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Reactivity Effect of Calcium Carbonate on the Formation of Carboaluminate Phases in Ground Granulated Blast Furnace Slag Blended Cements
Open accessAbstract
The reactivity effect of calcium carbonate, present in ground oyster shells and limestone filler, on the formation of carboaluminate phases in ground granulated blast furnace slag blended cement pastes was reported in this paper. Six different binary and ternary blended cement pastes were prepared using ground granulated blast furnace slag, ground oyster shells and limestone filler with different replacement levels (from 5 to 35%). The carboaluminate formation was assessed and quantified directly using X-ray diffraction (XRD), and indirectly by following the aluminate phase’s reaction (heat flow) and consumed calcium carbonate using Isothermal Calorimetry (IC) and Thermogravimetric Analysis (TGA), respectively. Further, the overall reaction degree calculated based on TGA results and the compressive strength were determined to support the findings obtained. The results revealed that the calcium carbonate present in ground oyster shells is more reactive when compared to that present in limestone filler, where more formed hemi- and monocarboaluminate phases were observed in mixtures containing ground oyster shells. An enhancement in compressive strength and overall reaction degree was observed by adding 5% ground oyster shells as cement replacement.
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“(ii) the produced calcite reacts with aluminate (C 3 A), contributing to the formation of calcium carboaluminate phases [148,179,182,183,185].”
From An overview of utilizing CO2 for accelerated carbonation treatment in the concrete industry (2022) · cites this paper as [185]
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Metadata
- Authors
- Deboucha, W., Sebaibi, N., El Mendili, Y., Fabien, A., Alengaram, U. J., Leklou, N., Hamdadou, M. N., Bourdot, A., & Gascoin, S.
- Affiliations
- Builders École d'ingénieurs (FR)
- COMUE NU, Laboratoire de Recherche ESITC Caen, 1 Rue Pierre et Marie Curie, 14610 Epron, France
- University of Malaya (MY)
- Centre National de la Recherche Scientifique (FR)
- Corresponding author
- Deboucha, Walid
- ORCID
- Venue
- Sustainability
- Publisher
- MDPI AG
- Published
- 2021-06-07
- Volume
- 13
- Issue
- 11
- Pages
- 6504
- ISSN
- 2071-1050 (ISSN-L)
- OpenAlex
- W3170255558
- Cited by
- 35
- References
- 40
- Citations by year
- 2026: 12 · 2025: 5 · 2024: 5 · 2023: 6 · 2022: 7
- FWCI
- 2.33
- Type
- journal article
- Language
- en
- Open access
- gold
- doi.org
- Licence
- Locations
- Sustainability (publishedVersion, cc-by)
- HAL (submittedVersion, cc-by)
- HAL (submittedVersion)
- RePEc: Research Papers in Economics (submittedVersion)
- DOAJ (DOAJ: Directory of Open Access Journals) (submittedVersion, cc-by-sa)
- Topics
- Physical Sciences › Engineering › Civil and Structural Engineering › Concrete and Cement Materials Research
- Physical Sciences › Engineering › Building and Construction › Materials Engineering and Processing
- Physical Sciences › Engineering › Building and Construction › Recycling and utilization of industrial and municipal waste in materials production
- Keywords
- carboaluminate phases, ground granulated blast furnace slag, blended cement, limestone powder, monocarboaluminate, cement replacement, compressive strength, degree of reaction, heat flow
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