Chemistry of organic fluorine compounds II: a critical review

Abstract

Survey of the Literature of Organic Fluorine Chemistry Survey of Fluorinating Agents Methods of Introducing Fluorine into Organic Molecules: Addition of Fluorine Addition of Hydrogen Fluoride Addition of Halogen Fluorides to Unsaturated Systems Addition of Fluorine and Other Elements Replacement of Hydrogen by Fluorine Replacement by Means of High-Valency Fluorides Electrophilic Fluorination of Carbon-Hydrogen Bonds Replacement of Halogens by Fluorine Replacement of Oxygen by Fluorine Replacement of Sulfur by Fluorine Replacement of Nitrogen by Fluorine Reactions of Organic Fluorine Compounds Reduction Oxidation Halogenation Nitration Nitrosation Sulfonation Acid-Catalyzed Syntheses Hydrolysis Alkylation Fluorocarbene Insertions Arylation Acylation Fluorinated Sulfur, Phosphorus, Boron, and Silicon Compounds Base-Catalyzed Condensation Reactions of Fluoromagnesium and Fluorolithium Compounds Other Organometallic Syntheses Additions: Linear Additions across Double Bonds Linear Additions to Acetylenic Compounds Cycloadditions Forming Three- and Four-Membered Rings Cycloadditions Forming Five- and Six-membered Rings Addition Reactions across Polyfluoroalkyl- and Perfluoroalkyl-Substituted CO and CN Multiple Bond Systems Eliminations Molecular Rearrangements andd Pyrolysis Fluorinated Compounds as Reagents Properties of Fluorinated Compounds Physical and Physicochemical Properties Biological Properties Analysis of Organic Fluorine Compounds Destructive Analytical Methods Modern Methods of Separation, Identification, and Structure Determination Nuclear Magnetic Resonance Spectroscopy of Organofluorine Compounds Application of Fluorinated Compounds Refrigerants, Propellants, and Foam-Blowing Agents Fire Suppression Agents Organic Fluoropolymers Fluorinated Pharmaceuticals ']8F-Labeled Radiopharmaceuticals Fluorinated Anesthetics Perfluorinated Liquids in Biology and Medicine Fluorinated Agrochemicals