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Cited by 184

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Atmospheric acidification of mineral aerosols: a source of bioavailable phosphorus for the oceans

Open access
Nenes, A., Krom, M. D., Mihalopoulos, N., Van Cappellen, P., Shi, Z., Bougiatioti, A., Zarmpas, P., Herut, B.·2011·Atmospheric Chemistry and Physics

Abstract

Abstract. Primary productivity of continental and marine ecosystems is often limited or co-limited by phosphorus. Deposition of atmospheric aerosols provides the major external source of phosphorus to marine surface waters. However, only a fraction of deposited aerosol phosphorus is water soluble and available for uptake by phytoplankton. We propose that atmospheric acidification of aerosols is a prime mechanism producing soluble phosphorus from soil-derived minerals. Acid mobilization is expected to be pronounced where polluted and dust-laden air masses mix. Our hypothesis is supported by the soluble compositions and reconstructed pH values for atmospheric particulate matter samples collected over a 5-yr period at Finokalia, Crete. In addition, at least tenfold increase in soluble phosphorus was observed when Saharan soil and dust were acidified in laboratory experiments which simulate atmospheric conditions. Aerosol acidification links bioavailable phosphorus supply to anthropogenic and natural acidic gas emissions, and may be a key regulator of ocean biogeochemistry.

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Crossref · 10.5194/acp-11-6265-2011

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Metadata

Authors
Nenes, A., Krom, M. D., Mihalopoulos, N., Van Cappellen, P., Shi, Z., Bougiatioti, A., Zarmpas, P., & Herut, B.
Venue
Atmospheric Chemistry and Physics
Published
2011-07-01
Volume
11
Issue
13
Pages
6265-6272
ISSN
  • 1680-7316 (ISSN-L)
  • 1680-7324
OpenAlex
W2096907405
Cited by
184
References
2
FWCI
5.33
Type
journal article
Language
en
Open access
gold

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CoChat. (2026). Citation check: Atmospheric acidification of mineral aerosols: a source of bioavailable phosphorus for the oceans. https://app.cochat.ai/papers/10.5194/acp-11-6265-2011
The paper
Nenes, A., Krom, M. D., Mihalopoulos, N., Van Cappellen, P., Shi, Z., Bougiatioti, A., Zarmpas, P., & Herut, B. (2011). Atmospheric acidification of mineral aerosols: a source of bioavailable phosphorus for the oceans. Atmospheric Chemistry and Physics. https://doi.org/10.5194/acp-11-6265-2011

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