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Dispersions of Surface‐Modified Carbon Nanotubes in Water‐Soluble and Water‐Insoluble Polymers
Abstract
Microscale aggregate formation, resulting from high intrinsic filler attractions, is one of the major issues in nanocomposite preparation and processing. Herein, the dispersive effects achieved by a wide range of surface‐active agents, as well as surface oxidation and functionalization, are investigated. The aim of our research is to form a uniform, multiwalled carbon nanotube (MWNT) distribution in water‐soluble (poly(ethylene glycol)) and water‐insoluble (polypropylene) polymers. In order to understand the surface‐charge‐related stability of the treated nanotubes solutions, zeta‐potential measurements are applied. Quantification of the state of the MWNT dispersion is derived from particle‐size analysis, while visual characterization is based on optical and electron microscopy. To estimate the nucleating ability of the surface‐modified carbon nanotubes, the temperature of crystallization and the degree of crystallinity are calculated from differential scanning thermograms. Finally, we suggest general guidelines to produce uniform MWNT dispersions using a dispersive agent and/or surface treatment in water‐soluble and water‐insoluble polymers.
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Cited by
Dispersion and functionalization of carbon nanotubes for polymer-based nanocomposites: A review
Ma, P.-C., Siddiqui, N. A., Marom, G., & Kim, J.-K. (2010) · Composites Part A: Applied Science and Manufacturing · doi:10.1016/j.compositesa.2010.07.003 · Cited by 3,414
Self-citationCatalyst layer ink interactions that affect coatability
Dixit, M. B., Harkey, B. A., Shen, F., & Hatzell, K. B. (2018) · Journal of The Electrochemical Society · doi:10.1149/2.0191805jes · Cited by 126
Pan, X., Wang, Q., He, P., Liu, K., Ni, Y., Ouyang, X., Chen, L., Huang, L., Wang, H., & Tan, Y. (2019) · ACS Sustainable Chemistry & Engineering · doi:10.1021/acssuschemeng.9b00579 · Cited by 109
Alijani, H., & Shariatinia, Z. (2018) · Chemical Engineering Research and Design · doi:10.1016/j.cherd.2017.11.014 · Cited by 94
Metadata
- Authors
- Vaisman, L., Marom, G., & Wagner, H. D.
- Venue
- Advanced Functional Materials
- Publisher
- Wiley
- Published
- 2006-01-27
- Volume
- 16
- Issue
- 3
- Pages
- 357-363
- ISSN
- 1616-301X (ISSN-L)
- 1616-3028
- OpenAlex
- W1996457075
- Cited by
- 393
- References
- 0
- FWCI
- 6.45
- Type
- journal article
- Language
- en
- Open access
- closed
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- Vaisman, L., Marom, G., & Wagner, H. D. (2006). Dispersions of Surface‐Modified Carbon Nanotubes in Water‐Soluble and Water‐Insoluble Polymers. Advanced Functional Materials. https://doi.org/10.1002/adfm.200500142
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