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Recording and Analysis of AC Impedance Data for Corrosion Studies
Abstract
A brief review is given of the application of AC impedance measurements to electrochemical processes. Only very few applications for corrosion processes have been reported. The background and various methods of analysis of AC impedance data are discussed. The parameters which characterize the corrosion behavior can be determined from plots of the frequency dependence of the impedance in the complex plane which result in semicircles for very simple cases. These parameters can also be determined from straight line plots of the real part Z′ vs ωZ″ or Z″/ω, where Z″ is the imaginary part of the impedance and the frequency f is expressed as ω = 2πf. Additional methods of analysis include evaluation of the frequency dependence of the series resistance Rs and series capacitance Cs, the absolute value of the impedance |Z| and the phase angle δ. Experimental results obtained with a system for automatic recording and analysis of impedance data are given for a dummy cell which represents a corroding electrode.
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Cites
Dispersion and Absorption in Dielectrics I. Alternating Current Characteristics
Cole, K. S., & Cole, R. H. (1941) · The Journal of Chemical Physics · doi:10.1063/1.1750906 · Cited by 10,152
Cited by
Electrochemical impedance spectroscopy (EIS) of corrosion processes on inhomogeneous surfaces
Jüttner, K. (1990) · Electrochimica Acta · doi:10.1016/0013-4686(90)80004-8 · Cited by 817
King, A. D., Birbilis, N., & Scully, J. R. (2014) · Electrochimica Acta · doi:10.1016/j.electacta.2013.12.124 · Cited by 640
Özcan, M., Dehri, İ., & Erbil, M. (2004) · Applied Surface Science · doi:10.1016/j.apsusc.2004.04.017 · Cited by 498
A review of AC impedance modeling and validation in SOFC diagnosis
Huang, Q.-A., Hui, R., Wang, B., & Zhang, J. (2007) · Electrochimica Acta · doi:10.1016/j.electacta.2007.05.071 · Cited by 403
Okafor, P. C., & Zheng, Y. (2009) · Corrosion Science · doi:10.1016/j.corsci.2009.01.027 · Cited by 356
Metadata
- Authors
- Mansfeld, F.
- Venue
- Corrosion
- Published
- 1981-05-01
- Volume
- 37
- Issue
- 5
- Pages
- 301-307
- ISSN
- 0010-9312 (ISSN-L)
- 1938-159X
- OpenAlex
- W4239954316
- Cited by
- 583
- References
- 1
- FWCI
- 11.49
- Type
- journal article
- Language
- en
- Open access
- closed
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