The DOI matches its Crossref record.
Stability of some carbonates at 25 degrees C and one atmosphere total pressure
Abstract
The stabilities of a number of carbonates, both minerals and synthetic compounds, were determined by dissolving them in water saturated with 1 atm. carbon dioxide at 25 degrees C. and 1 atm. total pressure. The pH of the solution was monitored continuously and the equilibrium value determined by extrapolating the pH-time data to infinite time. This equilibrium pH value was used to obtain the standard free energies of formation of the carbonates. The values obtained are listed below and are compared, where data are available, with values listed in U.S. Bureau of Standards Circular 500 or in Latimer9s Oxidation Potentials.
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In the citing paper
“The Gibbs energies of formation (ΔGf°) of MnCO3 range from − 809.89 kJ/mol to − 818.81 kJ/mol with solubility products (log_Ksp) from − 9.43 to − 10.99 [5, 14].”
From Dissolution and solubility of calcite-rhodochrosite solid solutions [(Ca1-xMnx)CO3] at 25 °C (2021) · cites this paper as [14]
In the citing paper
“Additionally, CaCO3 has a very well-defined solubility product (log_Ksp) reported to fall within − 8.30 [14, 38].”
From Dissolution and solubility of calcite-rhodochrosite solid solutions [(Ca1-xMnx)CO3] at 25 °C (2021) · cites this paper as [14]
In the citing paper
“The various ΔGf° values for MnCO3(s) found in the literature ranged from − 809.89 ± 0.73 kJ/mol [5] to − 818.81 kJ/mol [14], including − 812.53 kJ/mol [45], − 813.0 kJ/mol [39], − 814.6 kJ/mol [14], − 816.05 ± 1.38 kJ/mol [46], − 816.32 ± 0.07 kJ/mol [41], − 816.6 ± 0.2 kJ/mol [47] and − 816.7 kJ/mol [42].”
From Dissolution and solubility of calcite-rhodochrosite solid solutions [(Ca1-xMnx)CO3] at 25 °C (2021) · cites this paper as [14]
In the citing paper
“The solubilities of the MnxCa1-xCO3 solid solutions in the present work were generally lower than the data calculated using the empirical expression derived from the experimental electrochemical cell data [5], which was related to the ΔGf° value of − 809.89 ± 0.73 kJ/mol for MnCO3 being too large in comparison to those (− 812.53 ~ − 818.81 kJ/mol) in the present work and other studies [14, 39, 41,”
From Dissolution and solubility of calcite-rhodochrosite solid solutions [(Ca1-xMnx)CO3] at 25 °C (2021) · cites this paper as [14]
Citations
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Sorted by citations
Plummer, L. N., & Busenberg, E. (1982) · Geochimica et Cosmochimica Acta · doi:10.1016/0016-7037(82)90056-4 · Cited by 1,886
Calcium Carbonate Formation and Dissolution
Morse, J. W., Arvidson, R. S., & Lüttge, A. (2007) · Chemical Reviews · doi:10.1021/cr050358j · Cited by 1,228
The dissolution kinetics of major sedimentary carbonate minerals
Morse, J. W., & Arvidson, R. S. (2002) · Earth-Science Reviews · doi:10.1016/s0012-8252(01)00083-6 · Cited by 766
Complete oxidation of solid phase sulfides by manganese and bacteria in anoxic marine sediments
Aller, R. C., & Rude, P. D. (1988) · Geochimica et Cosmochimica Acta · doi:10.1016/0016-7037(88)90335-3 · Cited by 409
Davis, J. A., Fuller, C. C., & Cook, A. D. (1987) · Geochimica et Cosmochimica Acta · doi:10.1016/0016-7037(87)90330-9 · Cited by 375
Metadata
- Authors
- Garrels, R. M., Thompson, M. E., & Siever, R.
- Venue
- American Journal of Science
- Publisher
- American Journal of Science (AJS)
- Published
- 1960-06-01
- Volume
- 258
- Issue
- 6
- Pages
- 402-418
- ISSN
- 0002-9599 (ISSN-L)
- OpenAlex
- W2014901561
- Cited by
- 297
- References
- 0
- Citations by year
- 2025: 1 · 2024: 4 · 2023: 5 · 2022: 7 · 2021: 5 · 2020: 2 · 2019: 1 · 2018: 3 · 2017: 1 · 2016: 66 · 2015: 1 · 2014: 5 · 2013: 10 · 2012: 3
- FWCI
- 6.65
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- American Journal of Science (publishedVersion)
- Topics
- Physical Sciences › Chemistry › Organic Chemistry › Chemical Thermodynamics and Molecular Structure
- Physical Sciences › Chemical Engineering › Filtration and Separation › Chemical and Physical Properties in Aqueous Solutions
- Physical Sciences › Environmental Science › Environmental Engineering › CO2 Sequestration and Geologic Interactions
- Keywords
- carbonate stability, standard Gibbs energy of formation, carbonate minerals, equilibrium pH, oxidation potential, thermodynamic data
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