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Adsorption of Crystal Violet Dye Using Activated Carbon of Lemon Wood and Activated Carbon/Fe3O4 Magnetic Nanocomposite from Aqueous Solutions: A Kinetic, Equilibrium and Thermodynamic Study
Open accessAbstract
Activated carbon prepared from lemon (Citrus limon) wood (ACL) and ACL/Fe3O4 magnetic nanocomposite were effectively used to remove the cationic dye of crystal violet (CV) from aqueous solutions. The results showed that Fe3O4 nanoparticles were successfully placed in the structure of ACL and the produced nanocomposites showed superior magnetic properties. It was found that pH was the most effective parameter in the CV dye adsorption and pH of 9 gave the maximum adsorption efficiency of 93.5% and 98.3% for ACL and ACL/Fe3O4, respectively. The Dubinin–Radushkevich (D-R) and Langmuir models were selected to investigate the CV dye adsorption equilibrium behavior for ACL and ACL/Fe3O4, respectively. A maximum adsorption capacity of 23.6 and 35.3 mg/g was obtained for ACL and ACL/Fe3O4, respectively indicating superior adsorption capacity of Fe3O4 nanoparticles. The kinetic data of the adsorption process followed the pseudo-second order (PSO) kinetic model, indicating that chemical mechanisms may have an effect on the CV dye adsorption. The negative values obtained for Gibb’s free energy parameter (−20 < ΔG < 0 kJ/mol) showed that the adsorption process using both types of the adsorbents was physical. Moreover, the CV dye adsorption enthalpy (ΔH) values of −45.4 for ACL and −56.9 kJ/mol for ACL/Fe3O4 were obtained indicating that the adsorption process was exothermic. Overall, ACL and ACL/Fe3O4 magnetic nanocomposites provide a novel and effective type of adsorbents to remove CV dye from the aqueous solutions.
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Cites
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Adsorption of Crystal Violet from aqueous solution onto NaOH-modified rice husk
Chakraborty, S., Chowdhury, S., & Das Saha, P. (2011) · Carbohydrate Polymers · doi:10.1016/j.carbpol.2011.06.058 · Cited by 630
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Superior adsorption capacity of functionalised straw adsorbent for dyes and heavy-metal ions
Liu, Q., Li, Y., Chen, H., Lu, J., Yu, G., Möslang, M., & Zhou, Y. (2020) · Journal of Hazardous Materials · doi:10.1016/j.jhazmat.2019.121040 · Cited by 404
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Efficient encapsulation of toxic dye from wastewater using biodegradable polymeric adsorbent
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Kumar, P., Patel, A. K., Singhania, R. R., Chen, C.-W., Saratale, R. G., & Dong, C.-D. (2023) · Bioresource Technology · doi:10.1016/j.biortech.2023.129654 · Cited by 60
Tang, L., Liu, C., Liu, X., Zhang, L., Fan, B., Wang, B., & Wang, F. (2025) · Food Chemistry: X · doi:10.1016/j.fochx.2025.102311 · Cited by 32
Modeling and optimization of acid orange 7 adsorption process using magnetite/carbon nanocomposite
Nistor, M.-A., Halip, L., Muntean, S. G., Kurunczi, L., & Costișor, O. (2022) · Sustainable Chemistry and Pharmacy · doi:10.1016/j.scp.2022.100778 · Cited by 10
Metadata
- Authors
- Foroutan, R., Peighambardoust, S. J., Peighambardoust, S. H., Pateiro, M., & Lorenzo, J. M.
- Venue
- Molecules
- Publisher
- MDPI AG
- Published
- 2021-04-13
- Volume
- 26
- Issue
- 8
- Pages
- 2241
- ISSN
- 1420-3049 (ISSN-L)
- OpenAlex
- W3155924738
- Cited by
- 353
- References
- 55
- FWCI
- 15.69
- Type
- journal article
- Language
- en
- Open access
- gold
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- CoChat. (2026). Citation check: Adsorption of Crystal Violet Dye Using Activated Carbon of Lemon Wood and Activated Carbon/Fe3O4 Magnetic Nanocomposite from Aqueous Solutions: A Kinetic, Equilibrium and Thermodynamic Study. https://app.cochat.ai/papers/10.3390/molecules26082241
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- Foroutan, R., Peighambardoust, S. J., Peighambardoust, S. H., Pateiro, M., & Lorenzo, J. M. (2021). Adsorption of Crystal Violet Dye Using Activated Carbon of Lemon Wood and Activated Carbon/Fe3O4 Magnetic Nanocomposite from Aqueous Solutions: A Kinetic, Equilibrium and Thermodynamic Study. Molecules. https://doi.org/10.3390/molecules26082241
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