The Application of Catalytic Processes on the Production of Algae-Based Biofuels: A Review
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Abstract
Over the last decades, microalgal biomass has gained a significant role in the development of different high-end (nutraceuticals, colorants, food supplements, and pharmaceuticals) and low-end products (biodiesel, bioethanol, and biogas) due to its rapid growth and high carbon-fixing efficiency. Therefore, microalgae are considered a useful and sustainable resource to attain energy security while reducing our current reliance on fossil fuels. From the technologies available for obtaining biofuels using microalgae biomass, thermochemical processes (pyrolysis, Hydrothermal Liquefaction (HTL), gasification) have proven to be processed with higher viability, because they use all biomass. However, due to the complex structure of the biomass (lipids, carbohydrates, and proteins), the obtained biofuels from direct thermochemical conversion have large amounts of heteroatoms (oxygen, nitrogen, and sulfur). As a solution, catalyst-based processes have emerged as a sustainable solution for the increase in biocrude production. This paper’s objective is to present a comprehensive review of recent developments on the catalyst-mediated conversion of algal biomass. Special attention will be given to operating conditions, strains evaluated, and challenges for the optimal yield of algal-based biofuels through pyrolysis and HTL.
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Catalyst type, quantity, price, bottlenecks in recovery, and deactivation process after a certain period in continuous operation are difficulties appointed in the literature.
“the catalyst type, quantity, price, bottlenecks in recovery, and the deactivation process after a certain period in a continuous operation are also difficulties appointed in the literature [116–118].”
From Research Progress, Trends, and Future Prospects on Hydrothermal Liquefaction of Algae for Biocrude Production: A Bibliometric Analysis (2024) · cites this paper as [118]
Biocrude may cause corrosion in equipment.
“the biocrude may cause corrosion in equipment”
From Research Progress, Trends, and Future Prospects on Hydrothermal Liquefaction of Algae for Biocrude Production: A Bibliometric Analysis (2024) · cites this paper as [118]
There are few studies on understanding the pathway for co-HTL at a molecule level.
“there are few studies on understanding the pathway for the co-HTL at a molecule level”
From Research Progress, Trends, and Future Prospects on Hydrothermal Liquefaction of Algae for Biocrude Production: A Bibliometric Analysis (2024) · cites this paper as [118]
Direct combustion of biocrude may lead to high NOx emissions due to high amounts of nitrogen contained in microalgae cells.
“the direct combustion may lead to high NOx emissions, due to the high amounts of nitrogen contained in microalgae cells [93, 117, 118].”
From Research Progress, Trends, and Future Prospects on Hydrothermal Liquefaction of Algae for Biocrude Production: A Bibliometric Analysis (2024) · cites this paper as [118]
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References 210 · Cited by 68
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- 035. · DOI
- Authors
- Zuorro, A., García-Martínez, J. B., & Barajas-Solano, A. F.
- Affiliations
- Sapienza University of Rome (IT)
- Department of Environmental Sciences, Universidad Francisco de Paula Santander, Av. Gran Colombia No. 12E-96, Cucuta 540003, Colombia
- Universidad Francisco de Paula Santander (CO)
- Corresponding author
- Zuorro, Antonio
- Venue
- Catalysts
- Publisher
- MDPI AG
- Published
- 2020-12-28
- Volume
- 11
- Issue
- 1
- Pages
- 22
- ISSN
- 2073-4344 (ISSN-L)
- OpenAlex
- W3126040288
- Cited by
- 68
- References
- 210
- Citations by year
- 2026: 6 · 2025: 12 · 2024: 13 · 2023: 13 · 2022: 16 · 2021: 8
- FWCI
- 2.91
- Type
- journal article
- Language
- en
- Open access
- gold
- doi.org
- Licence
- Locations
- Catalysts (publishedVersion, cc-by)
- Preprints.org (acceptedVersion, cc-by)
- IRIS Research product catalog (Sapienza University of Rome) (submittedVersion, cc-by)
- Repositorio Universidad Francisco de Paula Santander (submittedVersion, cc-by)
- DOAJ (DOAJ: Directory of Open Access Journals) (submittedVersion, cc-by-sa)
- Funders
- Ministerio de Ciencia, Tecnología e Innovación
- Sapienza Università di Roma
- Topics
- Physical Sciences › Engineering › Biomedical Engineering › Thermochemical Biomass Conversion Processes
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Algal biology and biofuel production
- Physical Sciences › Engineering › Mechanical Engineering › Catalysis and Hydrodesulfurization Studies
- Keywords
- microalgae, algal biofuels, catalytic conversion, pyrolysis, hydrothermal liquefaction, gasification, biocrude, heteroatom content, algal biomass, bio-oil upgrading, microalgae strains
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