The DOI matches its Crossref record; 78 of the 78 references it cites were found in a registry or an index.
Aqueous chemistry and its role in secondary organic aerosol (SOA) formation
Open accessAbstract
Abstract. There is a growing understanding that secondary organic aerosol (SOA) can form through reactions in atmospheric waters (i.e., clouds, fogs, and aerosol water). In clouds and wet aerosols, water-soluble organic products of gas-phase photochemistry dissolve into the aqueous phase where they can react further (e.g., with OH radicals) to form low volatility products that are largely retained in the particle phase. Organic acids, oligomers and other products form via radical and non-radical reactions, including hemiacetal formation during droplet evaporation, acid/base catalysis, and reaction of organics with other constituents (e.g., NH4+). This paper provides an overview of SOA formation through aqueous chemistry, including atmospheric evidence for this process and a review of radical and non-radical chemistry, using glyoxal as a model precursor. Previously unreported analyses and new kinetic modeling are reported herein to support the discussion of radical chemistry. Results suggest that reactions with OH radicals tend to be faster and form more SOA than non-radical reactions. In clouds these reactions yield organic acids, whereas in wet aerosols they yield large multifunctional humic-like substances formed via radical-radical reactions and their O/C ratios are near 1.
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Pöschl, U., & Shiraiwa, M. (2015) · Chemical Reviews · doi:10.1021/cr500487s · Cited by 657
Sun, Y., Wang, Z., Fu, P., Jiang, Q., Yang, T., Li, J., & Ge, X. (2013) · Atmospheric Environment · doi:10.1016/j.atmosenv.2013.06.019 · Cited by 406
Ervens, B., & Volkamer, R. (2010) · Atmospheric Chemistry and Physics · doi:10.5194/acp-10-8219-2010 · Cited by 386
Li, Y., Pöschl, U., & Shiraiwa, M. (2016) · Atmospheric Chemistry and Physics · doi:10.5194/acp-16-3327-2016 · Cited by 384
Evolution of trace gases and particles emitted by a chaparral fire in California
Akagi, S. K., Craven, J. S., Taylor, J. W., McMeeking, G. R., Yokelson, R. J., Burling, I. R., Urbanski, S. P., Wold, C. E., Seinfeld, J. H., Coe, H., et al. (2012) · Atmospheric Chemistry and Physics · doi:10.5194/acp-12-1397-2012 · Cited by 353
Metadata
- Authors
- Lim, Y. B., Tan, Y., Perri, M. J., Seitzinger, S. P., & Turpin, B. J.
- Venue
- Atmospheric Chemistry and Physics
- Publisher
- Copernicus GmbH
- Published
- 2010-11-10
- Volume
- 10
- Issue
- 21
- Pages
- 10521-10539
- ISSN
- 1680-7316 (ISSN-L)
- 1680-7324
- OpenAlex
- W2103639584
- Cited by
- 585
- References
- 78
- FWCI
- 23.75
- Type
- journal article
- Language
- en
- Open access
- gold
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