The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Cluster activation theory as an explanation of the linear dependence between formation rate of 3nm particles and sulphuric acid concentration
Open accessAbstract
Abstract. According to atmospheric observations new particle formation seems to be a function of sulphuric acid concentration to the power from one to two. The nucleation theorem then predicts that the critical cluster contains one to two sulphuric acid molecules. However, existing nucleation theories predicts that the power is more (or equal) than 2. Here we present an activation theory, which can explain the observed slope. In cluster activation the clusters containing one sulphuric acid molecule will activate for further growth due to heterogeneous nucleation, heterogeneous chemical reactions including polymerization or activation of soluble clusters. In the activation process organic vapours are typically needed as condensing agents.
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Cites
Oceanic phytoplankton, atmospheric sulphur, cloud albedo and climate
Charlson, R. J., Lovelock, J. E., Andreae, M. O., & Warren, S. G. (1987) · Nature · doi:10.1038/326655a0 · Cited by 4,305
Cited by
Atmospheric composition change – global and regional air quality
Monks, P. S., Granier, C., Fuzzi, S., Stohl, A., Williams, M. L., Akimoto, H., Amann, M., Baklanov, A., Baltensperger, U., Bey, I., et al. (2009) · Atmospheric Environment · doi:10.1016/j.atmosenv.2009.08.021 · Cited by 872
Self-citationImpact of nucleation on global CCN
Merikanto, J., Spracklen, D. V., Mann, G. W., Pickering, S. J., & Carslaw, K. S. (2009) · Atmospheric Chemistry and Physics · doi:10.5194/acp-9-8601-2009 · Cited by 851
Atmospheric new particle formation and growth: review of field observations
Kerminen, V.-M., Chen, X., Vakkari, V., Petäjä, T., Kulmala, M., & Bianchi, F. (2018) · Environmental Research Letters · doi:10.1088/1748-9326/aadf3c · Cited by 665
Self-citationOxidation products of biogenic emissions contribute to nucleation of atmospheric particles
Riccobono, F., Schobesberger, S., Scott, C. E., Dommen, J., Ortega, I. K., Rondo, L., Almeida, J., Amorim, A., Bianchi, F., Breitenlechner, M., et al. (2014) · Science · doi:10.1126/science.1243527 · Cited by 642
Self-citationCauses and importance of new particle formation in the present‐day and preindustrial atmospheres
Gordon, H., Kirkby, J., Baltensperger, U., Bianchi, F., Breitenlechner, M., Curtius, J., Dias, A., Dommen, J., Donahue, N. M., Dunne, E. M., et al. (2017) · Journal of Geophysical Research: Atmospheres · doi:10.1002/2017jd026844 · Cited by 478
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Metadata
- Authors
- Kulmala, M., Lehtinen, K. E. J., & Laaksonen, A.
- Venue
- Atmospheric Chemistry and Physics
- Publisher
- Copernicus GmbH
- Published
- 2006-03-10
- Volume
- 6
- Issue
- 3
- Pages
- 787-793
- ISSN
- 1680-7316 (ISSN-L)
- 1680-7324
- OpenAlex
- W2129433315
- Cited by
- 449
- References
- 1
- FWCI
- 27.46
- Type
- journal article
- Language
- en
- Open access
- gold
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- Kulmala, M., Lehtinen, K. E. J., & Laaksonen, A. (2006). Cluster activation theory as an explanation of the linear dependence between formation rate of 3nm particles and sulphuric acid concentration. Atmospheric Chemistry and Physics. https://doi.org/10.5194/acp-6-787-2006
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