Cited by 75Natural Fiber Reinforced Compositesbiodegradable polymer synthesis and propertiesNanocomposite Films for Food Packaging

Mechanical Reinforcement by Microalgal Biofiller in Novel Thermoplastic Biocompounds from Plasticized Gluten

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Ciapponi, Riccardo, Turri, Stefano, Levi, Marinella·2019·Materials

Abstract

The aim of this work was to develop new bioplastic compounds from wheat gluten, biobased plasticizers (glycerol, octanoic acid and 1,4-butanediol), and microalgal biomass as a filler. The effects of the composition on tensile properties, thermal stability, and water sensitivity were investigated. Microalgal biomass was added with the selected quantities: 10, 20, and 30 per hundred parts (php). Mechanical mixing of the components, i.e., gluten, plasticizer, and microalgae, was followed by molding in a hot press. Microlgal filler improved mechanical properties of the plasticized gluten material: in samples plasticized with 1,4-butanediol, 30 php of biomass increased the tensile modulus by nearly one order of magnitude, from 36.5 MPa to 273.1 MPa, and it also increased the tensile strength from 3.3 MPa to 4.9 MPa. The introduction of microalgal biomass slightly increased the surface sensitivity against water: 30 php of biomass reduced the water contact angle from 41° to 22° in samples plasticized with glycerol, but the biomass lowered the overall water absorption kinetics for material with each plasticizer. Microalgal biomass proved therefore to be an interesting sustainable resource with which to develop materials based on gluten, in particular to increase the mechanical properties of the compounds without reducing thermal stability or water resistance.

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References 34 · Cited by 75

Authors
Ciapponi, R., Turri, S., & Levi, M.
Affiliations
  • National Interuniversity Consortium of Materials Science and Technology (IT)
  • Politecnico di Milano (IT)
Corresponding author
Ciapponi, Riccardo
Venue
Materials
Publisher
MDPI AG
Published
2019-05-07
Volume
12
Issue
9
Pages
1476
ISSN
1996-1944 (ISSN-L)
OpenAlex
W2944341485
Cited by
75
References
34
Citations by year
2026: 4 · 2025: 13 · 2024: 12 · 2023: 12 · 2022: 15 · 2021: 15 · 2020: 4
FWCI
3.63
Type
journal article
Language
en
Open access
Locations
  • Materials (publishedVersion, cc-by)
  • PubMed Central (publishedVersion, cc-by)
  • PubMed (publishedVersion)
  • DOAJ (DOAJ: Directory of Open Access Journals) (submittedVersion)
  • Virtual Community of Pathological Anatomy (University of Castilla La Mancha) (submittedVersion)
Funders
Horizon 2020 (689785)
Topics
  • Physical Sciences › Materials Science › Polymers and Plastics › Natural Fiber Reinforced Composites
  • Physical Sciences › Materials Science › Biomaterials › biodegradable polymer synthesis and properties
  • Physical Sciences › Materials Science › Biomaterials › Nanocomposite Films for Food Packaging
Keywords
wheat gluten, microalgal biomass, biocomposites, plasticizers, glycerol, 1,4-butanediol, octanoic acid, tensile properties, thermal stability, water absorption, water contact angle, hot compression molding

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