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Fractionnement isotopique lors des changements d’état solide-vapeur et liquide-vapeur de l’eau à des températures inférieures à 0°C
Open accessAbstract
Measurements of the hydrogen isotopic composition of water in atmospheric precipitations make possible the study of their formation and evolution, since deuterium is a natural tracer for the water molecule.In a hydrologic cycle, each change of state is accompanied by an isotopic fractionation expressed in terms of a factor ?, which is a function of temperature. This fractionation is due to differences in the physical properties of the molecules H2O and HDO. In the work described in this paper we have measured α between −40°C and 0°C for the phase equilibrium ice-water vapor and between −15°C and 0°C for the equilibrium liquid-water vapor.The values obtained may be expressed in the relationslog ?solide-vapeur= αsolide-vapeur = −4.10 · 10−2 + 7.074/T2log ?liquide-vapeur= αliquide-vapeur = −4.34 · 10−2 + 6.520/T2.
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Citations
Cited by
Deuterium and oxygen 18 in precipitation: Modeling of the isotopic effects during snow formation
Jouzel, J., & Merlivat, L. (1984) · Journal of Geophysical Research: Atmospheres · doi:10.1029/jd089id07p11749 · Cited by 833
Self-citationThe origin of Arctic precipitation under present and glacial conditions
JOHNSEN, S. J., DANSGAARD, W., & WHITE, J. W. C. (1989) · Tellus B · doi:10.1111/j.1600-0889.1989.tb00321.x · Cited by 561
Stable isotopes in atmospheric water vapor and applications to the hydrologic cycle
Galewsky, J., Steen‐Larsen, H. C., Field, R. D., Worden, J., Risi, C., & Schneider, M. (2016) · Reviews of Geophysics · doi:10.1002/2015rg000512 · Cited by 489
Equilibrium Oxygen, Hydrogen and Carbon Isotope Fractionation Factors Applicable to Geologic Systems
Chacko, T., Cole, D. R., & Horita, J. (2001) · Reviews in Mineralogy and Geochemistry · doi:10.2138/gsrmg.43.1.1 · Cited by 462
Rowley, D. B., Pierrehumbert, R. T., & Currie, B. S. (2001) · Earth and Planetary Science Letters · doi:10.1016/s0012-821x(01)00324-7 · Cited by 441
Metadata
- Authors
- Merlivat, L., & Nief, G.
- Venue
- Tellus A: Dynamic Meteorology and Oceanography
- Publisher
- Stockholm University Press
- Published
- 1967-01-01
- Volume
- 19
- Issue
- 1
- Pages
- 122
- ISSN
- 0280-6495 (ISSN-L)
- 1600-0870
- OpenAlex
- W1979180024
- Cited by
- 205
- References
- 0
- FWCI
- 6.95
- Type
- journal article
- Language
- fr
- Open access
- bronze
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- CoChat. (2026). Citation check: Fractionnement isotopique lors des changements d’état solide-vapeur et liquide-vapeur de l’eau à des températures inférieures à 0°C. https://app.cochat.ai/papers/10.3402/tellusa.v19i1.9756
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- Merlivat, L., & Nief, G. (1967). Fractionnement isotopique lors des changements d’état solide-vapeur et liquide-vapeur de l’eau à des températures inférieures à 0°C. Tellus A: Dynamic Meteorology and Oceanography. https://doi.org/10.3402/tellusa.v19i1.9756
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