A study on coating with nanoclay on the production of flame retardant cotton fabrics
Open accessAbstract
In this study, flame retardant properties of 100% cotton fabrics were tried to be improved by using commercial nanoclay (Cloisite 20A) which is a clay based montmorillonite. Flame retardancy and thermal decomposition behavior of the samples were characterized by the vertical burning test, limiting oxygen index (LOI), and thermogravimetric analysis (TGA). The surface morphology of untreated and treated fabric was examined using a scanning electron microscope (SEM). Fourier-transform infrared spectroscopy (FTIR) analysis was carried out for Cloisite 20A, untreated and coated fabrics. The results of the tests showed that the coating treatment even at low nanoclay concentration is enough to have a considerable flame retardant effect. This result was attributed to the barrier effect of the nanoclay.
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Claims other papers make about this one
Each is checked against this paper’s own text: does it say what the citing paper says it does?
In the FTIR spectrum of MMT, bands at 1117 cm−1 and 1013 cm−1 are assigned to in-plane stretching vibrations of Si-O in the silicate network.
“In the spectrum of MMT, bands at 1117 cm⁻¹ and 1013 cm⁻¹ were assigned to in-plane stretching vibrations of Si-O in the silicate network”
From Montmorillonite-reinforced methacrylated collagen/methacrylated silk fibroin hydrogel-based inks: rheological and physicochemical characterization for bone scaffold applications (2026) · cites this paper as [62]
Section 3.3 (FTIR analysis; page unavailable) assigns the 1117 and 1013 cm⁻¹ bands in the Cloisite 20A spectrum to Si–O stretching. It does not specify that the stretching is in-plane, and it reports the spectrum of Cloisite 20A rather than MMT generally. (LLM, conf=0.88)
Experimental — accuracy not yet measuredIn the FTIR spectrum of MMT, bands at 917 cm−1 and 883 cm−1 correspond to bending vibrations of Al-Al-OH and Al-Fe-OH groups, respectively.
“bands at 917 cm⁻¹ and 883 cm⁻¹ correspond to bending vibrations of Al-Al-OH and Al-Fe-OH groups, respectively[62,63].”
From Montmorillonite-reinforced methacrylated collagen/methacrylated silk fibroin hydrogel-based inks: rheological and physicochemical characterization for bone scaffold applications (2026) · cites this paper as [62]
Section 3.3 (FTIR analysis) and Table 5 list bands for Cloisite 20A, but neither assigns bands at 917 or 883 cm⁻¹ to Al-Al-OH or Al-Fe-OH bending. Searches for those wavenumbers and groups found no passage in our copy addressing the claimed assignments; page numbers were not available. (LLM, conf=0.76)
Experimental — accuracy not yet measured
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Cites
Hybrid materials based on clays for environmental and biomedical applications
Ruiz-Hitzky, E., Aranda, P., Darder, M., & Rytwo, G. (2010) · Journal of Materials Chemistry · doi:10.1039/c0jm00432d · Cited by 325 · see citing works
Flagged first, then by citations
Research works printed but not linked: 41
- Cordner A, Mulcahy M, Brown P. 2013. Chemical regulation on fire: rapid policy advances on flame retardants. Environmental Science & Technology. https://doi.org/10.1021/es3036237. · DOI
- Gao D, Li R, Lv B, Ma J, Tian F, Zhang J. 2015. Flammability, thermal and physical-mechanical properties of cationic polymer/montmorillonite composite on cotton fabric. Composites Part B. https://doi.org/10.1016/j.compositesb.2015.03.061. · DOI
- Holder KM, Smith RJ, Grunlan JC. 2017. A review of flame retardant nanocoatings prepared using layer-by-layer assembly of polyelectrolytes. J Materials Science and Engineering. https://doi.org/10.1007/s10853-017-1390-1. · DOI
- Du L, Xu G, Zhang Y, Qian J, Chen J. 2011. Synthesis and properties of a novel intumescent flame retardant (IFR) and its application in halogen-free flame retardant ethylene propylene diene terpolymer (EPDM). Polymer Plastics Technology and Engineering. https://doi.org/10.1080/03602559.2010.543224. · DOI
- Yuan H, Xing W, Zhang P, Song L, Hu Y. 2012. Functionalization of cotton with UV cured flame retardant coatings. Industrial & Engineering Chemistry Research. https://doi.org/10.1021/ie202468u. · DOI
- Zhang DQ, Williams BL, Shrestha SB, Nasir Z, Becher EM, Lofink BJ, Santos VH, Patel H, Peng XH, Sun LY. 2017. Flame retardant and hydrophobic coatings on cotton fabrics via sol-gel and self-assembly techniques. Journal of Colloid And Interface Science. https://doi.org/10.1016/j.jcis.2017.06.087. · DOI
- Başyiğit ZO, Kut D. 2018. Formaldehyde-free and halogen-free flame retardant finishing on cotton fabric. Tekstil ve Konfeksiyon. https://doi.org/10.32710/tekstilvekonfeksiyon.482884. · DOI
- Ghoranneviss M, Shahidi S. 2014. Flame retardant properties of plasma pretreated/metallic salt loaded cotton fabric before and after direct dyeing. Journal Of Fusion Energy. https://doi.org/10.1007/s10894-013-9642-9. · DOI
- Carosio F, Alongi J, Malucelli G. 2012. Layer by layer ammonium polyphosphate based coatings for flame retardancy of polyester-cotton blends. Carbohydrate Polymers. https://doi.org/10.1016/j.carbpol. 2012.02.049. · DOI
- Shahidi S, Ghoranneviss M. 2014. Effect of plasma pretreatment followed by nanoclay loading on flame retardant properties of cotton fabric. J Journal Of Fusion Energy. https://doi.org/10.1007/s10894- 013-9645-6. · DOI
- Ghosh A. 2011. Nano-clay particle as textile coating. International Journal Of Engineering Science Technologies IJET-IJENS 11(5), p.34-36.
- Uddin F. 2008. Clays, nanoclays and montmorillonite minerals. Metallurgical and Materials Transactions. https://doi.org/10.1007/ s11661-008-9603-5. · DOI
- Shah AR, Prabhakar MN, Song J. 2017. Current advances in the fire retardancy of natural fiber and bio-based composites: A Review. International Journal of Precision Engineering and Manufacturing- Green Technology. https://doi.org/10.1007/s40684-017-0030-1. · DOI
- Guo Y, Chang CC, Halada G, Cuiffo MA, Xue Y, Zuo X, Pack S, Zhang L, He S, Weil E Rafailovich MH. (2017). Engineering flame retardant biodegradable polymer nanocomposites and their application in 3D printing. Polymer Degradation and Stability. https://doi.org/ 10.1016/j.polymdegradstab.2017.01.019. · DOI
- Majka TM, Leszczyńska A, Kandola BK, Pornwannachai W, Pielichowski K. 2017. Modification of organo-montmorillonite with disodium H-phosphonate to develop flame retarded polyamide 6 nanocomposites. Applied Clay Science. https://doi.org/10.1016/j. clay.2017.01.012. · DOI
- Makhlouf G, Hassan M, Nour M, Abdel-monem YK, Abdelkhalik A. 2017. A novel intumescent flame retardant: synthesis and its application for linear low-density polyethylene. Arabian Journal For Science And Engineering. https://doi.org/10.1007/s13369-017- 2443-0. · DOI
- Rehan M, El-Naggar ME, Mashaly HM, Wilken R. 2018. Nanocomposites based on chitosan/silver/clay for durable multi- functional properties of cotton fabrics. Carbohydrate Polymers. https://doi.org/10.1016/j.carbpol.2017.11.007. · DOI
- Chowdary MS, Kumar M. 2015. Effect of nanoclay on the mechanical properties of polyester and s-glass fiber (Al). International Journal of Animal Science and Technology. http://dx.doi.org/10.14257/ijast. 2015.74.04. · DOI
- Bhat G, Hegde RR, Kamath MG, Deshpande B. 2008. Nanoclay reinforced fibers and nonwovens. Journal of Engineered Fibers and Fabrics. https://doi.org/10.1177/155892500800300303. · DOI
- Qiu X, Li Z, Li X, Zhang Z. 2017. Flame retardant coatings prepared using layer by layer assembly: A review. Chemical Engineering Science. https://doi.org/10.1016/j.cej.2017.09.194. · DOI
- Zhu H., J. Njuguna. 2014. Nanolayered silicates/clay minerals: uses and effects on health. In Njuguna J., Pielichowski K., Zhu H. (Eds.), Health and Environmental Safety of Nanomaterials. The Netherlands, Woodhead Publishing, p.133-146.
- Yapar S., Özdemir G., Fernández Solarte A.M., Torres Sánchez R.M. 2015. Surface and Interface Properties of Lauroyl Sarcosinate- Adsorbed CP + -Montmorillonite. Clays and Clay Minerals. Vol. 63, No. 2, p.110-118 https://doi.org/10.1346/CCMN.2015.0630203). · DOI
- Erkan I., Alp I., Çelik M.S. 2010. Characterization of organo- bentonites obtained from different linear-chain quaternary alkylammonium salts. Clays and Clay Minerals. Vol.58, p.792-802.
- Schumann D., Hesse R., Sears S.K., Vali H. 2014. Expansion behavior of octadecylammonium-exchanged low to high-charge reference smectite-group minerals as revealed by high-resolution transmission electron microscopy on ultrathin sections. Clays and Clay Minerals. Vol.62, p.336-353.
- Zeng QH, Yu AB, Lu GQ, Paul DR. 2005. Clay-based polymer nanocomposites: research and commercial development. Journal Of Nanoscience And Nanotechnology. https://doi.org/10.1166/jnn.2005.411. · DOI
- Mittal G, Rhee KY, Mišković-Stanković V, Hui D. 2018. Reinforcements in multi-scale polymer composites: Processing, properties, and applications. Composites Part B-Engineering. https://doi.org/10.1016/j.compositesb.2017.11.028. · DOI
- Azeez AA, Rhee KY, Park SJ, Hui D. 2013. Epoxy clay nanocomposites -processing, properties and applications: A review. Composites Part B-Engineering. https://doi.org/10.1016/ j.compositesb.2012.04.012. · DOI
- Yelkovan S, Yılmaz D, Aksoy K. 2014. A study of organo-modified clay type on pet-clay based nanocomposite properties. Materials Science. Vol.3, No.1, p.33-46.
- Visakh PM. 2015. Advances in flame retardant of different types of nanocomposites. In: PM. Visakh, Y. Arao (Eds.), In Flame Retardants: Polymer Blends, Composites and Nanocomposites, Springer Press, New York, p.1-14.
- Cao GF, Sun Y, Chen JG, Song LP, Jiang JQ, Liu ZT, Liu ZW. 2014. Sutures modified by silver-loaded montmorillonite with antibacterial properties. Applied Clay Science. https://doi.org/10.1016/j .clay.2014.03.007. · DOI
- Bourbigot S, Devaux E, Flambard X. 2002. Flammability of polyamide-6/clay hybrid nanocomposite textiles. Polymer Degradation and Stability. https://doi.org/10.1016/S0141-3910(01) 00245-2. · DOI
- Li YC, Schulz J, Mannen S, Delhom C, Condon B, Chang S, Zammarano M, Grunlan JC. 2010. Flame retardant behavior of polyelectrolyte-clay thin film assemblies on cotton fabric. ACS Nano. https://doi.org/10.1021/nn100467e. · DOI
- Norouzi M., Zare Y., Kiany P. 2015. Nanoparticles as Effective Flame Retardants for Natural and Synthetic Textile Polymers: Application, Mechanism, and Optimization. Polymer Review. Vol.55, No.3, pp.531-560, doi: 10.1080/15583724.2014.980427 · DOI
- Rault F., Giraud S., Salaün F. 2015. Flame retardant/resistant based nanocomposites in textile. In Visakh M.P., Arao Y. (Eds.), Flame Retardants: Polymer Blends, Composites and Nanocomposites. Switzerland, Springer International Publishing: Cham, p.131-165.
- Devaux E, Rochery M, Bourbigot S. 2002. Polyurethane/clay andpolyurethane/POSS nanocomposites as flame retarded coating for polyester and cotton fabrics. Fire and Materials. Vol.26, p.149-154.
- Fabia J., Gawłowski A., Rom M., Ślusarczyk C., Brzozowska-Stanuch A., Sieradzka M. 2020. PET fibers modified with cloisite nanoclay. Polymers. Vol.12, No.4, p.1-19.
- Zhu P, Sui S, Wang B, Sun K, Sun G. 2004. A study of pyrolysis and pyrolysis products of flame-retardant cotton fabrics by DSC, TGA, and PY-GC-MS. Journal of Analytical and Applied Pyrolysis. https://doi.org/10.1016/j.jaap.2003.09.005. · DOI
- Zhu FL, Li KJ. 2011. Numerical modeling of heat and moisture through wet cotton fabric using the method of chemical thermodynamic law under simulated fire. Fire Technology. https://doi.org/10.1007/s10694-010-0201-x. · DOI
- Yapar S. 2009. Physicochemical study of microwave-synthesized organoclays. Colloids and Surfaces A: Physicochemical and Engineering Aspects. https://doi.org/10.1016/j.colsurfa.2009.04.032. · DOI
- Madejová J, Komadel P. 2001. Baseline studies of the clay minerals source society: infrared methods. Clays and Clay Minerals.Vol.49, No.5, p.410-432.
- Sartori C. 1997. The characterisation of alginate systems for biomedical applications (Doctoral dissertation). Brunel University, Department of Materials Engineering, London.
Cited by
Sorted by citations
Antunes, B. S. L., Pedrini, F., Komatsu, D., Asami, J., Dicko, C., & Duek, E. A. R. (2026) · International Journal of Biological Macromolecules · doi:10.1016/j.ijbiomac.2026.154129
- Authors
- KERTMEN, N., DALBAŞI, E. S., KÖRLÜ, A., ÖZGÜNEY, A., & YAPAR, S.
- Affiliations
- Ege University (TR)
- Ege University, Engineering Faculty, Textile Engineering Department, 35100 Bornova, İzmir, TURKEY
- Venue
- Tekstil ve Konfeksiyon
- Publisher
- Tekstil Ve Konfeksiyon
- Published
- 2020-12-29
- Volume
- 30
- Issue
- 4
- Pages
- 302-311
- ISSN
- 1300-3356 (ISSN-L)
- OpenAlex
- W3110780689
- Cited by
- 5
- References
- 1
- Citations by year
- 2025: 2 · 2023: 3
- FWCI
- 0.28
- Type
- journal article
- Language
- en
- Open access
- bronze
- doi.org
- Locations
- TEKSTİL VE KONFEKSİYON (publishedVersion)
- DergiPark (Istanbul University) (submittedVersion)
- Funders
- Ege Üniversitesi Bilimsel Araştırma Projeleri Koordinatörlüğü (16 MÜH-077)
- Topics
- Physical Sciences › Materials Science › Polymers and Plastics › Flame retardant materials and properties
- Physical Sciences › Materials Science › Polymers and Plastics › Polymer Nanocomposites and Properties
- Physical Sciences › Engineering › Building and Construction › Dyeing and Modifying Textile Fibers
- Keywords
- flame retardant cotton fabric, Cloisite 20A, montmorillonite, flame retardancy, thermal decomposition, limiting oxygen index, vertical burning test, fabric surface morphology
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review