, Mg/Ca ratio, carbonate precipitation
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