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Cited by 26Atmospheric chemistry and aerosolsAtmospheric aerosols and cloudsAtmospheric Ozone and Climate

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The fate of NO x emissions due to nocturnal oxidation at high latitudes: 1-D simulations and sensitivity experiments

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Joyce, P. L., von Glasow, R., Simpson, W. R.·2014·Atmospheric Chemistry and Physics
DOI 10.5194/acp-14-7601-2014

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Abstract

Abstract. The fate of nitrogen oxide pollution during high-latitude winter is controlled by reactions of dinitrogen pentoxide (N2O5) and is highly affected by the competition between heterogeneous atmospheric reactions and deposition to the snowpack. MISTRA (MIcrophysical STRAtus), a 1-D photochemical model, simulated an urban pollution plume from Fairbanks, Alaska to investigate this competition of N2O5 reactions and explore sensitivity to model parameters. It was found that dry deposition of N2O5 made up a significant fraction of N2O5 loss near the snowpack, but reactions on aerosol particles dominated loss of N2O5 over the integrated atmospheric column. Sensitivity experiments found the fate of NOx emissions were most sensitive to NO emission flux, photolysis rates, and ambient temperature. The results indicate a strong sensitivity to urban area density, season and clouds, and temperature, implying a strong sensitivity of the results to urban planning and climate change. Results suggest that secondary formation of particulate (PM2.5) nitrate in the Fairbanks downtown area does not contribute significant mass to the total PM2.5 concentration, but appreciable amounts are formed downwind of downtown due to nocturnal NOx oxidation and subsequent reaction with ammonia on aerosol particles.

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Metadata

Authors
Joyce, P. L., von Glasow, R., & Simpson, W. R.
Affiliations
  • University of Alaska Fairbanks (US)
  • University of East Anglia (GB)
ORCID
Venue
Atmospheric Chemistry and Physics
Publisher
Copernicus GmbH
Published
2014-07-29
Volume
14
Issue
14
Pages
7601-7616
ISSN
  • 1680-7316 (ISSN-L)
  • 1680-7324
DOI
10.5194/acp-14-7601-2014
OpenAlex
W2152233843
Cited by
26
References
1
Citations by year
2025: 2 · 2024: 4 · 2023: 3 · 2022: 5 · 2021: 5 · 2020: 1 · 2019: 1 · 2018: 2 · 2016: 2 · 2015: 1
FWCI
0.66
Type
journal article
Language
en
Open access
Licence
Locations
  • Atmospheric chemistry and physics (publishedVersion, cc-by)
  • UEA Digital Repository (University of East Anglia) (acceptedVersion, other-oa)
  • DOAJ (DOAJ: Directory of Open Access Journals) (submittedVersion, cc-by-sa)
Funders
  • National Science Foundation (0926220)
  • New York State Department of Environmental Conservation
  • National Oceanic and Atmospheric Administration
Topics
  • Physical Sciences › Earth and Planetary Sciences › Atmospheric Science › Atmospheric chemistry and aerosols
  • Physical Sciences › Environmental Science › Global and Planetary Change › Atmospheric aerosols and clouds
  • Physical Sciences › Earth and Planetary Sciences › Atmospheric Science › Atmospheric Ozone and Climate
Keywords
NOx emissions, dinitrogen pentoxide, dry deposition, ammonia, photolysis, temperature sensitivity, Fairbanks, Alaska

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