Long‐term changes in lower tropospheric baseline ozone concentrations: Comparing chemistry‐climate models and observations at northern midlatitudes

Abstract

Two recent papers have quantified long‐term ozone (O 3) changes observed at northern midlatitude sites that are believed to represent baseline (here understood as representative of continental to hemispheric scales) conditions. Three chemistry‐climate models (NCAR CAM‐chem, GFDL‐CM3, and GISS‐E2‐R) have calculated retrospective tropospheric O 3 concentrations as part of the Atmospheric Chemistry and Climate Model Intercomparison Project and Coupled Model Intercomparison Project Phase 5 model intercomparisons. We present an approach for quantitative comparisons of model results with measurements for seasonally averaged O 3 concentrations. There is considerable qualitative agreement between the measurements and the models, but there are also substantial and consistent quantitative disagreements. Most notably, models (1) overestimate absolute O 3 mixing ratios, on average by ~5 to 17 ppbv in the year 2000, (2) capture only ~50% of O 3 changes observed over the past five to six decades, and little of observed seasonal differences, and (3) capture ~25 to 45% of the rate of change of the long‐term changes. These disagreements are significant enough to indicate that only limited confidence can be placed on estimates of present‐day radiative forcing of tropospheric O 3 derived from modeled historic concentration changes and on predicted future O 3 concentrations. Evidently our understanding of tropospheric O 3, or the incorporation of chemistry and transport processes into current chemical climate models, is incomplete. Modeled O 3 trends approximately parallel estimated trends in anthropogenic emissions of NOx, an important O 3 precursor, while measured O 3 changes increase more rapidly than these emission estimates.