Microextraction Techniques as a Sample Preparation Step for Metal Analysis
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Atomic Absorption Spectroscopy, Dr.
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DLLME suffers from limitations such as the use of harmful chlorinated solvents like chloroform, chlorobenzene and carbon tetrachloride to stabilize the dispersion.
“Although extensively applied, DLLME suffers from some limitations that need to be overcome, as the use of harmful chlorinated solvents like chloroform, chlorobenzene and carbon tetrachloride to stabilize the dispersion [46].”
From Advances in ionic liquids and deep eutectic solvents-based liquid phase microextraction of metals for sample preparation in Environmental Analytical Chemistry (2021) · cites this paper as [46]
Section 2.3 says early DLLME methods mostly used chlorinated extraction solvents, and §2.3.3 gives examples using chloroform and carbon tetrachloride. Section 2.3.2.1 links extraction-solvent solubility to the stability of the cloudy suspension. The copy does not identify chlorobenzene, describe these solvents as harmful, or explicitly call their use a limitation of DLLME. Page numbers were not available. (LLM, conf=0.84)
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Cites
Determination of organic compounds in water using dispersive liquid–liquid microextraction
Rezaee, M., Assadi, Y., Milani Hosseini, M.-R., Aghaee, E., Ahmadi, F., & Berijani, S. (2006) · Journal of Chromatography A · doi:10.1016/j.chroma.2006.03.007 · Cited by 3,402 · see citing works
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Developments in Liquid-phase Microextraction Method Based on Solidification of Floating Organic Drop
WANG, Y.-Y., ZHAO, G.-Y., CHANG, Q.-Y., ZANG, X.-H., WANG, C., & WANG, Z. (2010) · Chinese Journal of Analytical Chemistry · doi:10.1016/s1872-2040(09)60073-6 · Cited by 31 · see citing works
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Herce-Sesa, B., López-López, J. A., & Moreno, C. (2021) · TrAC Trends in Analytical Chemistry · doi:10.1016/j.trac.2021.116398 · Cited by 86 · see citing works
- Authors
- Biparva, P., & Abbas, A.
- Affiliations
- Islamic Azad University, Langarud Branch (IR)
- Academic Center for Education, Culture and Research (IR)
- ORCID
- Biparva, Pourya
- Venue
- Atomic Absorption Spectroscopy
- Publisher
- InTech
- Published
- 2012-01-20
- OpenAlex
- W1551099274
- Cited by
- 13
- References
- 4
- Citations by year
- 2022: 1 · 2021: 2 · 2020: 1 · 2019: 2 · 2018: 2 · 2017: 5
- FWCI
- 0.00
- Type
- book chapter
- Language
- en
- Open access
- hybrid
- doi.org
- Licence
- cc-by
- Locations
- InTech eBooks (publishedVersion, cc-by)
- BiblioBoard Library Catalog (Open Research Library) (submittedVersion, cc-by)
- Contact-less Assessment of In-vivo Body Signals Using Microwave Doppler Radar (InTech) (submittedVersion, cc-by-nc-nd)
- Funders
- Academic Center for Education, Culture and Research
- Topics
- Physical Sciences › Chemistry › Analytical Chemistry › Analytical chemistry methods development
- Physical Sciences › Engineering › Mechanics of Materials › Laser-induced spectroscopy and plasma
- Physical Sciences › Environmental Science › Water Science and Technology › Environmental and Analytical Chemistry Studies
- Keywords
- microextraction, sample preparation, metal analysis, preconcentration, atomic absorption spectrometry
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