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Efficient Isolation and Solubilization of Pristine Single‐Walled Nanotubes in Bile Salt Micelles
Abstract
We have investigated a wide variety of surfactants for their efficiency in dissolving isolated single‐walled carbon nanotubes (SWNTs) in water. In doing so, we have completely avoided the harsh chemical or mechanical conditions, such as acid or ultrasonic treatments, that are known to damage SWNTs. Bile salts in particular are found to be exceptionally effective in dissolving individual tubes, as evidenced by highly resolved optical absorption spectra, bright bandgap fluorescence, and the unprecedented resolution (∼ 2.5 cm–1) of the radial breathing modes in Raman spectra. This is attributed to the formation of very regular and stable micelles around the nanotubes providing an unusually homogeneous environment. Quantitative information concerning the degree of solubilization is obtained from absorption spectroscopy.
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Citations
Cites
Noncovalent sidewall functionalization of single-walled carbon nanotubes for protein immobilization
Chen, R. J., Zhang, Y., Wang, D., & Dai, H. (2001) · Journal of the American Chemical Society · doi:10.1021/ja010172b · Cited by 2,534
Cited by
A route to brightly fluorescent carbon nanotubes for near-infrared imaging in mice
Welsher, K., Liu, Z., Sherlock, S. P., Robinson, J. T., Chen, Z., Daranciang, D., & Dai, H. (2009) · Nature Nanotechnology · doi:10.1038/nnano.2009.294 · Cited by 1,287
Liu, S., Wei, L., Hao, L., Fang, N., Chang, M. W., Xu, R., Yang, Y., & Chen, Y. (2009) · ACS Nano · doi:10.1021/nn901252r · Cited by 567
Antaris, A. L., Robinson, J. T., Yaghi, O. K., Hong, G., Diao, S., Luong, R., & Dai, H. (2013) · ACS Nano · doi:10.1021/nn4006472 · Cited by 310
Metadata
- Authors
- Wenseleers, W., Vlasov, I. I., Goovaerts, E., Obraztsova, E. D., Lobach, A. S., & Bouwen, A.
- Venue
- Advanced Functional Materials
- Publisher
- Wiley
- Published
- 2004-11
- Volume
- 14
- Issue
- 11
- Pages
- 1105-1112
- ISSN
- 1616-301X (ISSN-L)
- 1616-3028
- OpenAlex
- W2063867429
- Cited by
- 499
- References
- 1
- FWCI
- 5.42
- Type
- journal article
- Language
- en
- Open access
- closed
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- Wenseleers, W., Vlasov, I. I., Goovaerts, E., Obraztsova, E. D., Lobach, A. S., & Bouwen, A. (2004). Efficient Isolation and Solubilization of Pristine Single‐Walled Nanotubes in Bile Salt Micelles. Advanced Functional Materials. https://doi.org/10.1002/adfm.200400130
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