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Growth and Electrochemical Characterization versus Lithium of Fe3O4 Electrodes Made by Electrodeposition

Mitra, S., Poizot, P., Finke, A., Tarascon, J.‐M.·2006·Advanced Functional Materials

Abstract

Interest in binary oxides has been renewed because of their novel reactivity towards Li at low potential, which leads to large capacity gains. Here, the structural, morphological, and electrochemical properties of copper‐supported Fe 3 O 4 deposits prepared by cathodic reduction of a Fe III chelate in alkaline solution are reported. By tuning the deposit growth parameters, namely the deposition time and the temperature of the electrolytic bath, it is possible to prepare deposits with various morphologies. Thick deposits with well‐faceted particles of Fe 3 O 4 are produced when long deposition times are used; thin and shapeless deposits are formed after shorter electrolysis times. A screening study shows Fe 3 O 4 films prepared at 50 °C under –5 mA cm–2 for 40 s give the best electrochemical performance towards Li, namely with a sustained reversible capacity for over 50 cycles and outstanding rate capability even after 50 repeated charge–discharge sequences. Electrodeposition techniques provide an alternative efficient way to configure high‐performance conversion electrodes based on carbon‐free binary oxides.

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Metadata

Authors
Mitra, S., Poizot, P., Finke, A., & Tarascon, J. ‐.
Venue
Advanced Functional Materials
Publisher
Wiley
Published
2006-09-21
Volume
16
Issue
17
Pages
2281-2287
ISSN
  • 1616-301X (ISSN-L)
  • 1616-3028
OpenAlex
W2160245654
Cited by
232
References
0
FWCI
5.74
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Growth and Electrochemical Characterization versus Lithium of Fe3O4 Electrodes Made by Electrodeposition. https://app.cochat.ai/papers/10.1002/adfm.200500753
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Mitra, S., Poizot, P., Finke, A., & Tarascon, J. ‐. (2006). Growth and Electrochemical Characterization versus Lithium of Fe3O4 Electrodes Made by Electrodeposition. Advanced Functional Materials. https://doi.org/10.1002/adfm.200500753

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